설프로포스

설프로포스
설프로포스 구조식 이미지
카스 번호:
35400-43-2
한글명:
설프로포스
동의어(한글):
설프로포스;술프로포스
상품명:
SULPROFOS
동의어(영문):
BOLSTAR;ntn9306;Bolster;merpafos;helothion;SULPROFOS;BOLSTAR(R);SULPROPHOS;BAY 123234;mercaprofos
CBNumber:
CB5129467
분자식:
C12H19O2PS3
포뮬러 무게:
322.45
MOL 파일:
35400-43-2.mol
MSDS 파일:
SDS

설프로포스 속성

녹는점
-15℃
끓는 점
bp0.1 155-158°
밀도
1.20 g/cm3
증기압
8.4×10-5Pa (20 °C)
굴절률
nD20 1.5859
저장 조건
APPROX 4°C
수용성
0.31mg 1l-1(20°C)
물리적 상태
액체
Specific Gravity
1.20 (20℃)
Merck
13,9081
BRN
1990231
노출 한도
NIOSH PEL: TWA 1 mg/m3; ACGIH TLV: TWA 1 mg/m3.
EPA
Sulprofos (35400-43-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 21-23/25-50/53
안전지침서 36/37-45-60-61
OEB C
OEL TWA: 1 mg/m3
유엔번호(UN No.) 3018
WGK 독일 3
RTECS 번호 TE4165000
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 35400-43-2(Hazardous Substances Data)
독성 LD50 orally in rats: 227 mg/kg (Bull, Ivie)
기존화학 물질 KE-05-0610
유해화학물질 필터링 97-1-142
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 술프로포스 및 이를 3% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H330 흡입하면 치명적임 급성 독성 물질 흡입 구분 1, 2 위험 GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.

설프로포스 C화학적 특성, 용도, 생산

화학적 성질

Sulprofos is a tan colored liquid.

용도

Sulprofos is used to control Lepidoptera, thrips and other insects in cotton, soya, tobacco, vegetables and tomatoes.

일반 설명

Tan-colored liquid with a sulfide-like odor.

반응 프로필

Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

위험도

Cholinesterase inhibitor. Questionable carcinogen.

Safety Profile

Poison by ingestion. Moderately toxic by skin contact. When heated to decomposition it emits very toxic fumes of POx and SOx.

잠재적 노출

A potential danger to those involved in the manufacture, formulation, and application of this insecticide that is used for control of certain lepidopterous, dipterous, and hemipterous insects on cotton, etc.

환경귀착

Biological. From the first-order biotic and abiotic rate constants of sulprofos in estu- arine water and sediment/water systems, the estimated biodegradation half-lives were 19.5–61.6 and 3.5–19 days, respectively (Walker et al., 1988).
Photolytic. When sulprofos was exposed to sunlight as deposits on cotton foliage, glass surfaces and in aqueous solution, the insecticide degraded rapidly (half-life <2 days). Irradiation of sulprofos in aqueous solution using UV light (λ >290
Chemical/Physical. Emits toxic oxides of sulfur and phosphorus when heated to decomposition (Lewis, 1990).

신진 대사 경로

Sulprofos is an organophosphorus insecticide possessing a 4-(methylthio) phenyl group and as such its metabolic fate has much in common with fenthion with which it also has the phosphorothioate (P=S) group in common. The major route of sulprofos metabolism is by oxidation to the sulfoxide and more slowly to the sulfone. The additional route of bioactivation is through oxidative desulfuration to form the sulprofos oxon and all five oxidative metabolites (sulprofos sulfoxide, sulprofos sulfone, sulprofos oxon, sulprofos oxon sulfoxide and sulprofos oxon sulfone) have been detected in rats. Degradative metabolism by hydrolysis or oxidative dearylation to the phenols occurs rapidly. Stage II metabolism in mammals involves the rapid conjugation of the phenolic dearylation products. The fate of the S-propyl phosphorodithioate group has not apparently been reported.

신진 대사

Major metabolic routes are by oxidation to the sulfoxide and sulfone and oxidative desulfuration to the oxons. Detoxification by dearylation to the phenols occurs rapidly. Sulprofos is degraded in soil with a half-life ranging from a few days to several weeks, depending on the soil type.

운송 방법

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

폐기물 처리

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

설프로포스 준비 용품 및 원자재

원자재

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