Phenanthrene
- CAS No.
- 85-01-8
- Chemical Name:
- Phenanthrene
- Synonyms
- Phenanthren;31055;Philippines;phenanthrene, pure;ravatite;Phenantren;Phenathrene;Phenanthrenetech;phethane;Phenantrin
- CBNumber:
- CB8854465
- Molecular Formula:
- C14H10
- Molecular Weight:
- 178.23
- MOL File:
- 85-01-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/29 16:45:47
| Melting point | 98-100 °C (lit.) |
|---|---|
| Boiling point | 340 °C (lit.) |
| Density | 1.063 g/mL at 25 °C (lit.) |
| vapor density | 6.14 |
| vapor pressure | 0.00012 hPa (20 °C) |
| refractive index | 1.5943 |
| Flash point | 99-101°C |
| storage temp. | room temp |
| solubility | Soluble in alcohol, benzene, toluene, and glacial acetic acid |
| pka | >15 (Christensen et al., 1975) |
| form | platelets (fine) |
| color | brown |
| Water Solubility | insoluble |
| Merck | 14,7212 |
| BRN | 1905428 |
| Henry's Law Constant | 0.49, 1.80, 3.35, and 7.89 at 5, 15, 25, and 35 °C, respectively (gas stripping-GC, Odabasi et al., 2006) |
| Exposure limits | OSHA: TWA 0.2 mg/m3 |
| Dielectric constant | 2.72（43.0℃） |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 85-01-8(CAS DataBase Reference) |
| IARC | 3 (Vol. Sup 7, 92) 2010 |
| NIST Chemistry Reference | Phenanthrene(85-01-8) |
| EPA Substance Registry System | Phenanthrene (85-01-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H410 | |||||||||
| Precautionary statements | P264-P270-P273-P301+P312-P391-P501 | |||||||||
| Hazard Codes | Xn,N,F,T | |||||||||
| Risk Statements | 22-36/37/38-50-50/53-40-67-65-38-11-52/53-39/23/24/25-23/24/25-63-43-45-20/21/22-20 | |||||||||
| Safety Statements | 26-60-61-36/37-29-62-45-16-7-24/25-23-53-37/39-22-33-25-9 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | SF7175000 | |||||||||
| F | 8 | |||||||||
| Autoignition Temperature | >450 °C | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2902 90 00 | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| Toxicity | LD50 i.p. in mice: 700 mg/kg (IARC) | |||||||||
| NFPA 704 |
|
Phenanthrene price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | P11409 | Phenanthrene 98% | 85-01-8 | 25G | ₹2394.08 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | P11409 | Phenanthrene 98% | 85-01-8 | 100G | ₹6668.48 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | P11409 | Phenanthrene 98% | 85-01-8 | 500G | ₹26375.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 73338 | Phenanthrene certified reference material, TraceCERT? | 85-01-8 | 100MG | ₹11734.05 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 695114 | Phenanthrene sublimed grade, ≥99.5% | 85-01-8 | 1G | ₹2763.98 | 2022-06-14 | Buy |
Phenanthrene Chemical Properties,Uses,Production
Description
Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) composed of three fused benzene rings. The name phenanthrene is a composite of phenyl and anthracene. In its pure form, it is found in cigarette smoke and is a known irritant, photosensitizing skin to light. Phenanthrene appears as a white powder having blue fluorescence.
Chemical Properties
Phenanthrene is a white crystalline substance. Weak aromatic odor. Polycyclic aromatic hydrocarbons (PAHs) are compounds containing multiple benzene rings and are also called polynuclear aromatic hydrocarbons.
Physical properties
Colorless, monoclinic crystals with a faint, aromatic odor
Uses
Phenanthrene is a polycyclic aromatic hydrocarbons, an environmental pollutant.
Production Methods
Phenanthrene occurs in coal tar and can be isolated from several types of crude petroleum.
Definition
ChEBI: A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene.'
General Description
Colorless monoclinic crystals with a faint aromatic odor. Solutions exhibit a blue fluorescence.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Phenanthrene may react with oxidizing materials .
Health Hazard
The acute oral toxicity of phenanthrene is low.It is more toxic than anthracene. An oral LD50value in mice is reported at 700 mg/kg. It maycause tumor in skin at the site of application.The evidence of carcinogenicity in animals,however, is inadequate.
Fire Hazard
Phenanthrene is combustible.
Safety Profile
Poison by intravenous route. Moderately toxic by ingestion. Mutation data reported. A human skin photosensitizer. Questionable carcinogen with experimental neoplastigenic and tumorigenic data by skin contact. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes
Potential Exposure
Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Carcinogenicity
Phenanthrene is ineffective as an initiator. It is not classifiable as to human carcinogenicity— class 3 by IARC and class D by IRIS, based on no human data and inadequate data from a single gavage study in rats and skin painting and injection studies in mice.
Shipping
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Waste Disposal
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
Phenanthrene Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
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chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| AnalyticsStanza Inc | +91-7032031309 +91-7032031309 | Hyderabad, India | 227 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| HiMedia Laboratories | 91-22-61471919 | Maharashtra, India | 1843 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| AnalyticsStanza Inc | 58 |
| JSK Chemicals | 58 |
| HiMedia Laboratories | 58 |
| A.J Chemicals | 58 |
| CHEMSWORTH | 30 |
| CLEARSYNTH LABS LTD. | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Otto Chemie Pvt. Ltd. | 58 |