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4-CHLORO-O-TOLUIDINE HYDROCHLORIDE

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE Structure
CAS No.
3165-93-3
Chemical Name:
4-CHLORO-O-TOLUIDINE HYDROCHLORIDE
Synonyms
FAST RED;cga-72647;devolredk;devolredtr;nci-c02368;CI NO 37085;ci37085[qr];kromongreenb;devolredk[qr];daitoredsalttr
CBNumber:
CB8347938
Molecular Formula:
C7H9Cl2N
Molecular Weight:
178.06
MOL File:
3165-93-3.mol
Modify Date:
2023/5/15 10:44:01

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE Properties

solubility DMSO (Slightly), Methanol (Slightly)
Colour Index 37085
form Solid
color Off-White
Stability Hygroscopic
EPA Substance Registry System 4-Chloro-o-toluidine hydrochloride (3165-93-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H340-H350-H370-H372-H410
Precautionary statements  P201-P202-P260-P264-P270-P273-P280-P301+P312+P330-P307+P311-P391-P405-P501
Hazard Codes  T,N
Risk Statements  45-23/24/25-50/53-68
Safety Statements  53-45-60-61
RIDADR  1579
RTECS  XU5250000
HazardClass  6.1(b)
PackingGroup  III

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE Chemical Properties,Uses,Production

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Uses

p-Chloro-o-toluidine and its hydrochloride salt are used in manufacturing azo dyes for cotton, silk, acetate, and nylon and as intermediates in the production of the dyes C.I. 12800, pigment red 7, and pigment yellow 49 (IARC 1990, 2000). p-Chloro-o-toluidine has also been used since the 1960s in the manufacture of the pesticide (insecticide and acaricide) chlordimeform. It is believed that chlordimeformis no longer produced or used worldwide (IARC 1990).

General Description

A white crystalline solid. Toxic by skin absorption and inhalation (dust).

Air & Water Reactions

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE may be sensitive to prolonged exposure to air and light. Water soluble.

Reactivity Profile

Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. .

Hazard

Toxic by ingestion, inhalation, and skin absorption.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx and Cl-. See also other chloro toluidine entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Carcinogenicity

p-Chloro-o-toluidine and its hydrochloride salt are reasonably anticipated to be human carcinogens based on limited evidence of carcinogenicity from studies in humans and evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 34)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Jaffs Dyechem Private Limited +91-9825035135 +91-7925392314 Gujarat, India 309 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Amritlal Chemaux Pvt Ltd. 08048950083 Mumbai, India 54 58 Inquiry
Jaffs Dyechem Private Limited 91-79-25392314 Gujarat, India 53 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21676 55 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
9ding chemical ( Shanghai) Limited 021-021-52271985 17721149837 China 19806 60 Inquiry
Yantai Zhengxin New Material Technology Co. LTD 15065715832; 13854547682 China 3601 58 Inquiry
Shandong Jiuyue Biological Technology Co., LTD 15553348166 China 3470 58 Inquiry
4-CHLORO-2-METHYLANILINE HYDROCHLORIDE 4-CHLORO-O-TOLUIDINE HYDROCHLORIDE 5-CHLORO-2-AMINOTOLUENE DIAZONIUM CHLORIDE P-CHLORO-O-TOLUIDINE DIAZONIUMHLORIDE 2-AMINO-5-CHLOROTOLUENE HYDROCHLORIDE FAST RED FAST RED TR SALT CI NO 37085 2-amino-5-chlorotoluenehydrochloride[qr] 2-methyl-4-chloroanilinehydrochloride 2-methyl-4-chloroanilinehydrochloride[qr] 4-chloro-2-methylanilinehydrochloride[qr] 4-chloro-2-methylbenzenaminehydrochloride 4-chloro-2-methylbenzenaminehydrochloride[qr] 4-chloro-2-methyl-benzenaminhydrochloride 4-chloro-2-methyl-benzenaminhydrochloride[qr] 4-chloro-2-toluidinehydrochloride 4-chloro-2-toluidinehydrochloride[qr] 4-chloro-6-methylanilinehydrochloride 4-chloro-6-methylanilinehydrochloride[qr] 4-chloro-o-toluidinhydrochloride 4-chloro-o-toluidinhydrochloride[qr] 4-chloro-o-toluidiniumchloride 5-chloro-2-aminotoluenehydrochloride 5-chloro-2-aminotoluenehydrochloride[qr] amartholfastredtrbase[qr] amartholfastredtrsalt[qr] asymmetricmeta-chloro-ortho-toluidinehydrochloride[qr] azanilredsalttrd azanilredsalttrd[qr] azoenefastredtrsalt azoenefastredtrsalt[qr] azogenefastredtr azogenefastredtr[qr] azoicdiazocomponent11base azoicdiazocomponent11base[qr] benzenamine,-chloro-2-methyl-,hydrochloride brentaminefastredtrsalt brentaminefastredtrsalt[qr] c.i.azoicdiazocomponent11 cga-72647 chlorhydratede4-chloroorthotoluidine chlorhydratede4-chloroorthotoluidine(french)[qr] chlorhydratedechloro-4o-toluidine[qr] ci37085[qr] ciazoicdiazocomponent11[qr] clorhidratode4-cloro-o-toluidine[qr] daitoredsalttr daitoredsalttr[qr] devolredk devolredk[qr] devolredtasalt[qr] devolredtr devolredtr[qr] diazofastredtr diazofastredtr[qr] diazofastredtra diazofastredtra[qr]