15-Crown-5
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15-Crown-5 속성
- 녹는점
- -20°C(lit.)
- 끓는 점
- 93-96 °C/0.05 mmHg (lit.)
- 밀도
- 1.113 g/mL at 20 °C (lit.)
- 증기압
- 0.5-0.82Pa at 20-25℃
- 굴절률
- n
20/D 1.465(lit.)
- 인화점
- >230 °F
- 저장 조건
- room temp
- 용해도
- 유기용매와 섞일 수 있음.
- 물리적 상태
- 액체
- Specific Gravity
- 1.109
- 색상
- 무색투명~연황색
- 수용성
- 혼용 가능
- 감도
- Hygroscopic
- BRN
- 1618144
- 안정성
- 안정적인. 산화제, 강산과 호환되지 않습니다. 물이나 습한 공기에 노출되지 않도록 하세요.
- LogP
- -0.9 at 20℃ and pH7.7
- 표면장력
- 68.5mN/m at 1g/L and 20℃
- CAS 데이터베이스
- 33100-27-5(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 22-36/38-36-20/22-36/37/38-20/21/22 | ||
안전지침서 | 26-39-36 | ||
유엔번호(UN No.) | 2810 | ||
WGK 독일 | 3 | ||
RTECS 번호 | SB0200000 | ||
F 고인화성물질 | 10-21 | ||
위험 참고 사항 | Irritant | ||
TSCA | Yes | ||
위험 등급 | 6.1(b) | ||
포장분류 | III | ||
HS 번호 | 29329995 | ||
독성 | LD50 orl-rat: 1410 mg/kg DCTODJ 1,339,78 |
15-Crown-5 C화학적 특성, 용도, 생산
화학적 성질
colourless liquid용도
15-Crown-5 is used as an efficient phase transfer catalyst and as a complexing agent. It is used to isolate oxonium ion (H7O3)+ salts especially from a solution of tetrchloroauric acid. It catalyzes the O-alkylation of the sodium salts of carboxylic acids in the penicillin and cephalosporin series, thereby facilitating esterification reaction without usage of acid. It is also used to facilitate the Williamson synthesis of ethers with hindered alcohols and sodium hydride. It is used with lithium aluminum hydride, for performing reduction reactions in hydrocarbon solvents. Further, it is involved in the Horner-Wadsworth-Emmons reaction to prepare stilbenes from aldehydes.정의
ChEBI: A saturated organic heteromonocyclic parent that is cyclopentadecane in which the carbon atoms at positions 1, 4, 7, 10 and 13 have been replaced by oxygen atoms to give a crown ether.일반 설명
15-Crown-5 is a crown ether generally used as a ligand in coordination chemistry because of its strong chelating property with certain alkali cations to form complexes. Some derivatives of 15-crown-5 are used as sensors and probes in different physical-chemical processes, phase-transfer reactions, and selective capture of ions for separation and transport.Safety Profile
Moderately toxic by ingestion, skin contact, and intraperitoneal routes. A skin and eye . When heated to decomposition it emits acrid smoke and irritating fumesPurification Methods
Dry it over 3A molecular sieves and distil it in a high vacuum. [Beilstein 19/12 V 252.]15-Crown-5 준비 용품 및 원자재
원자재
준비 용품
METHYL 3-((PIPERIDIN-4-YL)METHYL)BENZOATE
4-((1-(tert-부톡시카르보닐)피페리딘-4-일)메틸)벤조산
METHYL 4-((PIPERIDIN-4-YL)METHYL)BENZOATE
2-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID
에틸렌 산화물 시클릭 헥사머
PERFLUORO-15-CROWN-5
2-메틸-1,3-디옥솔란
3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID
1-트리아콘타놀
클로르플루아주론
METHYL 2-((PIPERIDIN-4-YL)METHYL)BENZOATE
4-플로로아닐린
15-Crown-5 공급 업체
글로벌( 483)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12450 | 58 |
Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5828 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 16914 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21668 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9332 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32760 | 60 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 |
info@tnjchem.com | China | 2989 | 55 |
Zjartschem | +86-571 87238903 |
jocelynpan@zjarts.com | CHINA | 993 | 58 |
Shanghai Zheyan Biotech Co., Ltd. | 18017610038 |
zheyansh@163.com | CHINA | 3620 | 58 |
15-Crown-5 관련 검색:
1,4,10-트리옥사-7,13-디아자-사이클로펜타데칸 4′-포르밀벤조-15-크라운-5
12-Crown-4
CYCLOHEXANO-15-CROWN-5
4-T-BUTYLCYCLOHEXANO-15-CROWN-5,4-TERT-BUTYLCYCLOHEXANO-15-CROWN-5
Hydroxy-15-crown-5,2-(HYDROXYMETHYL)-15-CROWN 5-ETHER,2-HYDROXYMETHYL-15-CROWN-5
4'-BROMOBENZO-15-CROWN-5,4'-BROMOBENZO-15-CROWN 5-ETHER,4-BROMOBENZO-15-CROWN-5
4'-NITROBENZO-15-CROWN-5,4-NITROBENZO-15-CROWN-5,4'-NITROBENZO-15-CROWN 5-ETHER
DIBENZO-15-CROWN-5
4'-CARBOXYBENZO-15-CROWN-5,4-CARBOXYBENZO-15-CROWN-5,4'-CARBOXYBENZO-15-CROWN 5-ETHER
4-AMINOBENZO-15-CROWN-5 HYDROCHLORIDE,4'-AMINOBENZO-15-CROWN-5 HYDROCHLORIDE
4'-AMINOBENZO-15-CROWN 5-ETHER,4'-AMINOBENZO-15-CROWN-5
1-AZA-15-CROWN-5,1-AZA-15-CROWN 5-ETHER
4-TERT-BUTYLBENZO-15-CROWN-5,4-T-BUTYLBENZO-15-CROWN-5,tert-Butylbezno-15-crown-5
Benzo-15-crown-5
4'-(2,4-DINITRO-6-TRIFLUOROMETHYLPHENYL)-AMINOBENZO-15-CROWN-5,4'-(2'',4''-DINITRO-6''-TRIFLUOROMETHYLPHENYL)-AMINOBENZO-15-CROWN-5
Dibenzodiaza-15-crown-4
2,3-NAPHTHO-15-CROWN-5