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Carbazole

Carbazole Structure
CAS No.
86-74-8
Chemical Name:
Carbazole
Synonyms
DIBENZOPYRROLE;9-AZAFLUORENE;Diphenylenimide;DIPHENYLENIMINE;Skf 20091;CARBAZOLE;usafek-600;USAF ek-600;'LGC' (2409);Diphenylimid
CBNumber:
CB4854492
Molecular Formula:
C12H9N
Molecular Weight:
167.21
MOL File:
86-74-8.mol
MSDS File:
SDS
Modify Date:
2024/6/25 10:02:26

Carbazole Properties

Melting point 243-246 °C (lit.)
Boiling point 355 °C (lit.)
Density 1.1
vapor pressure 400 mm Hg ( 323 °C)
refractive index 1.6192 (estimate)
Flash point 220 °C
storage temp. Store below +30°C.
solubility acetone: soluble50mg/mL
form Crystalline Powder, Flakes, or Chunks
pka 17.00±0.30(Predicted)
color Beige-yellow or beige-brownish
Water Solubility <0.1 g/100 mL at 19 ºC
Merck 14,1790
BRN 3956
Dielectric constant 1.3(Ambient)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, nitrogen oxides, potassium hydroxide.
InChIKey UJOBWOGCFQCDNV-UHFFFAOYSA-N
LogP 3.84 at 22℃ and pH7
CAS DataBase Reference 86-74-8(CAS DataBase Reference)
IARC 2B (Vol. 32, Sup 7, 71, 103) 2013
NIST Chemistry Reference Carbazole(86-74-8)
EPA Substance Registry System Carbazole (86-74-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS08
Signal word  Warning
Hazard statements  H341-H351-H413
Precautionary statements  P201-P202-P273-P280-P308+P313-P405
Hazard Codes  Xn,N,T
Risk Statements  22-36/37/38-40-50/53-63-43-23/24/25-45-67-68-51/53
Safety Statements  26-36-60-61-36/37-24/25-23-53-45-36/37/39
RIDADR  UN 2811 6.1/PG 3
WGK Germany  2
RTECS  FE3150000
10
Hazard Note  Harmful
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29339990
Toxicity LD50 orally in rats: >5 g/kg (Eagle, Carlson)
NFPA 704
1
2 0

Carbazole price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) C5132 Carbazole ≥95% (GC) 86-74-8 100G ₹3150.08 2022-06-14 Buy
Sigma-Aldrich(India) C5132 Carbazole ≥95% (GC) 86-74-8 250G ₹6235.2 2022-06-14 Buy
Sigma-Aldrich(India) PHR1564 Carprofen Related Compound A Pharmaceutical Secondary Standard; Certified Reference Material 86-74-8 200MG ₹15620.48 2022-06-14 Buy
Sigma-Aldrich(India) C5132 Carbazole ≥95% (GC) 86-74-8 500G ₹9547.65 2022-06-14 Buy
Sigma-Aldrich(India) 8.20255 Carbazole for synthesis 86-74-8 5G ₹3600 2022-06-14 Buy
Product number Packaging Price Buy
C5132 100G ₹3150.08 Buy
C5132 250G ₹6235.2 Buy
PHR1564 200MG ₹15620.48 Buy
C5132 500G ₹9547.65 Buy
8.20255 5G ₹3600 Buy

Carbazole Chemical Properties,Uses,Production

Chemical Properties

white crystals or light brown powder

Uses

Carbazole and its derivatives are widely used as an intermediate in synthesis of pharmaceuticals, agrochemicals, dyes, pigments and other organic compounds.?carbazole is also used in luminescence chemistry as a photosensitizing and additional charge transport material. Carbazole structure is a motif in pharmaceuticals such as carvedilol used to treat high blood pressure and to prevent cardiac arrhythmias and angina.

Definition

carbazole: A white crystalline compoundfound with anthracene,C12H9N; m.p. 238°C; b.p. 335°C. It isused in the manufacture of dyestuffs.

General Description

White crystals, plates, leaflets or light tan powder. Sublimes readily. Exhibits strong fluorescence and long phosphorescence on exposure to ultraviolet light.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Carbazole is an extremely weak base. Carbazole is incompatible with strong oxidizing agents. Carbazole reacts with nitrogen oxides. Potassium hydroxide fusion yields a salt.

Hazard

Possible carcinogen.

Fire Hazard

Flash point data for Carbazole are not available; however, Carbazole is probably combustible.

Safety Profile

intraperitoneal route. A flammable liquid.

Purification Methods

Dissolve carbazole (60g) in conc H2SO4 (300mL), extract with three 200mL portions of *benzene, then stir this into 1600mL of an ice-water mixture. The precipitate is filtered off, washed with a little water, dried, recrystallised from *benzene and then from pyridine/*benzene [Feldman et al. J Am Chem Soc 73 4341 1951]. It has also been recrystallised from EtOH or toluene, sublimed in vacuum, zone-refined, and purified by TLC. [UV: Armarego in Physical Methods in Heterocyclic Chemistry (Ed Katritzky, Academic Press) Vol III 158 1971, Beilstein 20/8 V 9.]

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