(-)-CAMPHENE

(-)-CAMPHENE Structure
CAS No.
5794-04-7
Chemical Name:
(-)-CAMPHENE
Synonyms
(1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE;2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane;Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-;[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane;L-Camphene;(-)-Camphene;(-)-Camphene,95%;(+/-)-Camphene, sum of camphene + fenchene;(1S,4R)-2,2-Dimethyl-3-methylenenorbornane;2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
CBNumber:
CB8468970
Molecular Formula:
C10H16
Molecular Weight:
136.23
MOL File:
5794-04-7.mol
Modify Date:
2023/5/25 18:01:20

(-)-CAMPHENE Properties

Melting point 36-38 °C(lit.)
Boiling point 157.5-158.5 °C(lit.)
Density 0.84 g/mL at 25 °C(lit.)
refractive index 1.4562 (estimate)
Flash point 98 °F
solubility Benzene (Slightly), Chloroform (Sparingly)
form Solid
color White to Off-White Waxy
Odor at 10.00 % in dipropylene glycol. fresh woody fir terpene
Odor Type woody
Merck 14,1730
Stability Volatile
LogP 4.239 (est)
EPA Substance Registry System Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS09
Signal word  Warning
Hazard statements  H226-H319-H410
Precautionary statements  P273-P391-P501-P264-P280-P305+P351+P338-P337+P313P
Hazard Codes  F
Risk Statements  11-10
Safety Statements  16-33-29
RIDADR  UN 1325 4.1/PG 2
WGK Germany  3
RTECS  EX1055000
HazardClass  4.1
PackingGroup  III
NFPA 704
3
0 1

(-)-CAMPHENE Chemical Properties,Uses,Production

Definition

ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.

Purification Methods

Purify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]

(-)-CAMPHENE Preparation Products And Raw materials

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2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan L-Camphene (1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane (1S,4R)-2,2-Dimethyl-3-methylenenorbornane ()-Camphene,(1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane (+/-)-Camphene, sum of camphene + fenchene (-)-Camphene,95% (-)-Camphene [1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE 2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane (-)-CaMphene, tech. 80% (suM of caMphene + fenchene) 5794-04-7 Alkenes Asymmetric Synthesis Chiral Building Blocks Organic Building Blocks