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Diethyl chloromalonate

Diethyl chloromalonate Structure
CAS No.
14064-10-9
Chemical Name:
Diethyl chloromalonate
Synonyms
Nsc 227952;Einecs 237-913-0;RARECHEM AL BI 0643;Diethyl chloromalote;Ethyl chloromalonate;Bosentan Impurity 16;DIETHYL CHLOROMALONATE;α-Chlorodiethylmalonate;Ethylmonochloromalonate;Diethyl chloroMalonate 95%
CBNumber:
CB7686706
Molecular Formula:
C7H11ClO4
Molecular Weight:
194.61
MOL File:
14064-10-9.mol
MSDS File:
SDS
Modify Date:
2024/4/23 14:28:52

Diethyl chloromalonate Properties

Boiling point 279.11°C (rough estimate)
Density 1.204 g/mL at 25 °C (lit.)
refractive index n20/D 1.432(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka 9.07±0.46(Predicted)
form Liquid
color Clear colorless
Specific Gravity 1.204
LogP 2.23 at 40℃ and pH4-9
CAS DataBase Reference 14064-10-9(CAS DataBase Reference)
EPA Substance Registry System Propanedioic acid, 2-chloro-, 1,3-diethyl ester (14064-10-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H314-H335-H400
Precautionary statements  P261-P271-P273-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C
Risk Statements  34-36/37
Safety Statements  26-27-28-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  III
HS Code  29171990

Diethyl chloromalonate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 437786 Diethyl chloromalonate 95% 14064-10-9 5ML ₹5877.98 2022-06-14 Buy
Sigma-Aldrich(India) 437786 Diethyl chloromalonate 95% 14064-10-9 25ML ₹19679.85 2022-06-14 Buy
Product number Packaging Price Buy
437786 5ML ₹5877.98 Buy
437786 25ML ₹19679.85 Buy

Diethyl chloromalonate Chemical Properties,Uses,Production

Chemical Properties

Clear Colourless Liquid

Uses

Diethyl chloromalonate is a compound used in the models of aquatic toxicity developed

General Description

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K2CO3-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives to afford functionalized 2,3-dihydrobenzofurans. It reacts with Cs2CO3 in the presence of elemental S8 or Sen to afford the corresponding diethyl thioxo- or selenoxomalonates, which can be trapped in situ with various 1,3-dienes.

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Diethyl chloroMalonate 95% 2-Chloro-malonic acid 1,3-diethyl ester Chloropropanedioicaciddiethylester chloro-propanedioicacidiethylester RARECHEM AL BI 0643 Diethyl chloromalote Propanedioic acid, chloro-, diethyl ester 2-chloro-malonic acid diethyl ester α-Chlorodiethylmalonate Ethyl chloromalonate Diethyl chloromalonate ,98% Diethyl chloromalonate ,90% 2-Chloromalonic acid diethyl Chloromalonic acid diethyl Einecs 237-913-0 Ethylmonochloromalonate Malonic acid, chloro-, diethyl ester Nsc 227952 Propanedioic acid, 2-chloro-, 1,3-diethyl ester Diethyl chloromalonate ,95% DIETHYL CHLOROMALONATE CHLOROMALONIC ACID DIETHYL ESTER 2-Chloropropanedioic Acid 1,3-Diethyl Ester Chloropropanedioic Acid Ethyl Ester Diethyl MonochloroMalonate Chlorinated diethylMalonate DIETHYL CHLOROMALONATE FOR SYNTHESIS Bosentan Impurity 16 1,3-diethyl 2-chloropropanedioate Diethyl 2-chloropropanedioate 14064-10-9 C7H11ClO4 ClCHCO2C2H52 Carbonyl Compounds C6 to C7 Building Blocks Organic Building Blocks Esters ester series Aliphatics Pharmaceutical Intermediates TheMalonateRamificationProducts C6 to C7 Carbonyl Compounds Esters