ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic ruthenium >Ruthenium carbonyl
Ruthenium carbonyl
- CAS No.
- 15243-33-1
- Chemical Name:
- Ruthenium carbonyl
- Synonyms
- Ru3(CO)12;TRIRUTHENIUM DODECACARBONYL;DODECACARBONYLTRIRUTHENIUM;pentaoxonium;RUTHENIUM CARBONYL;Rutheniumcarbonyl,99%;Ruthenium carbonyl 99%;carbon monoxide ruthenium;DIRUTHENIUM DODECACARBONYL;Ruthenium,dodecacarbonyltri-
- CBNumber:
- CB9426890
- Molecular Formula:
- C12O12Ru3
- Molecular Weight:
- 639.33
- MOL File:
- 15243-33-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/10/10 14:25:49
| Melting point | 150 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
| form | crystal |
| color | orange |
| CAS DataBase Reference | 15243-33-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H332 | |||||||||
| Precautionary statements | P261-P271-P304+P340+P312 | |||||||||
| Hazard Codes | F,Xn | |||||||||
| Risk Statements | 11-20-2017/11/20 | |||||||||
| Safety Statements | 24/25 | |||||||||
| RIDADR | 1325 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Flammable/Harmful | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
Ruthenium carbonyl price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 245011 | Triruthenium dodecacarbonyl 99% | 15243-33-1 | 1G | ₹12765 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 245011 | Triruthenium dodecacarbonyl 99% | 15243-33-1 | 5G | ₹34365.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 245011 | Triruthenium dodecacarbonyl 99% | 15243-33-1 | 50G | ₹272061 | 2022-06-14 | Buy |
| TCI Chemicals (India) | T2181 | Triruthenium Dodecacarbonyl | 15243-33-1 | 100MG | ₹3000 | 2022-05-26 | Buy |
| TCI Chemicals (India) | T2181 | Triruthenium Dodecacarbonyl | 15243-33-1 | 1G | ₹19800 | 2022-05-26 | Buy |
Ruthenium carbonyl Chemical Properties,Uses,Production
Description
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.
Chemical Properties
The substance appears as orange plates or powder and is soluble in non-polar organic solvents.
Uses
Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
Reactions
- Catalyst for the conversion of enynes to catechol derivatives.
- Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
- 3-Component couplings.
- Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
- Ester decarboxylation.
- Catalyst for hydroamination and C-H bond activation.
- Used in sp3 C-H bond arylation and carbonylation.
- Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
- Amination of α-hydroxy amides.
General Description
Atomic number of base material: 44 Ruthenium
Ruthenium carbonyl Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 224)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
| SOLFYN INTERNATIONAL LLP | +91-9321772608 +91-9321772608 | Mumbai, India | 105 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Souvenier Chemicals | 08048372762Ext 645 | Mumbai, India | 396 | 58 | Inquiry |
| Synthesis With Catalysts Private Limited | 08048250110Ext 908 | Delhi, India | 59 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 18646 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21667 | 55 | Inquiry |
| Accela ChemBio Inc. | +1-858-6993322 | United States | 19479 | 58 | Inquiry |
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C12H12Ru3
C12O12Ru3
Ru Catalysts
Transition Metal Compounds
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Ru (Ruthenium) Compounds
Catalysis and Inorganic Chemistry
Ru
Classes of Metal Compounds
Ru (Ruthenium) Compounds
Transition Metal Compounds
metal carbonyl complexes