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9-Bromophenanthrene

9-Bromophenanthrene Structure
CAS No.
573-17-1
Chemical Name:
9-Bromophenanthrene
Synonyms
9 - bromide;9 - broMine fe;9-Bromophenathrene;9-Bromophenanthene;9-BROMOPHENANTHRENE;9-bromo-phenanthren;9-phenathrylbromide;9-Bromo Phenantrene;9-Phenathryl bromide;9-Phenanthryl bromide
CBNumber:
CB8312934
Molecular Formula:
C14H9Br
Molecular Weight:
257.13
MOL File:
573-17-1.mol
MSDS File:
SDS
Modify Date:
2024/2/29 11:36:44

9-Bromophenanthrene Properties

Melting point 60-64 °C (lit.)
Boiling point 180-190 °C/2 mmHg (lit.)
Density 1.4251 (rough estimate)
refractive index 1.6404 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility chloroform: 50 mg/mL, clear
form Powder
color Light yellow
BRN 1869927
InChI InChI=1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H
InChIKey RSQXKVWKJVUZDG-UHFFFAOYSA-N
SMILES C1=C2C(C3C(C(Br)=C2)=CC=CC=3)=CC=C1
CAS DataBase Reference 573-17-1(CAS DataBase Reference)
NIST Chemistry Reference Phenanthrene, 9-bromo-(573-17-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
RTECS  SF7197000
8
Hazard Note  Irritant
HS Code  29036990
NFPA 704
1
0 0

9-Bromophenanthrene price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) B75409 9-Bromophenanthrene 96% 573-17-1 10G ₹2204.95 2022-06-14 Buy
Sigma-Aldrich(India) B75409 9-Bromophenanthrene 96% 573-17-1 25G ₹6150.65 2022-06-14 Buy
TCI Chemicals (India) B0838 9-Bromophenanthrene min. 98.0 % 573-17-1 25G ₹6000 2022-05-26 Buy
TCI Chemicals (India) B0838 9-Bromophenanthrene min. 98.0 % 573-17-1 250G ₹28300 2022-05-26 Buy
Product number Packaging Price Buy
B75409 10G ₹2204.95 Buy
B75409 25G ₹6150.65 Buy
B0838 25G ₹6000 Buy
B0838 250G ₹28300 Buy

9-Bromophenanthrene Chemical Properties,Uses,Production

Description

9-Bromophenanthrene is a luminescent material that fluoresces at short wavelengths and can be used as a molecular probe to detect the presence of other compounds and the mechanism of reaction, among other things.

Chemical Properties

light yellow powder. soluble in toluene, and chloroform (50 mg/ml).

Uses

9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.

Preparation

9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.

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