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Ethyl chloroformate

Ethyl chloroformate

CAS:
541-41-3
MF:
C3H5ClO2
MW:
108.52

Properties

Melting point:
-81 °C (lit.)
Boiling point:
93 °C (lit.)
Density 
1.135 g/mL at 25 °C (lit.)
vapor density 
3.74 (vs air)
vapor pressure 
3.42 psi ( 20 °C)
refractive index 
n20/D 1.395(lit.)
Flash point:
57 °F
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Ethyl Acetate (Slightly)
form 
Liquid
color 
White to off-white
Odor
Irritating; sharp, like hydrochloric acid.
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Merck 
14,3784
BRN 
385653
Dielectric constant
11.3(20℃)
Stability:
Moisture Sensitive
LogP
1.440 (est)

Safety Information

Symbol(GHS) 

GHS02,GHS05,GHS06
Signal word 
Danger
Hazard statements 
H225-H290-H302-H314-H330
Precautionary statements 
P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
F,T+,N
Risk Statements 
11-22-26-34-50
Safety Statements 
9-16-26-28-33-36/37/39-45-61
RIDADR 
UN 1182 6.1/PG 1
WGK Germany 
1
RTECS 
LQ6125000
10-19-21
Autoignition Temperature
842 °F
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
I
HS Code 
29151300

Use

Ethyl chloroformate decomposes slowly in water to form ethanol, HCl, and CO2 Attacks many metals especially in humid atmosphere [Handling Chemicals Safely 1980. p. 476]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

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