Tetracyanoethylene
![Tetracyanoethylene Structure](CAS/GIF/670-54-2.gif)
- CAS No.
- 670-54-2
- Chemical Name:
- Tetracyanoethylene
- Synonyms
- TCNE;Ethene-1,1,2,2-tetracarbonitrile;NSC 24833;(NC)2CC(CN)2;TetracyanoethyL;Tetracyanoethene;PERCYANOETHYLENE;Tetrakyanethylen;Tetrcyanoethylene;TETRACYANOETHYLENE
- CBNumber:
- CB9854093
- Molecular Formula:
- C6N4
- Molecular Weight:
- 128.09
- MOL File:
- 670-54-2.mol
- Modify Date:
- 2023/12/22 17:53:22
Melting point | 197-199 °C(lit.) |
---|---|
Boiling point | 223 °C |
Density | 1,348 g/cm3 |
refractive index | 1.5600 |
Flash point | 223°C |
storage temp. | 2-8°C |
form | Crystalline Powder, Crystals or Chunks |
color | White to beige-brown |
Water Solubility | hydrolyzes |
Sensitive | Moisture Sensitive |
λmax | 328nm(CHCl3)(lit.) |
Merck | 14,9195 |
BRN | 1679885 |
CAS DataBase Reference | 670-54-2(CAS DataBase Reference) |
NIST Chemistry Reference | Tetracyanoethylene(670-54-2) |
EPA Substance Registry System | Ethenetetracarbonitrile (670-54-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS06 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H300-H312+H332 | |||||||||
Precautionary statements | P261-P264-P280-P301+P310-P302+P352+P312-P304+P340+P312 | |||||||||
Hazard Codes | T+ | |||||||||
Risk Statements | 20/21-28-23/24 | |||||||||
Safety Statements | 28-36/37-45-28A-22-1 | |||||||||
RIDADR | UN 2811 6.1/PG 1 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | KM7300000 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29269095 | |||||||||
NFPA 704 |
|
Tetracyanoethylene price More Price(10)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | T8809 | Tetracyanoethylene 96% | 670-54-2 | 5G | ₹5401.68 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | T8809 | Tetracyanoethylene 96% | 670-54-2 | 25G | ₹24107.28 | 2022-06-14 | Buy |
TCI Chemicals (India) | T3264 | Tetracyanoethylene (purified by sublimation) | 670-54-2 | 1G | ₹2700 | 2022-05-26 | Buy |
TCI Chemicals (India) | T3264 | Tetracyanoethylene (purified by sublimation) | 670-54-2 | 5G | ₹9000 | 2022-05-26 | Buy |
TCI Chemicals (India) | T0077 | Tetracyanoethylene | 670-54-2 | 5G | ₹5800 | 2022-05-26 | Buy |
Tetracyanoethylene Chemical Properties,Uses,Production
Chemical Properties
white to beige-brown crystalline powder, crystals. Tetracyanoethylene [670-54-2], ethenetetracarbonitrile, TCNE, ( NC)2C = C (CN)2, Mr 128.09, mp 197 – 198℃, bp 223℃, n25 D 1.560. The preferred synthetic preparation of TCNE involves the debromination of the KBr complex of dibromomalononitrile. Tetracyanoethylene is a reactive compound that undergoes a variety of reactions including addition, replacement and cyclization. The chemistry of TCNE is exhaustively reviewed in.
Definition
The first member of a class of compounds called cyanocarbons.
Hazard
Hydrolyzes in moist air to hydrogen cyanide.
Purification Methods
Crystallise it from chlorobenzene, dichloroethane, or dichloromethane [Hall et al. J Org Chem 52 5528 1987]. Storeitat0oina desiccator over NaOH pellets. (It slowly evolves HCN on exposure to moist air CARE.) It can also be sublimed at 120o under vacuum. Also purify it by repeated sublimation at 120-130o/0.5mm. [Frey et al. J Am Chem Soc 107 748 1985, Traylor & Miksztal J Am Chem Soc 109 2778 1987, Fatiadi Synthesis 249 1986, Synthesis 749 1967, Beilstein 2 IV 1245.]
Tetracyanoethylene Preparation Products And Raw materials
Raw materials
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chevron_rightSupplier | Tel | Country | ProdList | Advantage | Inquiry |
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TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20361 | 58 | Inquiry |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | China | 9338 | 55 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29901 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
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