Dimethyl chloromalonate

Dimethyl chloromalonate Structure
CAS No.
28868-76-0
Chemical Name:
Dimethyl chloromalonate
Synonyms
CL-DMM;AURORA KA-6079;Dimethyl chloromalote;Chloro-Methyl Malonate;DIMETHYL CHLOROMALONATE;Ethylsuccinyl monochloride;ChlorotwoMethylMalonic aci;DiMethyl chloroMalonate 94%;ChlorotwoMethylMalonic acid;imethyl2-chloropropanedioate
CBNumber:
CB8129206
Molecular Formula:
C5H7ClO4
Molecular Weight:
166.56
MOL File:
28868-76-0.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:38

Dimethyl chloromalonate Properties

Boiling point 105-106 °C/19 mmHg (lit.)
Density 1.305 g/mL at 25 °C (lit.)
refractive index n20/D 1.437(lit.)
Flash point 224 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka 9.02±0.46(Predicted)
form clear liquid
color Colorless to Light yellow
BRN 1768415
CAS DataBase Reference 28868-76-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
21
HazardClass  8
PackingGroup  III
HS Code  2917198090
NFPA 704
1
3 0

Dimethyl chloromalonate price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 374539 Dimethyl chloromalonate 94% 28868-76-0 25G ₹14765.3 2022-06-14 Buy
Sigma-Aldrich(India) 374539 Dimethyl chloromalonate 94% 28868-76-0 25G ₹14765.3 2022-06-14 Buy
Sigma-Aldrich 374539 Dimethyl chloromalonate 94% 28868-76-0 100G ₹47770.73 2022-06-14 Buy
Sigma-Aldrich(India) 374539 Dimethyl chloromalonate 94% 28868-76-0 100G ₹47770.73 2022-06-14 Buy
TCI Chemicals (India) D5467 Dimethyl Chloromalonate min. 98.0 % 28868-76-0 5G ₹2800 2022-05-26 Buy
Product number Packaging Price Buy
374539 25G ₹14765.3 Buy
374539 25G ₹14765.3 Buy
374539 100G ₹47770.73 Buy
374539 100G ₹47770.73 Buy
D5467 5G ₹2800 Buy

Dimethyl chloromalonate Chemical Properties,Uses,Production

Uses

Dimethyl chloromalonate is suitable for use in the synthesis of 4,5,6-trichloropyrimidine. It may be used in the stereoselective synthesis of highly functionalized nitrocyclopropanes. It may be used in one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes.

General Description

Dimethyl chloromalonate (dimethyl 2-chloromalonate) is a dialkyl 2-substituted malonate. Carbanions of dimethyl chloromalonate are reported to react with naphthoquinone derivatives, via vicarious nucleophilic substitution or oxidative nucleophilic substitution of hydrogen processes. Dimethyl chloromalonate is reported to react with hydroquinone and monosubstituted hydroquinones to afford 2-oxido-benzo[b]furan derivatives. Synthesis of dimethyl 2-chloromalonate, via chlorination of dimethyl malonate has been reported.

Dimethyl chloromalonate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 187)Suppliers
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Ethylsuccinyl monochloride 2-CHLORO-MALONIC ACID DIMETHYL ESTER DIMETHYL CHLOROMALONATE CL-DMM AURORA KA-6079 2-Chloropropanedioic acid dimethyl ester Chloro-Methyl Malonate ChlorotwoMethylMalonic acid DiMethyl chloroMalonate 94% Propanedioic acid,2-chloro-, 1,3-dimethyl ester Dimethyl chloromalote ChlorotwoMethylMalonic aci dimethyl 2-chloropropanedioate imethyl2-chloropropanedioate 2-chloro-Propanedioic acid 1,3-dimethyl ester 28868-76-0 C5H7CIO4 C5H7ClO4 ClCHCOOCH32 Esters Organic Building Blocks Building Blocks C2 to C5 Carbonyl Compounds ester series Pharmaceutical Intermediates TheMalonateRamificationProducts C2 to C5 Carbonyl Compounds Esters