ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Esters >Carboxylic Acid Esters >Diethyl allylmalonate
Diethyl allylmalonate
- CAS No.
- 2049-80-1
- Chemical Name:
- Diethyl allylmalonate
- Synonyms
- NSC 8777;Diethyl allyl;ETHYL ALLYLMALONATE;ALLYLDIETHYLMALONATE;DIETHYL ALLYLMALONATE;DIETHYL 2-ALLYLMALONATE;Diethyl allylmalonate,97%;Allylmalonic acid diethyl;Diethyl Allylmalonate >Mono-allyldiethyl malonate
- CBNumber:
- CB9177941
- Molecular Formula:
- C10H16O4
- Molecular Weight:
- 200.23
- MOL File:
- 2049-80-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/1/29 17:42:43
| Boiling point | 222-223 °C(lit.) |
|---|---|
| Density | 1.015 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 160 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| pka | 12.63±0.46(Predicted) |
| color | Clear colorless to slightly yellow |
| Water Solubility | Not miscible or difficult to mix with water. |
| BRN | 1709466 |
| LogP | 1.990 (est) |
| CAS DataBase Reference | 2049-80-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Propanedioic acid, 2-propenyl-, diethyl ester(2049-80-1) |
| EPA Substance Registry System | Propanedioic acid, 2-propenyl-, diethyl ester (2049-80-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H335-H227-H315-H319 | |||||||||
| Precautionary statements | P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| RIDADR | NA 1993 / PGIII | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29171990 | |||||||||
| NFPA 704 |
|
Diethyl allylmalonate price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 446114 | Diethyl allylmalonate 95% | 2049-80-1 | 25ML | ₹3593.9 | 2022-06-14 | Buy |
| ALFA India | ALF-L02286-22 | Diethyl allylmalonate, 96% | 2049-80-1 | 100g | ₹7046 | 2022-05-26 | Buy |
| TCI Chemicals (India) | A0231 | Diethyl Allylmalonate min. 98.0 % | 2049-80-1 | 25G | ₹3900 | 2022-05-26 | Buy |
| ALFA India | ALF-L02286-14 | Diethyl allylmalonate, 96% | 2049-80-1 | 25g | ₹4339 | 2022-05-26 | Buy |
| TCI Chemicals (India) | A0231 | Diethyl Allylmalonate min. 98.0 % | 2049-80-1 | 500G | ₹52000 | 2022-05-26 | Buy |
Diethyl allylmalonate Chemical Properties,Uses,Production
Chemical Properties
clear colorless to slightly yellow liquid
Uses
Diethyl allylmalonate is an important intermediates in syntheses of vitamins B1 and B6, barbiturates, non-steroidal anti-inflammatory agents, other numerous pharmaceuticals, agrochemicals and flavors and fragrances compounds.
Preparation
Diethyl allyl malonate is obtained by reacting diethyl malonate with allyl bromide.
Under nitrogen atmosphere, to a 500 mL three-neck round bottom flask was added diethyl malonate (20 g), anhydrous potassium carbonate (43 g) and anhydrous CH3CN (200 mL). The reaction mixture was stirred at room temperature for 10 minutes, then allyl bromide (23 g) was slowly added to the reaction mixture at room temperature. The reaction mixture was heated to 80°C for 24 hours. The reaction mixture was cooled to room temperature and filtered through a bed of celite. The celite bed was washed with acetonitrile (100 mL) and the combined filtrates were concentrated to give diethyl allylmalonate (24 g) as a colorless liquid.
Synthesis Reference(s)
Chemistry Letters, 17, p. 291, 1988
The Journal of Organic Chemistry, 28, p. 504, 1963 DOI: 10.1021/jo01037a058
Diethyl allylmalonate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 197)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Innovative Labs | +91-9885794886 +91-9885794886 | Telangana, India | 219 | 58 | Inquiry |
| Santo Righello Pvt. Ltd | 91-9885571757 | Hyderabad, India | 919 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| VASIN BIO LIFE SCIENCES PVT LTD | 9491644688 | Hyderabad, India | 2096 | 58 | Inquiry |
| ChemDoc International Inc. | Maharashtra, India | 25 | 58 | Inquiry | |
| Innovative Labs | 91--9885794886 | Mallapur, India | 111 | 58 | Inquiry |
| Survival Technologies Private Limited | 08879997937 | Mumbai, India | 153 | 58 | Inquiry |
| Survival Technologies Pvt Ltd | +91 (22) 4212-8221 | New Delhi, India | 290 | 50 | Inquiry |
| Supplier | Advantage |
|---|---|
| Innovative Labs | 58 |
| Santo Righello Pvt. Ltd | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Reax Chemicals | 58 |
| VASIN BIO LIFE SCIENCES PVT LTD | 58 |
| ChemDoc International Inc. | 58 |
| Innovative Labs | 58 |
| Survival Technologies Private Limited | 58 |
| Survival Technologies Pvt Ltd | 50 |
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Diethyl Allylmalonate >
Propanedioic acid, 2-(2-propen-1-yl)-, 1,3-diethyl ester
iethyl2-prop-2-enylpropanedioate
2049-80-1
CH2CHCH2CHCOOC2H52
C10 to C11
Carbonyl Compounds
Building Blocks
Organic Building Blocks
Esters
Pharmaceutical Intermediates
Aromatic Esters
TheMalonateRamificationProducts