1,3-ジクロロプロパン (1mg/mlメタノール溶液) [水質分析用] 化学特性,用途語,生産方法
外観
無色~うすい黄色, 澄明の液体
溶解性
水に微溶 (2.87g/1000g水, 30℃), エタノール, エーテルに易溶。エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。
用途
有機合成中間体、溶剤、ドライクリーニング用洗剤
化学的特性
1,3-Dichloropropene occurs as a clear colourless liquid with a sweet chloroform-like odor. It is soluble in alcohol and ether, dissolves in water (0.27g/100ml). The half-life of 1,3-dichloropropene in ambient air may range from 7 to 50 hours.
使用
1,3-Dichloropropane is used as an intermediate in organic synthesis. It is also used as solvent, detergent and chromatographic analysis. Further, it is used to prepare 3,7-dithia-nonanedioic acid by reacting with mercaptoacetic acid.
定義
ChEBI: 1,3-dichloropropane is a chloroalkane that is propane in which a hydrogen from each of the terminal methyl groups has been replaced by a chlorine. It has a role as an environmental contaminant and a nematicide. It is a chloroalkane and a chlorohydrocarbon.
製造方法
1,3-Dichloropropane is obtained by the action of propylene glycol with hydrochloric acid.
1,3-Dichloropropane synthesis: A process for the preparation of 1,3-dichloropropane by reacting bis(3-hydroxypropyl)ether with hydrogen chloride, optionally in the presence of tertiary basic nitrogen compounds or other tertiary aliphatic bases as catalysts, distilling off the 1,3-dichloropropane and the water of reaction and working up the two phases.
Process for the preparation of 1,3-dichloropropane
一般的な説明
1,3-dichloropropane is a colorless watery liquid with a sweet odor. Sinks in water. Produces irritating vapor. (USCG, 1999)
空気と水の反応
Highly flammable.
反応プロフィール
Halogenated aliphatic compounds, such as 1,3-Dichloropropane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
健康ハザード
INHALATION: May cause some central nervous system depression. EYES: May cause some pain and irritation. SKIN: Mild irritation.
安全性プロファイル
Moderately toxic by
ingestion. Mutation data reported. A very
dangerous fire hazard when exposed to heat
or flame. When heated to decomposition it
emits highly toxic fumes of Cl and
phosgene. See also CHLORINATED
HYDROCARBONS, ALIPHATIC; and
PROPYLENE DICHLORIDE.
1,3-ジクロロプロパン (1mg/mlメタノール溶液) [水質分析用] 上流と下流の製品情報
原材料
準備製品
2-(2-(ジフェニルホスフィノ)エチル)ピリジン
[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(II)ジクロリド
1,3-ビス(ジフェニルホスフィノ)プロパン
ビス(2,4-ペンタンジオナト)パラジウム(II)
ビス(ジベンジリデンアセトン) パラジウム(0)
シクロプロパン
S,S'-[2-(ジメチルアミノ)-1,3-プロパンジイル]ビス(ベンゼンスルホノチオアート)
グリシジルメチルエーテル
1,3-ジアミノプロパン
1,1,3-トリクロロプロパン
1,1-シクロブタンジカルボン酸ジエチル
アリルブチルエーテル
(3-クロロプロピル)マロン酸ジエチル
トリメチレン ビス(4-アミノベンゾアート)
1,2-ジアザシクロペンタン
3-クロロプロピルアミン