에틸렌 산화물 시클릭 헥사머
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에틸렌 산화물 시클릭 헥사머 속성
- 녹는점
- 42-45 °C(lit.)
- 끓는 점
- 116°C 0,2mm
- 밀도
- 1,175 g/cm3
- 굴절률
- 1.4580 (estimate)
- 인화점
- >230 °F
- 저장 조건
- Store below +30°C.
- 용해도
- 클로로포름(약간 용해됨), 메탄올(매우 소량)
- 물리적 상태
- 결정 또는 결정질 질량 또는 액체
- 색상
- 흰색 또는 투명한 무색
- 수용성
- 녹는
- 감도
- Hygroscopic
- Merck
- 14,2602
- BRN
- 1619616
- 안정성
- 안정적인. 강산, 강산화제와 호환되지 않습니다.
- InChIKey
- XEZNGIUYQVAUSS-UHFFFAOYSA-N
- CAS 데이터베이스
- 17455-13-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 22-36/37/38-36-20/22-20/21/22 | ||
안전지침서 | 26-36-39 | ||
유엔번호(UN No.) | 2811 | ||
WGK 독일 | 3 | ||
RTECS 번호 | MP4500000 | ||
F 고인화성물질 | 10 | ||
TSCA | Yes | ||
위험 등급 | 6.1(b) | ||
포장분류 | III | ||
HS 번호 | 29329995 | ||
독성 | LD50 orally in Rabbit: 525 mg/kg LD50 dermal Rabbit 3888 mg/kg | ||
기존화학 물질 | KE-19820 |
에틸렌 산화물 시클릭 헥사머 C화학적 특성, 용도, 생산
화학적 성질
slightly yellow solid용도
18-Crown-6 is used as an efficient phase transfer catalyst and as a complexing agent with a variety of small cation. It is involved in the synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6. It facilitates the solubility of potassium permanganate in benzene, which is used for oxidizing the organic compounds. It is used to accelerate various substitution reactions as well as enhances the power of nucleophiles such as potassium acetate. It is utilized in the alkylation reactions in the presence of potassium carbonate, N-alkylation of glutarimide and succinimide with dimethylcarbonate. The complex formed by its reaction with potassium cyanide acts as a catalyst in the cyanosilylation of aldehydes, ketones and quinines with trimethylsilyl cyanide (TMSCN).일반 설명
18-Crown-6 is the simplest crown ether that can be prepared by reacting triethylene glycol with triethylene glycol dichloride in the presence of potassium hydroxide as a base. 18-Crown-6 can solubilize metal salts, particularly potassium salts, in nonpolar and dipolar aprotic solvents. Thus, it is widely used as a phase transfer catalyst. It can also be used as a metal complexing agent to prepare a variety of molecular complexes.Purification Methods
Recrystallise it from acetonitrile and dry it in a vacuum. Purify it also by precipitating the 18-crown-6/nitromethane 1:2 complex with Et2O/nitromethane (10:1 mixture). The complex is decomposed in vacuum whereby 18-crown-6 distils off under the reduced pressure. [Beilstein 19/12 V 601.]에틸렌 산화물 시클릭 헥사머 준비 용품 및 원자재
원자재
Organic base
글로불린,고양이감마
Biochemistry
Alkali Metals, plasma standard solution, Specpure, Ba,Be,Ca,Cs,K,Li,Mg,Na,Rb,Sr, 100μg/ml
사이안화 칼륨
15-Crown-5
준비 용품
[(2-OXO-2H-CHROMEN-7-YL)OXY]ACETIC ACID
5-아미노메틸-피롤리딘-2-온
5-Bromoindazole
3-AMINO-2-FLUORO-4-PICOLINE
에폭시시클로로덴칸(1.2-)
Cefpodoxime proxetil
4-AMINO-2,6-DIFLUOROPYRIMIDINE
1,1'-DIMETHYLFERROCENE
N,N-디메틸에틸렌디아민
2-(4-브로모페닐)티오펜
3-페녹시페닐아세토니트릴
2,4-DIAMINO-6-FLUOROPYRIMIDINE
2-AMINO-4,6-DIFLUOROPYRIMIDINE
옥소티아졸리딘
N,N,N',N'-Tetraphenylbenzidine
에틸렌 산화물 시클릭 헥사머 공급 업체
글로벌( 711)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Shandong Believe Chemical PTE.LTD | +86-18553607090 +8618553607090 |
1093908296@qq.com | China | 1672 | 58 |
weifang runzhong fine chemical co., ltd | 536-7868377 +8618653686003 |
sq@runzhongchem.com | China | 187 | 58 |
LEAPCHEM CO., LTD. | +86-852-30606658 |
market18@leapchem.com | China | 43348 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12450 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +86-17531190177; +8617531190177 |
peter@yan-xi.com | China | 5873 | 58 |
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5828 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20294 | 58 |
Apeloa production Co.,Limited | +8619933239880 |
admin@apcl.com.cn | China | 853 | 58 |
Hebei Mojin Biotechnology Co.,Ltd | +8613288715578 |
angelia@hbmojin.com | China | 830 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
에틸렌 산화물 시클릭 헥사머 관련 검색:
디메틸 에테르 에틸렌글리콜모노부틸에테르 에틸벤젠 옥타데케인 디에틸에테르 디시클로헥실-18-CROWN-6 6,7,9,10,17,18,20,21-옥타히드로디벤조(베타,카파)(1,4,7,10,13,16) 헥사옥사시클로옥타디신 에틸렌 산화물 시클릭 헥사머
12-Crown-4
4'' 4 (5 )-DI-TERT.BUTYLDICYCLOHEXANO-18-CROWN-6,MIXTUREOFISOMERS
(+)-(18-CROWN-6)-2,3,11,12-TETRACARBOXYLIC ACID
1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2-METHANOL
Isobutyl iodide
4-ACRYLAMIDOBENZO-18-CROWN-6 98%
4',4''(5'')-di-tert-butyldibenzo-18-crown-6, mixed isomers,4,4'-Di-tert-butyldibenzo-18-crown-6
4-AMINOBENZO-18-CROWN-6 PURUM,97%
4-Nitrobenzo-18-crown-6,99%
4-VINYLBENZO-18-CROWN-6 97%