Camphene
- CAS No.
- 79-92-5
- Chemical Name:
- Camphene
- Synonyms
- CAMPHENE 90;CAMPHENE 46;D,L-CAMPHENE;Camphene(DOT);Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-;FEMA 2229;2,2-Dimethyl-3-methylene-bicyclo[2.2.1]heptane;NA 9011;CAMPHENE;78.0%(GC)
- CBNumber:
- CB9303627
- Molecular Formula:
- C10H16
- Molecular Weight:
- 136.23
- MOL File:
- 79-92-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/14 15:18:30
| Melting point | 48-52 °C (lit.) |
|---|---|
| Boiling point | 159-160 °C (lit.) |
| Density | 0.85 g/mL at 25 °C (lit.) |
| vapor pressure | 3.99 hPa (20 °C) |
| refractive index | 1.4551 |
| FEMA | 2229 | CAMPHENE |
| Flash point | 94 °F |
| storage temp. | 2-8°C |
| solubility | 0.0042g/l |
| form | Crystalline Low Melting Solid |
| color | White |
| Specific Gravity | 0.85 |
| PH | 5.5 (H2O, 22℃)(saturated aqueous solution) |
| Odor | at 10.00 % in dipropylene glycol. woody herbal fir needle camphor terpenic |
| Odor Type | woody |
| Odor Threshold | 0.88ppm |
| Water Solubility | practically insoluble |
| Merck | 14,1730 |
| JECFA Number | 1323 |
| Dielectric constant | 2.7（20℃） |
| InChIKey | CRPUJAZIXJMDBK-DTWKUNHWSA-N |
| LogP | 4.22 at 20℃ |
| CAS DataBase Reference | 79-92-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Camphene(79-92-5) |
| EPA Substance Registry System | Camphene (79-92-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H228-H319-H410 | |||||||||
| Precautionary statements | P210-P240-P241-P264-P273-P305+P351+P338 | |||||||||
| Hazard Codes | F,N | |||||||||
| Risk Statements | 11-10-50/53-36 | |||||||||
| Safety Statements | 16-33-61-60-26 | |||||||||
| RIDADR | UN 1325 4.1/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | EX1055000 | |||||||||
| Autoignition Temperature | 265 °C | |||||||||
| HS Code | 2902 19 00 | |||||||||
| HazardClass | 4.1 | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
Camphene price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.20254 | (+)-Camphene for synthesis | 79-92-5 | 100G | ₹3510 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | CRM40378 | Camphene solution certified reference material, 2000?μg/mL in methanol, ampule of 1?mL | 79-92-5 | 1ML | ₹9522.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.20254 | (+)-Camphene for synthesis | 79-92-5 | 1KG | ₹10380 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 456055 | Camphene 95% | 79-92-5 | 25G | ₹4750 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 456055 | Camphene 95% | 79-92-5 | 1KG | ₹11670 | 2022-06-14 | Buy |
Camphene Chemical Properties,Uses,Production
Chemical Properties
Camphene is a colorless to white crystalline solid, Camphor, or turpentine odor. It may be shipped as a liquid. Freezing/Melting point 5 50C.
Occurrence
Reported found in carrot, dill, fennel, marjoram, nutmeg, parsley, pepper, tarragon and thyme.
Uses
Camphene is used in the preparation of fragrances and as a food additive for flavoring.
Preparation
From pinene by catalytic isomerization or from bornyl chloride by heating with alkali in the presence of abietenesulfonic acid.
Definition
ChEBI: A monoterpene with a bicyclic skeleton that is bicyclo[2.2.1]heptane substituted by geminal methyl groups at position 2 and a methylidene group at position 3. It is a widespread natural product found in many essential oils.
General Description
A colorless to white crystalline solid with an insipid camphor-like odor. Dust and crystals are irritants to the eyes, nose and throat. Emits flammable vapors when heated. Emits acrid smoke and irritating fumes at high temperature. Used for the manufacture of synthetic camphor.
Reactivity Profile
Camphene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.
Hazard
Toxic by ingestion.
Health Hazard
Inhalation causes irritation of nose and throat. Contact with eyes or skin causes irritation.
Pharmacology
Oral administration of camphene (260 mmols/kg) to rats increased bile flow by 50% 4 hr after administration (M?rsdorf, 1966). Development of atheromatosis of the aorta in rabbits fed 1 g cholesterol/day for 3 months was considerably inhibited by simultaneous administration of a mixture of terpenes including camphene, injected sc in a dose of 1 ml every other day for 6 wk and then given orally in doses of 2 ml/day (Benk?, Macher, Szarvas & Tiboldi, 1961). The effect of 1 g cholesterol/day for 8 wk in the diet of rabbits in increasing the number and volume of mast cells in the aortic adventitia and increasing the total lipid content of the aortic wall was slightly enhanced by the simultaneous addition of 11 g camphene/day (Lesznyak, Benko, Szabo & Muller, 1972). This camphene treatment also decreased the lipid accumulation in the liver, but had no effect on the cholesterol-induced atheromatosis of the aorta (Benko, Szabo, Muller & Lesznyak, 1972).
Anticancer Research
This was tested against melanoma cells in a syngeneic model, and there was promisingantitumor activity (Ma et al. 2016).
Safety Profile
Mutation data reported. Combustible; yields flammable vapors when heated and can react with oxidizing materials. To fight fire, use water spray, foam, fog, CO2. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential Exposure
Camphene is used to manufacture synthetic camphor; for making moth-proofing and in the cosmetics, perfume, and food flavoring industries.
Shipping
UN1325 Flammable solids, organic, n.o.s., Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN2319 Terpene hydrocarbons, n.o.s., Hazard Class: 3; Labels: 3- Flammable liquid
Incompatibilities
Forms explosive mixture with air. Emulsions in xylene may violently decompose on contact with iron or aluminum above 70C. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause exothermic reaction, releasing flammable hydrogen gas
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
Camphene Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| UNILOSA INTERNATINAL PRIVATE LIMITED | +91-9999069917 +91-9999069917 | New Delhi, India | 152 | 58 | Inquiry |
| Ghaziabad Aromatics | +91-9811327736 +91-9654012346 | Uttar Pradesh, India | 80 | 58 | Inquiry |
| Indenta Chemicals (India) Pvt Ltd | +91-2226849600 +91-9326627752 | Maharashtra, India | 48 | 58 | Inquiry |
| Swati Menthol and Allied Chemicals Ltd | +91-9837848873 +91-9837848871 | Uttar Pradesh, India | 49 | 58 | Inquiry |
| Himachal Terepene Products Pvt Ltd | +91-9805022389 +91-9816380001 | Himachal Pradesh, India | 16 | 58 | Inquiry |
| Aamirav Ingredients And Specialties Pvt Ltd | +91-2224980102 +91-9820077171 | Maharashtra, India | 138 | 58 | Inquiry |
| Gyan Flavours Export Pvt. Ltd. | 91-11-22814681 | Delhi, India | 19 | 58 | Inquiry |
| Dujodwala Products Limited | +91 22 22824089 | Mumbai, India | 2 | 58 | Inquiry |
| Ghaziabad Aromatics | 91-120-4134410 | Delhi, India | 17 | 58 | Inquiry |
| Aamirav Ingredients & Specialties Pvt. Ltd. | 91-22-24980102 | Maharashtra, India | 63 | 58 | Inquiry |
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