Acrylonitrile
- CAS No.
- 107-13-1
- Chemical Name:
- Acrylonitrile
- Synonyms
- 2-Propenenitrile;Propenenitrile;prop-2-enenitrile;ACRYLIC ACID NITRILE;Acrylon;CH2CHCN;Acrylnitril;PROPENITRILE;CYANOETHYLENE;Acrylonitrile monomer
- CBNumber:
- CB8764818
- Molecular Formula:
- C3H3N
- Molecular Weight:
- 53.06
- MOL File:
- 107-13-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/2 17:04:23
| Melting point | -83 °C (lit.) |
|---|---|
| Boiling point | 77 °C (lit.) |
| Density | 0.806 g/mL at 20 °C |
| vapor density | 1.83 (vs air) |
| vapor pressure | 86 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 32 °F |
| storage temp. | 2-8°C |
| solubility | 73g/l |
| form | Liquid |
| color | Clear |
| PH | 6.0-7.5 (50g/l, H2O, 20℃) |
| Odor | Mild pyridine-like odor at 2 to 22 ppm |
| Odor Threshold | 8.8ppm |
| explosive limit | 2.8-28%(V) |
| Water Solubility | Soluble. 7.45 g/100 mL |
| Sensitive | Light Sensitive |
| Merck | 14,131 |
| BRN | 605310 |
| Henry's Law Constant | 1.30 at 30.00 °C (headspace-GC, Hovorka et al., 2002) |
| Exposure limits | NIOSH REL: TWA 1 ppm, 15-min C 1 ppm, IDLH 85 ppm; OSHA PEL: TWA 2 ppm, 15-min C 10 ppm; ACGIH TLV: TWA 2 ppm. |
| Dielectric constant | 33.009999999999998 |
| LogP | 0.017 at 21℃ |
| CAS DataBase Reference | 107-13-1(CAS DataBase Reference) |
| IARC | 2B (Vol. 71) 1999 |
| NIST Chemistry Reference | 2-Propenenitrile(107-13-1) |
| EPA Substance Registry System | Acrylonitrile (107-13-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |      GHS02,GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H301+H311+H331-H315-H317-H318-H335-H350-H361fd-H411 | |||||||||
| Precautionary statements | P210-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | F,T,N,Xn | |||||||||
| Risk Statements | 45-11-23/24/25-37/38-41-43-51/53-39/23/24/25-62-63 | |||||||||
| Safety Statements | 53-9-16-45-61-36/37 | |||||||||
| RIDADR | UN 1093 3/PG 1 | |||||||||
| OEB | D | |||||||||
| OEL | TWA: 1 ppm, Ceiling: 10 ppm [15-minute] [skin] | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | AT5250000 | |||||||||
| F | 8 | |||||||||
| Autoignition Temperature | 481 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | I | |||||||||
| HS Code | 29261000 | |||||||||
| Toxicity | LD50 orally in rats: 0.093 g/kg (Smyth, Carpenter) | |||||||||
| IDLA | 60 ppm | |||||||||
| NFPA 704 |
|
Acrylonitrile price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.00834 | Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis | 107-13-1 | 100ML | ₹2310 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.00834 | Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis | 107-13-1 | 1L | ₹3930 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 110213 | Acrylonitrile ≥99%, contains 35-45?ppm monomethyl ether hydroquinone as inhibitor | 107-13-1 | 5ML | ₹1315.2 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 110213 | Acrylonitrile ≥99%, contains 35-45?ppm monomethyl ether hydroquinone as inhibitor | 107-13-1 | 100ML | ₹2507.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 40003 | Acrylonitrile solution certified reference material, 5000?μg/mL in methanol | 107-13-1 | 1ML | ₹5772.2 | 2022-06-14 | Buy |
Acrylonitrile Chemical Properties,Uses,Production
Chemical Properties
Acrylonitrile is a colorless, flammable liquid. Its vapors may explode when exposed to an open flame. Acrylonitrile does not occur naturally. It is produced in very large amounts by several chemical industries in the United States and its requirement and demand has increased in recent years. The largest users of acrylonitrile are chemical industries that make acrylic and modacrylic fi bers, high impact acrylonitrile-butadiene-styrene (ABS) plastics. Acrylonitrile is also used in business machines, luggage, and construction material, in the manufacturing of styrene-acrylonitrile (SAN) plastics for automotive and household goods, and in packaging material. Adiponitrile is used to make nylon, dyes, drugs, and pesticides.
Uses
Acrylonitrile is used in the production of acrylic fibers, resins, and surface coating; as an intermediate in the production of pharmaceuticals and dyes; as a polymer modifier; and as a fumigant. It may occur in fire-effluent gases because of pyrolyses of polyacrylonitrile materials. Acrylonitrile was found to be released from the acrylonitrile–styrene copolymer and acrylonitrile–styrene–butadiene copolymer bottles when these bottles were filled with food-simulating solvents such as water, 4% acetic acid, 20% ethanol, and heptane and stored for 10 days to 5 months (Nakazawa et al. 1984). The release was greater with increasing temperature and was attributable to the residual acrylonitrile monomer in the polymeric materials.
Definition
ChEBI: Acrylonitrile is a nitrile that is hydrogen cyanide in which the hydrogen has been replaced by an ethenyl group. It is very toxic and irritant but is also a sensitizer. It caused both irritant and allergic contact dermatitis in a production manufacture.
Air & Water Reactions
Highly flammable. Soluble in water.
