3-브로모프로피온산
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3-브로모프로피온산 속성
- 녹는점
- 58-62 °C(lit.)
- 끓는 점
- 140-142 °C (45 mmHg)
- 밀도
- 1.48 g/mL at 25 °C(lit.)
- 굴절률
- 1.4753 (estimate)
- 인화점
- 150 °F
- 저장 조건
- 2-8°C
- 용해도
- H2O: 0.1 g/mL, 투명
- 물리적 상태
- 결정 또는 결정성 분말
- 산도 계수 (pKa)
- 4.00(at 25℃)
- 색상
- 흰색에서 약간 노란색
- 수용성
- 0.1G/ML
- Merck
- 14,1433
- BRN
- 1071333
- Dielectric constant
- 11.0(20℃)
- CAS 데이터베이스
- 590-92-1(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,C | ||
---|---|---|---|
위험 카페고리 넘버 | 11-34 | ||
안전지침서 | 26-36/37/39-45 | ||
유엔번호(UN No.) | UN 3261 8/PG 2 | ||
WGK 독일 | 3 | ||
RTECS 번호 | UE7875000 | ||
위험 참고 사항 | Corrosive/Highly Flammable | ||
TSCA | Yes | ||
위험 등급 | 4.1 | ||
포장분류 | III | ||
HS 번호 | 29159080 | ||
유해 물질 데이터 | 590-92-1(Hazardous Substances Data) |
3-브로모프로피온산 C화학적 특성, 용도, 생산
화학적 성질
white to pale yellow or orange crystalline. soluble in water, alcohol, ether, chloroform, benzene. Hydrolysis in alkaline solution generates hydroxypropionic acid. Corrosive. for organic synthesis.용도
3-Bromopropionic acid used as quaternization agent in amperometric biosensors.주요 응용
3-Bromopropionic acid is a widely used chemical intermediate. It can be used as a starting material to synthesize derivatives such as esters, acid halides and amides; the active group bromine can undergo a series of reactions, and is mainly used in the fields of pesticides and medicines. Such as the pesticides diflufenacil, furalax and so on.제조 방법
3-Bromopropionic acid is prepared by reacting acrylonitrile with hydrogen bromide to obtain bromopropionitrile and then hydrolyzing it. Add acrylonitrile to boiling hydrobromic acid, reflux at 130°C for 6 hours, extract the solid obtained by filtration with ethanol, and obtain the crude product after recovering ethanol by distillation under reduced pressure. By heating 2-cyanoethanol and 40% hydrobromic acid to reflux for 2h, 3-bromopropionic acid can also be produced with a yield of over 80%.Safety Profile
Moderately toxic by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.Purification Methods
The acid crystallises as plates from CCl4. It is soluble in organic solvents and H2O. Its methyl ester has b 65o/18mm and 80o/27mm. The S-benzylisothiouronium salt has m 136o. [Kendall & McKenzie Org Synth Coll Vol I 131 1941, Beilstein 2 IV 764.]3-브로모프로피온산 준비 용품 및 원자재
원자재
에틸렌시아노히드린
α-브로모프로피온산
베타-클로로프로피온산
tert-부틸(3-부티닐옥시)디페닐실란
T-부틸3-브로모프로피오네이트97
헵틸릭 산
N-부틸마그네슘브로마이드
3-브로모프로피오니트릴
아크릴산
3-브로모-1-프로판올
모노클로로프로피온산
준비 용품
베타-프로피올락톤
4H-AMINO-6-BROMO-2,3-DIHYDROTHIOCHROMEN-1,1-DIOXIDE
6-bromo-2,3-dihydrothiochromen-1,1-dioxide-4-one
3-(4-OXO-6-PHENYL-1,4-DIHYDRO-PYRIMIDIN-2-YLSULFANYL)-PROPIONIC ACID
4-Chromanone
4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide
3-브로모프로피온산에틸에스테르
3-Bromopropionyl chloride
6-bromo-2,3-dihydrothiochromen-4-one
6-카르복시헥실트리페닐포스포늄브로마이드
3-브로모프로피온산 공급 업체
글로벌( 311)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12450 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21668 | 55 |
JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 |
andy@katchemical.com | CHINA | 59 | 55 |
Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 |
sophieliu@speranzachem.com | China | 801 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29894 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2931 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39916 | 58 |