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Mannose Triflate

Mannose Triflate Structure
CAS No.
92051-23-5
Chemical Name:
Mannose Triflate
Synonyms
MANNOSE TRIFLATE;TATM;TATM USP/EP/BP;MANNOSE TRIFLATE F;beta-D-Mannopyranose;Mannose Triflate?New;Mannose triflate≥ 99%(GC);1,3,4,6-Tetra-O-acetyl-2-O-;Mannose Triflate, ultra pure;Mannose Triflate PLUS, ultra pure
CBNumber:
CB7774955
Molecular Formula:
C15H19F3O12S
Molecular Weight:
480.36
MOL File:
92051-23-5.mol
MSDS File:
SDS
Modify Date:
2024/7/5 11:27:01

Mannose Triflate Properties

Melting point 118-122 °C
alpha [α]D20 -14~-17゜(c=1,CHCl3)
Boiling point 481.6±45.0 °C(Predicted)
Density 1.50±0.1 g/cm3(Predicted)
refractive index -16 ° (C=1, CHCl3)
storage temp. -20°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Solid
color White to Off-White
optical activity [α]22/D -16°, c = 1 in chloroform
BRN 4341413
InChI InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3
InChIKey OIBDVHSTOUGZTJ-UBBZJQTNNA-N
SMILES [C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r|

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P261-P280-P271
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  3
10-21
HS Code  29329990

Mannose Triflate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) M1568 Mannose triflate For PET imaging, ≥98% (TLC) 92051-23-5 20MG ₹2359.85 2022-06-14 Buy
Sigma-Aldrich(India) M1568 Mannose triflate For PET imaging, ≥98% (TLC) 92051-23-5 25MG ₹3031 2022-06-14 Buy
Sigma-Aldrich(India) M1568 Mannose triflate For PET imaging, ≥98% (TLC) 92051-23-5 100MG ₹7328.53 2022-06-14 Buy
Sigma-Aldrich(India) M1568 Mannose triflate For PET imaging, ≥98% (TLC) 92051-23-5 10X25MG ₹15219.95 2022-06-14 Buy
Sigma-Aldrich(India) 655112 β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 98% 92051-23-5 100MG ₹4340.83 2022-06-14 Buy
Product number Packaging Price Buy
M1568 20MG ₹2359.85 Buy
M1568 25MG ₹3031 Buy
M1568 100MG ₹7328.53 Buy
M1568 10X25MG ₹15219.95 Buy
655112 100MG ₹4340.83 Buy

Mannose Triflate Chemical Properties,Uses,Production

Description

Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.

Uses

1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.

Preparation

The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).

Mannose Triflate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 235)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Qingdao Yonghefeng Economic and Trade Co., Ltd. +86-13375559818 +86-13375559818 China 195 58 Inquiry
Zibo Hangyu Biotechnology Development Co., Ltd +86-0533-2185556 +8617865335152 China 10991 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20294 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18646 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21667 55 Inquiry

Mannose Triflate Spectrum

MANNOSE TRIFLATE F 1,3,4,6-Tetraacetate 2-(trifluoromethanesulfonate) -D-Mannopyranose tetraacetyltrifluoromethanesulfonyl-beta-D-mannopyranose Mannose triflate, TATM, 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-(trifluoromethylsulfonyl)-β-D-mannopyranose 1-O,3-O,4-O,6-O-Tetraacetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate Mannose triflate 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose, Mannose triflate, TATM β-D-Maopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 1,3,4,6-Tetraacetate 2-(trifluoroMethanesulfonate) 1,3,4,6-Tetra-O-acetyl-2-O-trifluoroMethane 1,3,4,6-Tetra-O-acetyl-2-O-[(trifluoromethyl)sulphonyl]-beta-D-mannopyranose TATM, 1,3,4,6-Tetra-O-acetyl-2-O-triflyl-beta-D-mannopyranose b-D-Mannopyranose,1,3,4,6-tetraacetate 2-(trifluoroMethanesulfonate) beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoroMethanesulfonate 98% beta-D-Mannopyranose 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl- β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate(TATM) BETA-D-MANNOPYRANOSE 1,3,4,6-TETRAACETATE 2-TRIFLATE BETA-D-MANNOPYRANOSE, 1,3,4,6-TETRAACETATE 2-(TRIFLUOROMETHANE-SULFONATE) BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETATE 2-O-TRIFLUOROMETHANESULFONATE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-METHANESULFONYL-BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHANSULFONYL-BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULPHONYL-B-D-MANNOPYRANOSE TATM β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-*METHANESULFONY 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-b-D-mannopyranose 1,3,4,6-Tetra-O-acetyl-2-O- 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE, TATM 1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE(MANNOSE TRIFLATE) TETRA-O-ACETYL-2-O-TRIFLUOROMETHANE- & BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-AC& Mannose Triflate PLUS, ultra pure Mannose Triflate, ultra pure packing for GE Microlab Mannose Triflate, ultra pure packing for GE TRACERlab MXFDG Mannose Triflate, ultra pure 1,3,4,6-Tetra-O-Acetyl-2-O-(trifluoromethanesulfonyl)-a-D-mannopyranose Mannose triflate≥ 99%(GC) acetic acid [3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)-2-oxanyl]methyl ester TATM,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose [(2R,3R,4S,5S,6S)-3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)oxan-2-yl]methyl acetate Mannose triflate C15H19F3O12S high quality Cas number:92051-23-5 Tetra-O-acetyl-mannose triflate CRS β-D-Mannopyranose, 1,3,4,6-tetraacetate 2-(trifluoromethanesulfonate) TATM USP/EP/BP 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose β-D-Mannopyranose1,3,4,6-tetra-O-acetate2-O-trifluoromethanesulfonate 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate-β-D-Mannopyranose (2S,3S,4S,5R,6R)-6-(Acetoxymethyl)-3-(((trifluoromethyl)sulfonyl)oxy)tetrahydro-2H-pyran-2,4,5-triyl triacetate 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose MANNOSE TRIFLATE 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose 1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyr