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Dimethyl 2,6-Pyridinedicarboxylate

Dimethyl 2,6-Pyridinedicarboxylate Structure
CAS No.
5453-67-8
Chemical Name:
Dimethyl 2,6-Pyridinedicarboxylate
Synonyms
DIMETHYL PYRIDINE-2,6-DICARBOXYLATE;20g;dimethyl pyridine-2,6-carboxylate;Pyridine-2,6-dicarboxylic acid dimethyl ester;AKOS 90661;20G/100G/1KG;RARECHEM AL BF 0203;Dimethyl2,6-pyridin;DIMETHYL DIPICOLINATE;pyridine-2,6-carboxyL
CBNumber:
CB9118465
Molecular Formula:
C9H9NO4
Molecular Weight:
195.17
MOL File:
5453-67-8.mol
MSDS File:
SDS
Modify Date:
2023/10/28 21:33:43

Dimethyl 2,6-Pyridinedicarboxylate Properties

Melting point 121-125 °C(lit.)
Boiling point 100 °C(Press: 0.005 Torr)
Density 1.231±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform
form Solid
pka -0.46±0.10(Predicted)
color Off-White
Water Solubility Soluble in water(14 g/L) (25°C). Soluble in chloroform.
InChI InChI=1S/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3
InChIKey SNQQJEJPJMXYTR-UHFFFAOYSA-N
SMILES C1(C(OC)=O)=NC(C(OC)=O)=CC=C1
CAS DataBase Reference 5453-67-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H315-H318-H335
Precautionary statements  P261-P280-P305+P351+P338
Hazard Codes  Xi
Risk Statements  37/38-41
Safety Statements  26-39
WGK Germany  3
HS Code  29333990
NFPA 704
1
2 0

Dimethyl 2,6-Pyridinedicarboxylate price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 379336 Dimethyl 2,6-pyridinedicarboxylate 99% 5453-67-8 10G ₹7176.98 2022-06-14 Buy
Sigma-Aldrich(India) 379336 Dimethyl 2,6-pyridinedicarboxylate 99% 5453-67-8 50G ₹18673.13 2022-06-14 Buy
TCI Chemicals (India) P1444 Dimethyl 2,6-Pyridinedicarboxylate min. 98.0 % 5453-67-8 5G ₹2200 2022-05-26 Buy
TCI Chemicals (India) P1444 Dimethyl 2,6-Pyridinedicarboxylate min. 98.0 % 5453-67-8 25G ₹7500 2022-05-26 Buy
Product number Packaging Price Buy
379336 10G ₹7176.98 Buy
379336 50G ₹18673.13 Buy
P1444 5G ₹2200 Buy
P1444 25G ₹7500 Buy

Dimethyl 2,6-Pyridinedicarboxylate Chemical Properties,Uses,Production

Chemical Properties

Off-White Solid

Uses

Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:

  • ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivatives
  • N,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base
  • 1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione

Application

Dimethyl 2,6-pyridinedicarboxylate could be used as a starting material to synthesize four pyridine-bridged bis pyrazole ligands by Claisen condensation[1]. These ligands could be further treated with UCl4 to yield the corresponding novel mononuclear uranium(IV) complexes [UIV(R′′′2L)(Cl)4].    

General Description

The standard molar enthalpy of formation for dimethyl 2,6-pyridinedicarboxylate (dimethylpyridine-2,6-dicarboxylate) has been calculated from the standard molar enthalpy of combustion, which was measured by a static bomb calorimeter.

storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

References

[1] Korzekwa, Jana , et al. "Synthesis and characterization of uranium(IV) tetrachloro complexes in bis-pyrazolylpyridine ligand environments." Dalton Transactions (2017):10.1039.C7DT02947K.

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RARECHEM AL BF 0203 2,6-PYRIDINEDICARBOXYLIC ACID DIMETHYL ESTER DIPICOLINIC ACID DIMETHYL ESTER DIMETHYL 2,6-PYRIDINEDICARBOXYLATE DIMETHYL DIPICOLINATE AKOS 90661 2,6-diMethyl pyridine-2,6-dicarboxylate 20G/100G/1KG Dimethyl Dipicolinate Dipicolinic Acid Dimethyl Ester 2,6-Pyridinedicarboxylic Acid Dimethyl Ester DiMethyl 2,6-pyridinedicarbox Dimethylpyridine-2,6-dicarboxylate,98% Dimethyl 2,6-pyridinedicarboxylate 99% Dimethyl 2,6-pyridinecarboxylate pyridine-2,6-carboxyL 2,6-pyridinedicarboxylate Dimethyl2,6-pyridin Dimethyl2,6-Pyridinedicarboxylate> 2,6-Pyridinedicarboxylic acid, 2,6-dimethyl ester DIMETHYL 2,6-PYRIDINEDICARBOXYLATE ISO 9001:2015 REACH 2,6-Pyridine Dicarboxylic Acid Methyl Ester dimethyl pyridine-2,6-carboxylate DIMETHYL PYRIDINE-2,6-DICARBOXYLATE Pyridine-2,6-dicarboxylic acid dimethyl ester 20g 5453-67-8 5458-67-8 Heterocyclic Building Blocks Pyridines Building Blocks C9 to C46 Heterocycle-Pyridine series Building Blocks C8 to C9 Chemical Synthesis Heterocyclic Building Blocks C9 to C46 Heterocyclic Building Blocks Aromatics Heterocycles blocks Carboxes Pyridines Heterocyclic Compounds