Styralyl acetate
- CAS No.
- 93-92-5
- Chemical Name:
- Styralyl acetate
- Synonyms
- STYRALLYL ACETATE;Gardenol;1-PHENYLETHYL ACETATE;1-Phenylethylacetat;α-Methylbenzyl acetate;ALPHA-METHYLBENZYL ACETATE;METHYL PHENYL CARBINYL ACETATE;FEMA 2684;gardeniolii;Gardeniol ii
- CBNumber:
- CB8335113
- Molecular Formula:
- C10H12O2
- Molecular Weight:
- 164.2
- MOL File:
- 93-92-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/26 17:49:17
| Melting point | -60°C |
|---|---|
| Boiling point | 94-95 °C12 mm Hg(lit.) |
| Density | 1.028 g/mL at 25 °C(lit.) |
| vapor pressure | 5.5Pa at 20℃ |
| FEMA | 2684 | ALPHA-METHYLBENZYL ACETATE |
| refractive index |
n |
| Flash point | 196 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Almost insoluble in water, soluble in alcohol and oils. |
| form | liquid |
| Specific Gravity | 1.04 |
| color | Colorless |
| Odor | at 10.00 % in dipropylene glycol. green leafy gardenia rhubarb musty |
| Odor Type | green |
| Water Solubility | 1.27g/L at 20℃ |
| JECFA Number | 801 |
| LogP | 2.5 |
| CAS DataBase Reference | 93-92-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenemethanol, «alpha»-methyl-, acetate(93-92-5) |
| EPA Substance Registry System | Benzenemethanol, .alpha.-methyl-, acetate (93-92-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H227-H315-H319-H335 | |||||||||
| Precautionary statements | P305+P351+P338 | |||||||||
| Safety Statements | 24/25 | |||||||||
| RIDADR | NA 1993 / PGIII | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | DO9410000 | |||||||||
| Autoignition Temperature | 450 °C | |||||||||
| HS Code | 2915 39 00 | |||||||||
| Toxicity | LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg | |||||||||
| NFPA 704 |
|
Styralyl acetate price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W268402 | Methyl phenylcarbinyl acetate ≥98%, FCC, FG | 93-92-5 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W268402 | Methyl phenylcarbinyl acetate ≥98%, FCC, FG | 93-92-5 | 1KG | ₹7447.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W268402 | Methyl phenylcarbinyl acetate ≥98%, FCC, FG | 93-92-5 | 5KG | ₹19798.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W268402 | Methyl phenylcarbinyl acetate ≥98%, FCC, FG | 93-92-5 | 25KG | ₹63596.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.43785 | 1-Phenylethyl acetate for synthesis | 93-92-5 | 100ML | ₹4510 | 2022-06-14 | Buy |
Styralyl acetate Chemical Properties,Uses,Production
Description
α-Methylbenzyl acetate has an intensive green odor suggestive of gardenia with a bitter, acrid taste, interesting on dilution. May be prepared by acetylation of methyl phenyl carbinol; from benzaldehyde by reacting with magnesium methyl bromide and subsequent acetylation; from 1-bromoethylbenzene and silver acetate in acetic acid.
Chemical Properties
CLEAR COLOURLESS TO PALE YELLOWISH LIQUID
Occurrence
Reported found in gardenia flower oil and avocado.
Uses
Styralyl Acetate is a freshening compound with Alkoxylated Phenols.
Styralyl acetate finds extensive use in flavor compositions, particularly the "sharp"-fruity
types, Pineapple, Apricot, Gooseberry, Apple,
but also in Plum, Peach and many berry or
fruit complexes.
The concentration is about 1 to 30 ppm in
the finished product.
Preparation
By acetylation of methyl phenyl carbinol; from benzaldehyde by reacting with magnesium methyl bromide and subse quent acetylation; from 1-bromoethylbenzene and silver acetate in acetic acid.
Metabolism
Although no published data exist on the metabolism of methylphenylcarbinyl acetate, it is likely that hydrolysis to the carbinol and acetic acid is the initial step. Williams (1959) reports studies in which 50% of a dose of (±)-methylphenylcarbinol given to rabbits was excreted as the glucuronide in the urine within 24 hr. There was some evidence of oxidation and demethylation, as mandelic and hippuric acids were found in the urine. Previously, El Masry, Smith
Styralyl acetate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Jayshree Aromatics Pvt.Ltd. | +91-9925031256 +91-9925031256 | Gujarat, India | 89 | 58 | Inquiry |
| HJ AROCHEM | +91-8690768060 +91-9724420086 | Ahmedabad, India | 171 | 58 | Inquiry |
| KDAC Chem Pvt Ltd | +91-9099900331 +91-8866465777 | Maharashtra, India | 5 | 58 | Inquiry |
| Eternis Fine Chemicals Ltd | +91-2266513400 +91-2266513400 | Maharashtra, India | 9 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| Juhi Essence Sugandhi | 09958833263 | Uttar Pradesh, India | 60 | 58 | Inquiry |
| M/S Lucknow Aromatics Private Limited | 08069033835Ext 464 | Uttar Pradesh, India | 15 | 58 | Inquiry |
| Planters International Company | 09844020673 | Karnataka, India | 55 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Jayshree Aromatics Pvt.Ltd. | 58 |
| HJ AROCHEM | 58 |
| KDAC Chem Pvt Ltd | 58 |
| Eternis Fine Chemicals Ltd | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |
| Central Drug House(P) Ltd. | 58 |
| Juhi Essence Sugandhi | 58 |
| M/S Lucknow Aromatics Private Limited | 58 |
| Planters International Company | 58 |
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