ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Esters >Butyl Ester compounds >tert-Butyl bromoacetate
tert-Butyl bromoacetate
- CAS No.
- 5292-43-3
- Chemical Name:
- tert-Butyl bromoacetate
- Synonyms
- TERT-BUTYL 2-BROMOACETATE;T-BUTYL BROMOACETATE;1-Butylbromoacetate;BROMOACETIC ACID TERT-BUTYL ESTER;tert-Butyl Bromoacet;T-BUTYL 2-BROMOACETATE;2-Methyl-2-propanyl bromoacetate;BrCH2C(O)OC(CH3)3;BUTYLBROMOACETATE-TERT;ert-Butyl bromoacetate
- CBNumber:
- CB7853739
- Molecular Formula:
- C6H11BrO2
- Molecular Weight:
- 195.05
- MOL File:
- 5292-43-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/7 8:52:49
| Melting point | 44-47 °C |
|---|---|
| Boiling point | 50 °C10 mm Hg(lit.) |
| Density | 1.338 |
| vapor pressure | 1.62hPa at 25℃ |
| refractive index |
n |
| Flash point | 121 °F |
| storage temp. | 0-6°C |
| solubility | Chloroform, Ethyl Acetate (Slightly) |
| form | Liquid |
| Specific Gravity | 1.333 (20/4℃) |
| color | Clear colorless to yellow |
| Water Solubility | Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water. |
| Sensitive | Lachrymatory |
| BRN | 1753010 |
| InChIKey | BNWCETAHAJSBFG-UHFFFAOYSA-N |
| CAS DataBase Reference | 5292-43-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Acetic acid, bromo-, 1,1-dimethylethyl ester(5292-43-3) |
| EPA Substance Registry System | Acetic acid, bromo-, 1,1-dimethylethyl ester (5292-43-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H302-H314 | |||||||||
| Precautionary statements | P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,F | |||||||||
| Risk Statements | 10-36/37/38 | |||||||||
| Safety Statements | 26-24/25-16 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 19 | |||||||||
| Hazard Note | Irritant/Flammable/Lachrymatory | |||||||||
| TSCA | T | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29159080 | |||||||||
| NFPA 704 |
|
tert-Butyl bromoacetate price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 124230 | tert-Butyl bromoacetate 98% | 5292-43-3 | 10G | ₹1990 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 124230 | tert-Butyl bromoacetate 98% | 5292-43-3 | 50G | ₹7440 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 124230 | tert-Butyl bromoacetate 98% | 5292-43-3 | 250G | ₹24421.2 | 2022-06-14 | Buy |
| ALFA India | ALF-A14917-30 | tert-Butyl bromoacetate, 98% | 5292-43-3 | 250g | ₹14031 | 2022-05-26 | Buy |
| TCI Chemicals (India) | B1473 | tert-Butyl Bromoacetate min. 98.0 % | 5292-43-3 | 25G | ₹4400 | 2022-05-26 | Buy |
tert-Butyl bromoacetate Chemical Properties,Uses,Production
Chemical Properties
clear colorless to yellow liquid
Uses
tert-Butyl Bromoacetate is a halogenated t-butyl acetate commonly used as an alkylating agent. tert-Butyl Bromoacetate is used in the synthesis of collagenase inhibitors.
Preparation
Tert-butyl bromoacetate ester was synthesized using bromoacetic acid and isobutylene as raw materials,Amberlyst 15,a strong acidic cation exchange resin,as catalyst,and tert-butanol as modifier.
General Description
tert-Butyl bromoacetate serves as building blocks during the synthesis of model N-substituted oligoglycines (peptoids) containing an N-linked lactoside side-chain.
Safety
Tert-Butyl bromoacetate is a lachrymator. The reagent, reaction and its work-up should be handled in an adequately ventilated fume hood while wearing gloves, safety glasses and laboratory coat.
Purification Methods
Dissolve the ester in Et2O, wash it well with ice cold 10% aqueous K2CO3, dry it over CaCl2, filter and evaporate the Et2O, then fractionate it through a Vigreux column (p 11) in a vacuum. LACHRYMATORY. [Abramovitch et al. J Am Chem Soc 64 2274 1942, Abramovitch & Hauser J Am Chem Soc 65 986 1943, Beilstein 2 III 482.]
tert-Butyl bromoacetate Preparation Products And Raw materials
Raw materials
Preparation Products
DIETHYLAMINO-ACETIC ACID
(4-ACETYL-PIPERAZIN-1-YL)-ACETIC ACID
MORPHOLIN-4-YL-ACETIC ACID
TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD
tert-Butyl cyanoacetate
trans-3,4-Difluorocinnamic acid
AZIDOACETIC ACID
TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE
Zinc, bromo[2-(1,1-dimethylethoxy)-2-oxoethyl]-
(S)-4-BOC-MORPHOLINE-3-CARBOXYLIC ACID
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Global( 520)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| Otto Chemie Pvt Ltd | +91-2222070099 +91-2266382599 | Maharashtra, India | 429 | 58 | Inquiry |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | +91-26463395 +91-7926462688 | Gujarat, India | 1615 | 58 | Inquiry |
| Krishna Solvechem Ltd. | +91-9223432224 +91-2261230213 | Maharashtra, India | 56 | 58 | Inquiry |
| Yogi Enterprise | +91-9377714435 +91-9824314435 | Gujarat, India | 91 | 58 | Inquiry |
| HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
| Acid India Limited | 91-44-43454650 | Tamil Nadu, India | 29 | 58 | Inquiry |
| Oceanic Pharmachem Pvt. Ltd. | 91-22-42128600 | Maharashtra, India | 2006 | 58 | Inquiry |
| Aadish Impex Private Limited | 91-7710067023 | Maharashtra, India | 89 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| JSK Chemicals | 58 |
| Otto Chemie Pvt Ltd | 58 |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | 58 |
| Krishna Solvechem Ltd. | 58 |
| Yogi Enterprise | 58 |
| HiMedia Laboratories | 58 |
| Acid India Limited | 58 |
| Oceanic Pharmachem Pvt. Ltd. | 58 |
| Aadish Impex Private Limited | 58 |
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T-BUTYL BROMOACETATE,CAS:5292-43-3
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