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Methacrylonitrile

Methacrylonitrile

CAS:
126-98-7
MF:
C4H5N
MW:
67.09

Properties

Melting point:
−35.8 °C(lit.)
Boiling point:
90-92 °C(lit.)
Density 
0.8 g/mL at 25 °C(lit.)
vapor pressure 
64 mm Hg ( 20 °C)
refractive index 
n20/D 1.400(lit.)
Flash point:
54 °F
storage temp. 
2-8°C
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Colorless liquid
color 
Colourless
Odor Threshold
3ppm
Water Solubility 
2.57 g/100 mL (20 ºC)
Merck 
13,5968
Exposure limits
TLV-TWA skin 2.7 mg/m3 (1 ppm) (ACGIH).
LogP
0.76

Safety Information

Symbol(GHS) 

GHS02,GHS06
Signal word 
Danger
Hazard statements 
H225-H301-H311-H317-H331
Precautionary statements 
P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378-P403+P235-P501-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P261-P271-P304+P340-P311-P321-P403+P233-P405-P501
Hazard Codes 
F,T
Risk Statements 
11-23/24/25-43
Safety Statements 
9-16-18-29-45
RIDADR 
UN 3079 3/PG 1
OEB
B
OEL
TWA: 1 ppm (3 mg/m3) [skin]
WGK Germany 
1
RTECS 
UD1400000
HazardClass 
3.1
PackingGroup 
I
HS Code 
29269095
Toxicity
LD50 orally in rats: 0.25 ml/kg (Smyth)
IDLA
4.0 ppm

Use

METHACRYLONITRILE is a colorless, flammable, toxic liquid. Explosive in the form of vapor when exposed to heat, flame or sparks. When heated to decomposition Methacrylonitrile emits toxic fumes of nitrile and oxides of nitrogen [Lewis, 3rd ed., 1993, p. 829].

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