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Tetracyanoethylene

Tetracyanoethylene Structure
CAS No.
670-54-2
Chemical Name:
Tetracyanoethylene
Synonyms
TCNE;Ethene-1,1,2,2-tetracarbonitrile;NSC 24833;(NC)2CC(CN)2;TetracyanoethyL;Tetracyanoethene;PERCYANOETHYLENE;Tetrakyanethylen;Tetrcyanoethylene;TETRACYANOETHYLENE
CBNumber:
CB9854093
Molecular Formula:
C6N4
Molecular Weight:
128.09
MOL File:
670-54-2.mol
Modify Date:
2023/12/22 17:53:22

Tetracyanoethylene Properties

Melting point 197-199 °C(lit.)
Boiling point 223 °C
Density 1,348 g/cm3
refractive index 1.5600
Flash point 223°C
storage temp. 2-8°C
form Crystalline Powder, Crystals or Chunks
color White to beige-brown
Water Solubility hydrolyzes
Sensitive Moisture Sensitive
λmax 328nm(CHCl3)(lit.)
Merck 14,9195
BRN 1679885
CAS DataBase Reference 670-54-2(CAS DataBase Reference)
NIST Chemistry Reference Tetracyanoethylene(670-54-2)
EPA Substance Registry System Ethenetetracarbonitrile (670-54-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H300-H312+H332
Precautionary statements  P261-P264-P280-P301+P310-P302+P352+P312-P304+P340+P312
Hazard Codes  T+
Risk Statements  20/21-28-23/24
Safety Statements  28-36/37-45-28A-22-1
RIDADR  UN 2811 6.1/PG 1
WGK Germany  3
RTECS  KM7300000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29269095
NFPA 704
0
4 0

Tetracyanoethylene price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T8809 Tetracyanoethylene 96% 670-54-2 5G ₹5401.68 2022-06-14 Buy
Sigma-Aldrich(India) T8809 Tetracyanoethylene 96% 670-54-2 25G ₹24107.28 2022-06-14 Buy
TCI Chemicals (India) T3264 Tetracyanoethylene (purified by sublimation) 670-54-2 1G ₹2700 2022-05-26 Buy
TCI Chemicals (India) T3264 Tetracyanoethylene (purified by sublimation) 670-54-2 5G ₹9000 2022-05-26 Buy
TCI Chemicals (India) T0077 Tetracyanoethylene 670-54-2 5G ₹5800 2022-05-26 Buy
Product number Packaging Price Buy
T8809 5G ₹5401.68 Buy
T8809 25G ₹24107.28 Buy
T3264 1G ₹2700 Buy
T3264 5G ₹9000 Buy
T0077 5G ₹5800 Buy

Tetracyanoethylene Chemical Properties,Uses,Production

Chemical Properties

white to beige-brown crystalline powder, crystals. Tetracyanoethylene [670-54-2], ethenetetracarbonitrile, TCNE, ( NC)2C = C (CN)2, Mr 128.09, mp 197 – 198℃, bp 223℃, n25 D 1.560. The preferred synthetic preparation of TCNE involves the debromination of the KBr complex of dibromomalononitrile. Tetracyanoethylene is a reactive compound that undergoes a variety of reactions including addition, replacement and cyclization. The chemistry of TCNE is exhaustively reviewed in.

Definition

The first member of a class of compounds called cyanocarbons.

Hazard

Hydrolyzes in moist air to hydrogen cyanide.

Purification Methods

Crystallise it from chlorobenzene, dichloroethane, or dichloromethane [Hall et al. J Org Chem 52 5528 1987]. Storeitat0oina desiccator over NaOH pellets. (It slowly evolves HCN on exposure to moist air CARE.) It can also be sublimed at 120o under vacuum. Also purify it by repeated sublimation at 120-130o/0.5mm. [Frey et al. J Am Chem Soc 107 748 1985, Traylor & Miksztal J Am Chem Soc 109 2778 1987, Fatiadi Synthesis 249 1986, Synthesis 749 1967, Beilstein 2 IV 1245.]

Tetracyanoethylene Preparation Products And Raw materials

Global( 140)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Central Drug House(P) Ltd. 91-11-49404040 New Delhi, India 6160 58 Inquiry
Henan Fengda Chemical Co., Ltd +86-371-86557731 +86-13613820652 China 20361 58 Inquiry
Hangzhou FandaChem Co.,Ltd. 008657128800458; +8615858145714 China 9338 55 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29901 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
1,1,2,2-Tetracyanoethene 1,1,2,2-Tetracyanoethylene delta(sup2,2’)-bimalononitrile delta2,2'-Bimalononitrile Ethene, tetracyano- Ethylene, tetracyano- Tetracyanoethene Tetracyanoαthylen(ausderSchmelze) Tetracyanoαthylen(ausLOsung) Tetrakyanethylen PERCYANOETHYLENE TETRACYANOETHYLENE ETHYLENETETRACARBONITRILE Ethene tetracarbonitrile Tetracyanoethyleneoffwhitextl Tetrcyanoethylene Tetracyanoethylene,98% eth-1-ene-1,1,2,2-tetracarbonitrile Ethylenetetracarbonitrile, Percyanoethylene, TCNE 1,1,2,2-Ethenetetracarbonitrile Tetracyanoethylene, 98% 10GR Ethylenetetracarbonitrile TCNE TETRACYANOETHYLENE FOR SYNTHESIS Tetracyanoethylene, 2,3-Dicyanobut-2-ene-1,4-dinitrile (NC)2CC(CN)2 1,1,2,2-Ethylenetetracarbonitrile NSC 24833 Tetracyanoethylene (purified by sublimation) TetracyanoethyL Tetracyanoethylene (TCNE ) Tetracyanoethylene > TCNE Ethene-1,1,2,2-tetracarbonitrile 670-54-2 C6N4 CN2CCCN2 Organic Building Blocks Nitrogen Compounds Cyanides/Nitriles Oxidation Others Synthetic Reagents Building Blocks C6 to C7 Charge Transfer Complexes for Organic Metals TCNQ Derivatives Acceptors (Charge Transfer Complexes) organic compound Acceptors (Charge Transfer Complexes) Charge Transfer Complexes for Organic Metals Functional Materials TCNQ Derivatives