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Trifluoromethyl iodide

Trifluoromethyl iodide Structure
CAS No.
2314-97-8
Chemical Name:
Trifluoromethyl iodide
Synonyms
CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
CBNumber:
CB7356124
Molecular Formula:
CF3I
Molecular Weight:
195.91
MOL File:
2314-97-8.mol
Modify Date:
2024/5/15 8:51:21

Trifluoromethyl iodide Properties

Melting point <−78 °C(lit.)
Boiling point −22.5 °C(lit.)
Density 2.361
vapor pressure 540.5kPa at 25℃
refractive index 1.379
Flash point -22.5°C
form Gas
Water Solubility Slightly soluble in water.
Sensitive Light Sensitive
BRN 1732740
Stability Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable.
LogP 2.41 at 22.85℃
CAS DataBase Reference 2314-97-8(CAS DataBase Reference)
NIST Chemistry Reference Methane, trifluoroiodo-(2314-97-8)
EPA Substance Registry System Trifluoroiodomethane (2314-97-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS04,GHS07,GHS08
Signal word  Warning
Hazard statements  H280-H341-H420
Precautionary statements  P201-P202-P280-P308+P313-P410+P403-P502
Hazard Codes  Xn,Xi
Risk Statements  68
Safety Statements  36/37
RIDADR  UN 1956 2.2
WGK Germany  1
RTECS  PB6975000
27
Hazard Note  Irritant
TSCA  T
HazardClass  2.2
HS Code  2903780020
NFPA 704
0
0 0

Trifluoromethyl iodide price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 171441 Trifluoroiodomethane 99% 2314-97-8 100G ₹35635.9 2022-06-14 Buy
Product number Packaging Price Buy
171441 100G ₹35635.9 Buy

Trifluoromethyl iodide Chemical Properties,Uses,Production

Chemical Properties

colourless gas

Uses

Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.

Preparation

A glass flask provided with a gas outlet is filled with 80 g. (0.153 mole) of CI4 and 30 g. (0.135 mole) of IF5. The gas outlet is connected via short rubber tubes to several gas traps cooled with liquid nitrogen. Agitation of the vessel produces vigorous evolution of gas. When the reaction subsides, the system is heated for 30 min at 90-100°C. The condensate in the gas traps is then washed with 5% NaOH and fractionated. The yield is 90%. preparation of Trifluoromethyl iodide

Synthesis Reference(s)

Journal of the American Chemical Society, 107, p. 5014, 1985 DOI: 10.1021/ja00303a042

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