Reactivity Profile
ACRYLONITRILE produces poisonous hydrogen cyanide gas on contact with strong acids or when heated to decomposition. Reacts violently with strong oxidizing agents (dibenzoyl peroxide, di-tert-butylperoxide, bromine) [Sax, 9th ed., p. 61]. Rapidly ignites in air and forms explosive mixtures with air. Polymerizes violently in the presence of strong bases or acids. Underwent a runaway reaction culminating in an explosion on contact with a small amount of bromine or solid silver nitrate [Bretherick, 5th ed., 1995, p. 404].
Contact allergens
Acrylonitrile is a raw material used extensively in industry, mainly for acrylic and modacrylic fibers, acrylonitrile-butadiene-styrene and styrene-acrylonitrile resins, adiponitrile used in nylon’s synthesis, for nitrile rubber, and plastics. It is also used as an insecticide. This very toxic and irritant substance is also a sensitizer and caused both irritant and allergic contact dermatitis in a production manufacturer.
Potential Exposure
Acrylonitrile is used in the manufacture of synthetic fibers, polymers, acrylostyrene plastics, acrylonitrile butadiene styrene plastics, nitrile rubbers, chemicals, and adhesives. It is also used as a pesticide. In the past, this chemical was used as a room fumigant and pediculicide (an agent used to destroy lice).
Carcinogenicity
Acrylonitrile is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.
storage
Work with acrylonitrile should be conducted in a fume hood to prevent exposure by inhalation, and splash goggles and impermeable gloves should be worn at all times to prevent eye and skin contact. Acrylonitrile should be used only in areas free of ignition sources. Containers of acrylonitrile should be stored in secondary containers in the dark in areas separate from oxidizers and bases.
Shipping
UN1093 Acrylonitrile, stabilized, Hazard Class 3; Labels: 3 Flammable liquids, 6.1-Poisonous materials
Purification Methods
Wash acrylonitrile with dilute H2SO4 or dilute H3PO4, then with dilute Na2CO3 and water. Dry it with Na2SO4, CaCl2 or (better) by shaking with molecular sieves. Fractionally distil it under N2. It can be stabilised by adding 10ppm tert-butyl catechol. Immediately before use, the stabilizer can be removed by passage through a column of activated alumina (or by washing with 1% NaOH solution if traces of water are permissible in the final material), followed by distillation. Alternatively, shake it with 10% (w/v) NaOH to extract inhibitor, and then wash it in turn with 10% H2SO4, 20% Na2CO3 and distilled water. Dry for 24hours over CaCl2 and fractionally distil under N2 taking fraction boiling at 75.0-75.5oC (at 734mm). Store it with 10ppm tert-butyl catechol. Acrylonitrile is distilled off when required. [Burton et al. J Chem Soc, Faraday Trans 1 75 1050 1979, Beilstein 2 IV 1473.]
Incompatibilities
Acrylonitrile is reactive with, and must be kept away from, strong oxidizers, especially bromine. Use extreme care to keep Acrylonitrile away from strong bases, strong acids, copper, copper alloys, ammonia and amines. Contact with these chemicals can cause a chemical reaction resulting in a fire or explosion. Chemical compatibility should also be determined before Acrylonitrile comes in contact with any other chemical.
Waste Disposal
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration with provision for nitrogen oxides removal from effluent gases by scrubbers or afterburners. A chemical disposal method has also been suggested involving treatment with alcoholic NaOH; the alcohol is evaporatedand calcium hypochlorite added; after 24 hours the product is flushed to the sewer with large volumes of water. Recovery of acrylonitrile from acrylonitrile process effluents is an alternative to disposal.
Acrylonitrile Preparation Products And Raw materials
Raw materials
1of3
chevron_rightPreparation Products
1of8
chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| PAARICHEM RESOURCES LLP | +91-8104961021 +91-8104961021 | Maharashtra, India | 82 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| OCEAN TRADING CORPORATION | +91(22) 24921669 | New Delhi, India | 6211 | 58 | Inquiry |
| Scientific OEM | +91-22- 2343 7546 / 2341 3094 | New Delhi, India | 1996 | 38 | Inquiry |
| ALPHA CHEMIKA | +91-22-22061123 +91-22-66382501 | Mumbai, India | 1681 | 43 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| LOBA CHEMIE PVT.LTD. | 91-22-6663 6699 | Mumbai, India | 3077 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| PAARICHEM RESOURCES LLP | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| OCEAN TRADING CORPORATION | 58 |
| Scientific OEM | 38 |
| ALPHA CHEMIKA | 43 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| LOBA CHEMIE PVT.LTD. | 58 |
| Central Drug House(P) Ltd. | 58 |
| Triveni chemicals | 58 |
Related articles
- Acrylonitrile - a Brief Introduction
- Acrylonitrile, also known as AN or vinyl cyanide, is a man-made VOC. It is a pungent smelling, colorless flammable liquid.
- Apr 27，2022
- Uses of Acrylonitrile
- Acrylonitrile is an organic compound with the formula CH2CHCN. It is a colorless volatile liquid although commercial samples c....
- Oct 25，2021
- Acrylonitrile-Health Hazard and Toxicity
- Acrylonitrile is an organic compound with the formula CH2CHCN. It is a colorless volatile liquid, although commercial samples ....
- Sep 4，2019
107-13-1(Acrylonitrile)Related Search:
1of4
chevron_right