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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:35138-22-8
Purity:98% Min. Package:1G;1KG;100KG
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:35138-22-8
Purity:99% Package:100g ;1KG ;5KG 25KG Remarks:Catalysts
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:35138-22-8
Purity:99% Package:25KG;5KG;1KG
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Products Intro: Product Name:bis(1,5-cyclooctadiene)rhodium(i) tetrafluoroborate
CAS:35138-22-8
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:35138-22-8
Purity:0.99 Package:5KG;1KG

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Basic information
Uses
Product Name:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms:Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
CAS:35138-22-8
MF:C16H24BF4Rh
MW:406.07
EINECS:460-220-1
Product Categories:Rh;organometallic complex
Mol File:35138-22-8.mol
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Structure
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties
Melting point 210 °C
density 0.42 g/cm3 (20℃)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color Red
PH7 (5g/l, H2O, 20℃)
Water Solubility insoluble
Sensitive Slightly air & moisture sensitive
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKeyIEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference35138-22-8(CAS DataBase Reference)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-34
Safety Statements 16-45-36/37/39-26
RIDADR UN 2921
WGK Germany 2
Hazard Note Irritant
TSCA No
HazardClass 8
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
ALFA English
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis
Uses
  1. Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
  2. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions. 
Chemical Propertiesdark red
UsesBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.
reaction suitabilitycore: rhodium
reagent type: catalyst
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials
Raw materialsEthanol-->Ethyl acetate-->1,5-Cyclooctadiene-->Silver tetrafluoroborate-->Rhodium(III) chloride hydrate-->BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE-->Ammonium fluoborate
Tag:Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(35138-22-8) Related Product Information
Sodium tetrafluoroborate Octamethylcyclotetrasiloxane Rhodium 1,3-CYCLOOCTADIENE 1,5-Cyclooctadiene Potassium tetrafluoroborate Fluoroboric acid Ammonium fluoborate Dichloro(1,5-cyclooctadiene)palladium(II) methoxy(cyclooctadiene)rhodium(i) dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Tris(dibenzylideneacetone)dipalladium Dichloro(1,5-cyclooctadien)ruthenium(II) polymer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE
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