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Rhodium(III) chloride hydrate

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CAS:20765-98-4
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CAS:20765-98-4
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Products Intro: Product Name:Rhodium (III) chloride trihydrate
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Rhodium(III) chloride hydrate manufacturers

Rhodium(III) chloride hydrate Basic information
Product Name:Rhodium(III) chloride hydrate
Synonyms:RHODIUM TRICHLORIDE HYDRATE;RhodiumchloridehydrateRh;RHODIUM(III) CHLORIDE HYDRATE: 99.9% (38% RH);Rhodium(III) Chloride n-Hydrate;Rhodium(III) chloride hydrate ,99.9%;RhodiuM(III) chloride hydrate, (trace Metal basis);RhodiuM(III) chloride hydrate, 38% Rh 1GR;RHODIUM(III) CHLORIDE HYDRATE, 99.98%
CAS:20765-98-4
MF:Cl3H2ORh
MW:227.27
EINECS:606-630-8
Product Categories:Metal and Ceramic Science;Rhodium Salts;Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;RhodiumMetal and Ceramic Science;metal halide;Materials Science;Metal and Ceramic Science;Rhodium Salts;chemical reaction,pharm,electronic,materials
Mol File:20765-98-4.mol
Rhodium(III) chloride hydrate Structure
Rhodium(III) chloride hydrate Chemical Properties
Melting point 100 °C (dec.)(lit.)
storage temp. Store below +30°C.
solubility Methanol (Slightly), Water (Slightly)
form crystalline
color White to off-white
Water Solubility soluble
Sensitive Hygroscopic
Merck 14,8188
Exposure limitsACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 2 mg/m3; TWA 0.001 mg/m3
Stability:hygroscopic
InChIKeyHSSMNYDDDSNUKH-UHFFFAOYSA-K
CAS DataBase Reference20765-98-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-41
Safety Statements 26-36/39
RIDADR 1759
WGK Germany 3
TSCA Yes
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Rhodium(III) chloride hydrate Usage And Synthesis
Chemical Propertiesred-brown to dark brown crystalline powder, easily soluble in water, hydrochloric acid, alcohol and alkali solution, insoluble in ether and aqua regia, lose crystal water by strong heat and become insoluble, and then decompose into rhodium and chlorine.
UsesRhodium(III) chloride hydrate is used as a catalyst to prepare acetic acid. It is also used as a catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene. It is involved in the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.
ApplicationRhodium(III) chloride is often used in synthetic chemistry as a hydrogenation catalyst. Rhodium(III) chloride is also used to make transition metal complexes, some of which are used as reagents in the decarbonylation dehydration reactions of fatty acids to alkenes.
ReactionsCatalyst in conjunction with "pybox" for the asymmetric hydrosilylation of ketones.
C-C bond forming reactions.
Rhodium (III) chloride trihydrate Reaction
Rhodium(III) chloride hydrate Preparation Products And Raw materials
Preparation ProductsBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate-->Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Tag:Rhodium(III) chloride hydrate(20765-98-4) Related Product Information
Boron trichloride Rhodium(III) Chloride Chromium(III) chloride Antimony trichloride Trichlorine nitride Ammonium chloride Oxalyl chloride Thionyl chloride Tributyltin chloride Rhodium Lithium chloride 2,3,5-Triphenyltetrazolium chloride Sodium chloride Tris(triphenylphosphine)rhodiu Choline chloride Aluminum chlorohydrate Ruthenium(III) chloride Magnesium chloride Rhodium Chloride Hydrate