4H-Dibenzo(de,g)quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-6 -methyl-, (S)-
- CAS No.
- 2169-44-0
- Chemical Name:
- 4H-Dibenzo(de,g)quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-6 -methyl-, (S)-
- Synonyms
- Rogersine;NSC 247564;NSC 247506;Lauroscholtzine;Methyllaurotetanine;Boldine 2-methyl ether;(+)-N-Methyllaurotetamine;(6aS)-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]quinolin-9-ol;(+)-6-Methyl-1,2,10-trimethoxy-5,6,6aα,7-tetrahydro-4H-dibenzo[de,g]quinoline-9-ol;(6aS)-1,2,10-trimethoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-9-ol
- CBNumber:
- CB91243115
- Molecular Formula:
- C20H23NO4
- Molecular Weight:
- 341.4
- MOL File:
- 2169-44-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 102.5°C |
|---|---|
| Boiling point | 477.03°C (rough estimate) |
| Density | 1.2064 (rough estimate) |
| refractive index | 1.5614 (estimate) |
| solubility | Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc. |
| form | Powder |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H320 |
| Precautionary statements | P264-P337+P313-P305+P351+P338 |
4H-Dibenzo(de,g)quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-6 -methyl-, (S)- Chemical Properties,Uses,Production
Description
This alkaloid, identified as the N-methyl derivative of laurotetanine (q. v.), has
been isolated from Escholtzia californica Cham., Phylica fengerialla and P.
rogersii Pillans. The base is known in two modifications; as an amorphous
powder and a colourless crystals from MeOH containing 0.5 mole of solvent,
identical with rogersine (q.v.). The alkaloid has [α]D + 1110 (c 0.86, MeOH) and
the ultraviolet spectrum in EtOH has absorption maxima at 219, 282 and
304 rn[J.; while that in alkaline solution (0.05 N/NaOH) has absorption maxima
at 223 and 329 mil.
The alkaloid yields a crystalline hydriodide, m.p. 245°C; the methiodide,
m.p. 199-2000 C and the Q-ethyl (-)-tartrate, m.p. 206-7°C (dec.) giving a
methiodide, m.p. 213° C.
References
Arndt, Baarschers., J. Chern. Soc., 2244 (1964)
Manske, Shin., Can. J. Chern., 43,2180 (1965)
Baarschers, Arndt., Tetrahedron, 21,2155 (1965)
Pachler, Arndt, Baarschers., ibid, 21,2159 (1965)
4H-Dibenzo(de,g)quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-6 -methyl-, (S)- Preparation Products And Raw materials
Raw materials
Preparation Products
4H-Dibenzo(de,g)quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-6 -methyl-, (S)- Suppliers
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