1,2-BENZANTHRACENE
![1,2-BENZANTHRACENE Structure](CAS/GIF/56-55-3.gif)
- CAS No.
- 56-55-3
- Chemical Name:
- 1,2-BENZANTHRACENE
- Synonyms
- BENZ[A]ANTHRACENE;BENZO(A)ANTHRACENE;TETRAPHENE;Benzanthracene;BENZANTHRENE;Teraphene;NSC 30970;etraphene;Benzo(a)anthr;Benzoanthracene
- CBNumber:
- CB6690674
- Molecular Formula:
- C18H12
- Molecular Weight:
- 228.29
- MOL File:
- 56-55-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/26 15:15:06
Melting point | 157-159 °C(lit.) |
---|---|
Boiling point | 437.6 °C(lit.) |
Density | 1.274 g/cm3 |
vapor pressure | 54.8 (de Kruif, 1980) |
refractive index | 1.7710 (estimate) |
Flash point | -18 °C |
storage temp. | 2-8°C |
solubility | Soluble in ethanol, ether, acetone, benzene (U.S. EPA, 1985), toluene, xylenes, and other monoaromatic hydrocarbons. |
pka | >15 (Christensen et al., 1975) |
form | Solid |
color | Light Yellow |
Water Solubility | 9.4ug/L(25 ºC) |
Merck | 14,1062 |
BRN | 1909298 |
Henry's Law Constant | 1.48, 3.06, 6.22, 12.0, and 20.8 at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998) |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 56-55-3(CAS DataBase Reference) |
IARC | 2B (Vol. 92, Sup 7) 2010 |
EPA Substance Registry System | Benz[a]anthracene (56-55-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS08,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H350-H410 | |||||||||
Precautionary statements | P201-P273-P308+P313-P501 | |||||||||
Hazard Codes | T,N,Xn,F | |||||||||
Risk Statements | 45-50/53-67-65-38-11-63-43-36/37/38-23/24/25-39/23/24/25-52/53-40-51/53-20 | |||||||||
Safety Statements | 53-45-60-61-62-36/37-24/25-23-26-33-25-16-9 | |||||||||
RIDADR | UN 3077 9/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | CV9275000 | |||||||||
HazardClass | 6.1(b) | |||||||||
PackingGroup | III | |||||||||
HS Code | 29029000 | |||||||||
Toxicity | LD50 for mice by intravenous injection 10 mg/kg (Patnaik, 1992). | |||||||||
NFPA 704 |
|
1,2-BENZANTHRACENE price More Price(8)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | B2209 | Benz[a]anthracene 99% | 56-55-3 | 500MG | ₹11775.15 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | B2209 | Benz[a]anthracene 99% | 56-55-3 | 1G | ₹13686.3 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 75451 | Benz[a]anthracene certified reference material, TraceCERT? | 56-55-3 | 50MG | ₹9134.48 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 48563 | Benz[a]anthracene analytical standard | 56-55-3 | 100MG | ₹8158.35 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 40070-U | Benz[a]anthracene solution certified reference material, 1000?μg/mL in methanol | 56-55-3 | 1ML | ₹3857 | 2022-06-14 | Buy |
1,2-BENZANTHRACENE Chemical Properties,Uses,Production
Description
1,2-Benzanthracene is available as colourless to yellow-brown fluorescent flakes or powder. It is stable, combustible, and incompatible with strong oxidising agents. On decomposition, 1,2-benzanthracene releases carbon monoxide, carbon dioxide, acrid smoke, and fumes. Exposures may cause irritation of the eyes, skin, and respiratory tract.
Chemical Properties
1,2-Benzanthracene is available as colorless to yellow brown fl uorescent fl akes or powder. It is stable, combustible, and incompatible with strong oxidizing agents. On decomposition, 1,2-benzanthracene releases carbon monoxide, carbon dioxide, acrid smoke, and fumes. During work, 1,2-benzanthracene can be absorbed into the body of occupational workers by inhalation, through the skin, and by ingestion. Exposures may cause irritation to the eyes, skin, and respiratory tract.
Physical properties
Colorless leaflets or plates with a greenish-yellow fluorescence
Uses
Benz[a]anthracene is a PAH that has carcinogenic properties. It is also used in the synthesis of anti-tumor agents.
General Description
Colorless leaflets or plates or coarse gold powder with a greenish-yellow fluorescence. May reasonably be expected to be a carcinogen.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
1,2-BENZANTHRACENE may react vigorously with strong oxidizing agents. Can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
Hazard
Confirmed carcinogen. Found in oils, waxes, smoke, food, drugs.
Health Hazard
ACUTE/CHRONIC HAZARDS: When heated to decomposition 1,2-BENZANTHRACENE emits acrid smoke and irritating fumes.
Fire Hazard
Flash point data for 1,2-BENZANTHRACENE are not available. 1,2-BENZANTHRACENE is probably combustible.
Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by skin contact and other routes. Poison by intravenous route. Human mutation data reported. It is found in oils, waxes, smoke, food, drugs. When heated to decomposition it emits acrid smoke and irritating fumes.
Carcinogenicity
BA’s metabolites are genotoxic in the Ames
mutation test and caused unscheduled DNA
synthesis in primary rat hepatocytes.In an
in vivo mutagenic assay, male CD rats
(6/group) were dosed three times with BA over
a 24-hour interval by intratracheal instillation.
Lung cells were enzymatically separated and
used to determine the frequency of DNA
adducts, sister chromatid exchanges (SCEs),
and micronuclei. BA induced DNA adducts,
SCEs, and micronuclei in this rat lung cell
system.
Benz(a)anthracene is designated an A2-
suspected human carcinogen by ACGIH and
has no assigned threshold limit value.
storage
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed
Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.
Purification Methods
Crystallise 1,2-benzanthracene from MeOH, EtOH or *benzene (charcoal), then chromatograph it on alumina from sodium-dried *benzene (twice), using vacuum distillation to remove *benzene. Final purification is by vacuum sublimation. [Beilstein 5 IV 2549.]
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Powder can form an explosive mixture with air.
Waste Disposal
Atomize into incinerator with a flammable liquid.
Precautions
Workers should wash thoroughly after using and handling 1,2-benzanthracene. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with the eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
1,2-BENZANTHRACENE Preparation Products And Raw materials
Raw materials
1of2
chevron_rightPreparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Inventichem | +918790275459 | Telangana, India | 155 | 58 | Inquiry |
Spectrochem Private Limited | 08048372608Ext 246 | Maharashtra, India | 1056 | 58 | Inquiry |
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Henan Research New Materials Co., Ltd. | +86-18903931628 +86-18903931531 | China | 180 | 58 | Inquiry |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16216 | 58 | Inquiry |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21670 | 55 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29826 | 58 | Inquiry |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
Related articles
- Benz[a]anthracene:Mechanism of Toxicity
- A procarcinogen, benz[a]anthracene is metabolized to its carcinogenic form by phase 1 and phase 2 metabolism. As with other po....
- Nov 18,2021
- What is 1,2-benzanthracene?
- 1,2-Benzanthracene (C18H12, CAS registry No. 56-55-3) is colorless leaflets or plates or coarse gold powder with a greenish-ye....
- Jan 7,2020
56-55-3(1,2-BENZANTHRACENE)Related Search:
1of4
chevron_right