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2-Bromotoluene

2-Bromotoluene Structure
CAS No.
95-46-5
Chemical Name:
2-Bromotoluene
Synonyms
1-BROMO-2-METHYLBENZENE;a13-26648;2-Bromtoluol;o-bromo-toluen;2-BROMOTOLUENE;2-bromo-toluen;2-tolylbromide;O-BROMOTOLUENE;2-Tolyl bromide;O-TOLYL BROMIDE
CBNumber:
CB8854692
Molecular Formula:
C7H7Br
Molecular Weight:
171.03
MOL File:
95-46-5.mol
Modify Date:
2023/12/25 17:47:29

2-Bromotoluene Properties

Melting point -27 °C (lit.)
Boiling point 58-60 °C/10 mmHg (lit.)
Density 1.422 g/mL at 25 °C (lit.)
refractive index n20/D 1.555(lit.)
Flash point 174 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.422
color Clear colorless to light yellow
Water Solubility <0.1 g/100 mL at 15 ºC
Merck 14,1439
BRN 1904176
Dielectric constant 4.2800000000000002
Stability Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 95-46-5(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1-bromo-2-methyl-(95-46-5)
EPA Substance Registry System o-Bromotoluene (95-46-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H411
Precautionary statements  P264-P270-P273-P301+P312-P391-P501
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  36/37/39-37/39-26
WGK Germany  3
RTECS  XS7965500
Hazard Note  Harmful/Irritant
TSCA  Yes
PackingGroup  III
HS Code  29036990
NFPA 704
2
2 0

2-Bromotoluene price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) B82006 2-Bromotoluene 99% 95-46-5 25G ₹2099.45 2022-06-14 Buy
Sigma-Aldrich(India) B82006 2-Bromotoluene 99% 95-46-5 100G ₹5095.65 2022-06-14 Buy
ALFA India ALF-A12315-36 2-Bromotoluene, 99% 95-46-5 500g ₹13302 2022-05-26 Buy
ALFA India ALF-A12315-22 2-Bromotoluene, 99% 95-46-5 100g ₹5217 2022-05-26 Buy
ALFA India ALF-A12315-14 2-Bromotoluene, 99% 95-46-5 25g ₹2251 2022-05-26 Buy
Product number Packaging Price Buy
B82006 25G ₹2099.45 Buy
B82006 100G ₹5095.65 Buy
ALF-A12315-36 500g ₹13302 Buy
ALF-A12315-22 100g ₹5217 Buy
ALF-A12315-14 25g ₹2251 Buy

2-Bromotoluene Chemical Properties,Uses,Production

Chemical Properties

liquid

Uses

2-Bromotoluene was used in the synthesis of (±)-isocomene. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported. 2-Bromotoluene is used in manufacturing pharmaceuticals (especially for nonsteroidal antiinflammatory drugs; Meclofenamic acid, Mefenamic acid) and other organic compounds

General Description

Clear colorless to pale beige liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Bromotoluene reacts with strong oxidizing agents.

Fire Hazard

2-Bromotoluene is combustible.

Purification Methods

Fractionally distil it through an efficient column. It can be separated from its isomers by gas chromatography on a column of “Sil-o-cel” firebrick (30-40mesh, 80 parts) coated with 5% (20 parts) of ICI E301 con rubber with N2 carrier gas at 170o/atm and 100mL/minute and using a conductivity cell detector. [Cowley et al. J Chem Soc 1801 1959, Beilstein 5 H 304, 5 I 153, 5 II 234 5 III 704, 5 IV 825.]

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1-Brom-2-methylbenzol 1-bromo-2-methyl-benzen 1-Methyl-2-bromobenzene a13-26648 Benzene,1-bromo-2-methyl- o-bromo-toluen o-Methylbromobenzene Toluene, o-bromo- toluene,2-bromo- Toluene,o-bromo- 2-BROMO-1-METHYLBENZENE 2-BROMOTOLUENE 2-BROMOTOLUENE / 1-BROMO-2-METHYLBENZENE 2-bromo-toluen 2-Bromtoluol 2-Methylphenylbromide 2-Tolyl bromide 2-tolylbromide 2-Methylbromobenzene o-methylphenyl bromide ORTHO BROMO TOLUENE O-TOLYL BROMIDE o-Bromomethylbenzene O-BROMOTOLUENE Adjacent broMine toluene 3-Bromotoluene,>99% 2-Bromotoluene,99% 1-Bromo-2-methylbenzene, 2-Methylbromobenzene 2-BroMotoluene, 99% 25ML 2-Bromo-1-methyL 2-Bromotoluene > 2-Bromotoluene ISO 9001:2015 REACH 2-BROMOTOLUENE For Synthesis 1-BROMO-2-METHYLBENZENE 95-46-5 CH3C6H4Br ARYL HALIDE Halogenated Hydrocarbons Organic Building Blocks C7 Aryl Building Blocks alkyl bromide Building Blocks Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Intermediates Organics Halogen toluene Miscellaneous Bromine Compounds Aryl C7 Halogenated Hydrocarbons