Silicon dioxide
- CAS No.
- 7631-86-9
- Chemical Name:
- Silicon dioxide
- Synonyms
- Aerosil;White carbon;NEOSYL;Dioxosilane;Geduran Si 60;SILICA GEL BLUE;Hollow glass microspheres;Silica gel 60 (0.015-0.040 mm);LICHROSORB SI 100 (10 MYM) 10 G;SILICA GEL 60 PF254 FOR PREPARATIVE LAYE
- CBNumber:
- CB8138262
- Molecular Formula:
- O2Si
- Molecular Weight:
- 60.08
- MOL File:
- 7631-86-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/12/18 14:15:32
Melting point | >1600 °C(lit.) |
---|---|
Boiling point | >100 °C(lit.) |
Density | 2.2-2.6 g/mL at 25 °C |
vapor pressure | 13.3hPa at 1732℃ |
refractive index | 1.46 |
Flash point | 2230°C |
storage temp. | 2-8°C |
solubility | Practically insoluble in water and in mineral acids except hydrofluoric acid. It dissolves in hot solutions of alkali hydroxides. |
pka | 6.65-9.8[at 20 ℃] |
form | suspension |
Specific Gravity | 2.2 |
color | White to yellow |
PH | 5-8 (100g/l, H2O, 20℃)(slurry) |
Odor | at 100.00?%. odorless |
Resistivity | 1∞10*20 (ρ/μΩ.cm) |
Water Solubility | insoluble |
Sensitive | Hygroscopic |
Hydrolytic Sensitivity | 6: forms irreversible hydrate |
Crystal Structure | Trigonal |
Merck | 14,8493 |
Exposure limits | NIOSH: IDLH 3000 mg/m3; TWA 6 mg/m3 |
Stability | Stable. |
CAS DataBase Reference | 7631-86-9(CAS DataBase Reference) |
IARC | 3 (Vol. Sup 7, 68) 1997 |
NIST Chemistry Reference | Silicon(iv) oxide(7631-86-9) |
EPA Substance Registry System | Silica (7631-86-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H317-H412 | |||||||||
Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 36/37/38-36/37-22-43-52/53-36/38 | |||||||||
Safety Statements | 26-37/39-36-36/37/39-36/37-61 | |||||||||
OEB | B | |||||||||
OEL | TWA: 6 mg/m3 | |||||||||
HS Code | 2811221000 | |||||||||
Toxicity | LC inhalation in rat: > 200gm/m3/1H | |||||||||
IDLA | 3,000 mg/m3 | |||||||||
NFPA 704 |
|
Silicon dioxide price More Price(180)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 916153 | Lithium modified silica nanoparticles pore size non-porous, 400?nm particle size | 7631-86-9 | 1G | ₹23027.18 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 915904 | Lithium modified silica nanoparticles pore size non-porous, 600?nm particle size | 7631-86-9 | 1G | ₹23027.18 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 915645 | Lithium modified silica nanoparticles pore size non-porous, 200?nm particle size | 7631-86-9 | 1G | ₹23027.18 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 914908 | Lithium modified silica nanoparticles pore size non-porous, 200?nm particle size, 20?% (w/w) in ethanol | 7631-86-9 | 1ML | ₹32567.18 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 914622 | Silica nanoparticles pore size non-porous, 500?nm particle size, 5?% (w/w) in water, dispersion | 7631-86-9 | 2ML | ₹15085.13 | 2022-06-14 | Buy |
Silicon dioxide Chemical Properties,Uses,Production
Chemical Properties
white crystals or powder
Physical properties
Colorless amorphous (i.e., fused silica) or crystalline (i.e., quartz) material having a low thermal expansion coefficient and excellent optical transmittance in far UV. Silica is insoluble in strong mineral acids and alkalis except HF, concentrated H3PO4, NH4 HF2 , concentrated alkali metal hydroxides. Owing to its good corrosion resistance to liquid metals such as Si, Ge, Sn, Pb, Ga, In, Tl, Rb, Bi, and Cd, it is used as crucible container for melting these metals, while silica is readily attacked in an inert atmosphere by molten metals such as Li, Na, K Mg, and Al. Quartz crystals are piezoelectric and pyroelectric. Maximum service temperature 1090°C.
Uses
Silicon(IV) oxide, amorphous is used as carriers, processing aids, anti-caking and free-flow agents in animal feed. Defoamer applications such as paint, food, paper, textile and other industrial applications. Synthetic silicon dioxides are used as a rheology control agent in plastics. It is also used to manufacture adhesives, sealants and silicones.
Definition
ChEBI: A silicon oxide made up of linear triatomic molecules in which a silicon atom is covalently bonded to two oxygens.
General Description
contains sodium stabilizing counterion
Hazard
Not toxic if ingested, inhaled silica dust can cause silicosis; carcinogen.
Agricultural Uses
Silica is silicon dioxide, one of the most abundant materials on the earth's crust. Quartz is an example of silica. It is used as a filler in fertilizers, and also, in the manufacture of glass, ceramics, abrasives, rubber and cosmetics.
Safety Profile
The pure unaltered form is considered a nuisance dust. Some deposits contain small amounts of crystahne quartz and are therefore fibrogenic. When diatomaceous earth is calcined (with or without fluxing agents) some sdica is converted to cristobalite and is therefore fibrogenic. Tridymite has never been detected in calcined batomaceous earth. See also other silica entries
Potential Exposure
Diatomaceous earth is used as a filtering agent and as a filler in construction materials, pesticides, paints, and varnishes. The calcined version (which has been heat treated) is the most dangerous and contains crystallized silica, and should be handled as silica. See also other entries on silica
Shipping
This material is not singled out by DOT in its Performance-Oriented Packaging Standards.
Purification Methods
Purification of silica for high technology applications uses isopiestic vapour distillation from concentrated volatile acids and is absorbed in high purity water. The impurities remain behind. Preliminary cleaning to remove surface contaminants uses dip etching in HF or a mixture of HCl, H2O2 and deionised water [Phelan & Powell Analyst 109 1299 1984].
Derivatives
Precipitated silica is obtained like silica gel by acidifying an aqueous solution of sodium silicate. Precipitated silica is used as filler in rubber for automobile tires and reinforcement particulate in elastomers, and as a flatting agent in paints and coatings for improving the flatness of coatings.
Incompatibilities
Silica, amorphous is a noncombustible solid. Generally unreactive chemically. Incompatible with fluorine, oxygen difluoride, chlorine trifluoride. Soluble in molten alkalis and reacts with most metallic oxides at high temperature.
Waste Disposal
Sanitary landfill.
Silicon dioxide Preparation Products And Raw materials
Raw materials
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Supplier | Advantage |
---|---|
SORBEAD INDIA | 58 |
VAYUNANDAN IMPEX | 58 |
HiTech Minerals And Chemicals | 58 |
Hind Exports | 58 |
NEELKANTH FINECHEM | 58 |
Akshar Chemicals | 58 |
JP International | 58 |
Gloria Interchem Pvt Ltd | 58 |
ADI Chemsol LLP | 58 |
Medfoun Pharma and Chemicals | 58 |
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