Isobornyl acrylate
- CAS No.
- 5888-33-5
- Chemical Name:
- Isobornyl acrylate
- Synonyms
- iboa;IBXA;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate;sr506;ebecryliboa;(1R,2R,4R)-rel-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl acrylate;qm589;EM70DN;sartomer506;al-co-cureiba
- CBNumber:
- CB9327469
- Molecular Formula:
- C13H20O2
- Molecular Weight:
- 208.3
- MOL File:
- 5888-33-5.mol
- Modify Date:
- 2024/7/24 17:31:20
| Melting point | <-35°C |
|---|---|
| Boiling point | 119-121 °C15 mm Hg(lit.) |
| Density | 0.986 g/mL at 25 °C(lit.) |
| vapor pressure | 1.3Pa at 20℃ |
| refractive index |
n |
| Flash point | 207 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Water Solubility | Difficult to mix in water. |
| FreezingPoint | 5 |
| Sensitive | Light Sensitive |
| BRN | 2254825 |
| Stability | Light sensitive |
| InChIKey | PSGCQDPCAWOCSH-BREBYQMCSA-N |
| LogP | 4.52 at 20℃ |
| CAS DataBase Reference | 5888-33-5(CAS DataBase Reference) |
| EPA Substance Registry System | Isobornyl acrylate (5888-33-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H319-H335-H410 | |||||||||
| Precautionary statements | P261-P264-P273-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N,Xi | |||||||||
| Risk Statements | 20/22-36/37/38-51/53 | |||||||||
| Safety Statements | 26-36-61-28 | |||||||||
| RIDADR | UN 3082 9 / PGIII | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | UD3940000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161290 | |||||||||
| Toxicity | LD50 oral in rat: 4890mg/kg | |||||||||
| NFPA 704 |
|
Isobornyl acrylate price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 392103 | Isobornyl acrylate technical grade, contains 200?ppm monomethyl ether hydroquinone as inhibitor | 5888-33-5 | 100ML | ₹2132.53 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 392103 | Isobornyl acrylate technical grade, contains 200?ppm monomethyl ether hydroquinone as inhibitor | 5888-33-5 | 500ML | ₹4676.4 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 392103 | Isobornyl acrylate technical grade, contains 200?ppm monomethyl ether hydroquinone as inhibitor | 5888-33-5 | 1L | ₹9341.98 | 2022-06-14 | Buy |
| TCI Chemicals (India) | I0638 | Isobornyl Acrylate (stabilized with MEHQ) min. 90.0 % | 5888-33-5 | 25G | ₹1800 | 2022-05-26 | Buy |
| TCI Chemicals (India) | I0638 | Isobornyl Acrylate (stabilized with MEHQ) min. 90.0 % | 5888-33-5 | 500G | ₹4700 | 2022-05-26 | Buy |
Isobornyl acrylate Chemical Properties,Uses,Production
Uses
Isobornyl acrylate (IBA) can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP).
Application
Isobornyl acrylate can be used as a co-monomer with other acrylic monomers in the preparation of pressure-sensitive adhesives (PSAs) for optical applications. It is also used in the development of high-performance and stable polymer gate dielectrics for organic thin-film transistors (OTFTs). Furthermore, it can also used in the preparation of UV-curable waterborne polyurethane (WPU) by copolymerization.
Hazard
Moderately toxic by ingestion. Low toxicity by skin contact. A moderate skin and mild eye irritant.
Synthesis
Isobornyl acrylate is prepared by reacting (-)- borneol,triethylamine with acryloyl chloride in anhydrous THF.Dissolve (-)- borneol (1.00 g, 6.48 mmol, 1 equiv) and triethylamine (0.98 g, 9.72 mmol, 1.5 equiv) in anhydrous THF (20 mL) in a 100 mL round-bottom flask. Add acryloyl chloride (0.88 g, 9.72 mmol, 1.5 equiv) dropwise to the reaction mixture at 0 °C. Allow the reaction to stir at room temperature overnight. Filter the reaction solution. Concentrate the reaction solution on the rotary evaporator. Wash the mixture with water (20 mL). Extract the mixture with dichloromethane (3x20 mL). Dry the combined organic phases over anhydrous sodium sulfate. Filter and concentrate the residue. Purify the crude product further by silica gel column chromatography (petroleum ether/ethyl acetate = 4:1) to obtain isobornyl acrylate.
Fig Synthetic method of Isobornyl acrylate
Isobornyl acrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| Vimal Agencies | 09967329039 | Mumbai, India | 52 | 58 | Inquiry |
| Kowa India Pvt., Ltd. | 91-22-28524680 | Maharashtra, India | 54 | 58 | Inquiry |
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | China | 189 | 55 | Inquiry |
| Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 | China | 114 | 58 | Inquiry |
| Gansu Jinyuantai New Material Co., Ltd. | +86-025-86618065 +86-13914714331 | China | 73 | 58 | Inquiry |
| Hubei Ipure Biology Co., Ltd | +8613367258412 | China | 10326 | 58 | Inquiry |
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