ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Ethers >(R)-(-)-Benzyl glycidyl ether
(R)-(-)-Benzyl glycidyl ether
- CAS No.
- 14618-80-5
- Chemical Name:
- (R)-(-)-Benzyl glycidyl ether
- Synonyms
- tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na
- CBNumber:
- CB9320637
- Molecular Formula:
- C10H12O2
- Molecular Weight:
- 164.2
- MOL File:
- 14618-80-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
| Melting point | 88-93°C |
|---|---|
| alpha | -5.4 º (c=5 in toluene) |
| Boiling point | 130 °C (0.1 mmHg) |
| Density | 1.077 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| form | paste (yellow) |
| Specific Gravity | 1.077 |
| color | Colorless to Almost colorless |
| optical activity | [α]20/D 5.4°, c = 5 in toluene |
| Water Solubility | Soluble in water. |
| BRN | 3588399 |
| CAS DataBase Reference | 14618-80-5(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| RIDADR | NA 1993 / PGIII | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TX2860020 | |||||||||
| HS Code | 29109000 | |||||||||
| Toxicity | mic-sat 660 nmol/plate MUREAV 298,197,1993 | |||||||||
| NFPA 704 |
|
(R)-(-)-Benzyl glycidyl ether price More Price(14)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 791547 | Titania paste, transparent | 14618-80-5 | 10G | ₹17092.68 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 791547 | Titania paste, transparent | 14618-80-5 | 20G | ₹31522.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 720429 | 1H-Pyrazol-3-ylboronic acid hydrate | 14618-80-5 | 250MG | ₹7934.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 720429 | 1H-Pyrazol-3-ylboronic acid hydrate | 14618-80-5 | 1G | ₹15966.88 | 2022-06-14 | Buy |
| Sigma-Aldrich | 363529 | (R)-(−)-Glycidyl benzyl ether 99% | 14618-80-5 | 1G | ₹3777.93 | 2022-06-14 | Buy |
(R)-(-)-Benzyl glycidyl ether Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.
General Description
1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.
Safety Profile
Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods
This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials
Raw materials
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Global( 315)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Rajbhushan Pharmaceuticals Pvt., Ltd. | 91-7573811680 | Gujarat, India | 26 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21669 | 55 | Inquiry |
| Supplier | Advantage |
|---|---|
| CHEMSWORTH | 30 |
| Otto Chemie Pvt. Ltd. | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| A.J Chemicals | 58 |
| Rajbhushan Pharmaceuticals Pvt., Ltd. | 58 |
| Reax Chemicals | 58 |
| Clearsynth Labs | 58 |
| Capot Chemical Co.,Ltd. | 60 |
| Henan Tianfu Chemical Co.,Ltd. | 55 |
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