Trimethylsulfoxonium iodide
![Trimethylsulfoxonium iodide Structure](CAS/GIF/1774-47-6.gif)
- CAS No.
- 1774-47-6
- Chemical Name:
- Trimethylsulfoxonium iodide
- Synonyms
- TMSOI;Trimethylsulfoxonium;TRIMETHYLSULPHOXONIUM IODIDE;Trimethyl sulfoxide iodide;trimethyloxosulphonium iodide;TriMethyloxosulfoniuM Iodide;NSC 71213;foxonium iodide;RARECHEM AQ A1 0066;Trimethyl sulfoxide
- CBNumber:
- CB5304873
- Molecular Formula:
- C3H9IOS
- Molecular Weight:
- 220.07
- MOL File:
- 1774-47-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/4 15:29:52
Melting point | 208-212 °C (dec.) (lit.) |
---|---|
Density | 1.7074 (estimate) |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | H2O: 50 mg/mL, clear |
form | Crystalline Powder |
color | White to light yellow |
PH | pH(50g/l, 25℃) : 4.8~6.0 |
Water Solubility | 15 g/L (20 ºC) |
Sensitive | Light Sensitive |
BRN | 3595854 |
InChI | InChI=1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1 |
InChIKey | BPLKQGGAXWRFOE-UHFFFAOYSA-M |
SMILES | [S+](=O)(C)(C)C.[I-] |
CAS DataBase Reference | 1774-47-6(CAS DataBase Reference) |
EPA Substance Registry System | Sulfoxonium, trimethyl-, iodide (1774-47-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 36/37/38-22 | |||||||||
Safety Statements | 37/39-26-36-24/25 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | WS3585000 | |||||||||
F | 8 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29309070 | |||||||||
NFPA 704 |
|
Trimethylsulfoxonium iodide price More Price(14)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | T80500 | Trimethylsulfoxonium iodide 98% | 1774-47-6 | 25G | ₹2900 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | T80500 | Trimethylsulfoxonium iodide 98% | 1774-47-6 | 100G | ₹3280 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | T80500 | Trimethylsulfoxonium iodide 98% | 1774-47-6 | 500G | ₹9600 | 2022-06-14 | Buy |
TCI Chemicals (India) | T1065 | Trimethylsulfoxonium Iodide | 1774-47-6 | 25G | ₹1700 | 2022-05-26 | Buy |
TCI Chemicals (India) | T1065 | Trimethylsulfoxonium Iodide | 1774-47-6 | 100G | ₹3500 | 2022-05-26 | Buy |
Trimethylsulfoxonium iodide Chemical Properties,Uses,Production
Chemical Properties
WHITE TO LIGHT YELLOW CRYSTALLINE POWDER
Uses
Trimethylsulfoxonium Iodide is used to synthesize methylene-transfer reagents that are used in the preparation of epoxides.
Synthesis
Trimethylsulfoxonium iodide is commonly prepared by a reaction of Dimethyl Sulfoxide with ≈2.5 equiv of Iodomethane. After refluxing for 24 h at 80?°C, the reaction mixture is cooled, and the crude solid product is filtered and washed with acetone to give the trimethylsulfoxonium iodide. Iodomethane has to be handled in a fume hood because of its high volatility and toxicity. Excess MeI is used to ensure the completion of the reaction.
storage
The iodide and chloride salts are hygroscopic and must be stored in a cool, dry place. They are incompatible with strong oxidizing agents and strong bases. The iodide salt is sensitive to light and needs to be protected from light as much as possible.
Trimethylsulfoxonium iodide Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
SAGAR LIFE SCIENCES PVT LTD | +91-8770359041 +91-8770359041 | Gujarat, India | 79 | 58 | Inquiry |
Seema Finechem Industry LLP | +91-8451840941 +91-8451840941 | NaviMumbai, India | 43 | 58 | Inquiry |
Danopharm Chemicals Pvt.Ltd. | +91 9821080785 | Mumbai, India | 37 | 58 | Inquiry |
Eskay Iodine Pvt Ltd | +91-22-6622 7575 | Mumbai, India | 28 | 58 | Inquiry |
Laksh Finechem Pvt.Ltd. | +91-9978522233 +91-78522233 | Gujarat, India | 55 | 58 | Inquiry |
Infinium Pharmachem Limited | +91-2692238849 +91-2692238850 | Gujarat, India | 65 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
Meenaakshi Molecules Pvt Ltd | +91-9121311126 +91-9121311126 | Telangana, India | 45 | 58 | Inquiry |
DeliCare LifeSciences Pvt Ltd | +91-7977363866 +91-7977363866 | Maharashtra, India | 25 | 58 | Inquiry |
1774-47-6(Trimethylsulfoxonium iodide)Related Search:
1of4
chevron_right