ПЕРОКСИД БАРИЯ химические свойства, назначение, производство
Описание
Barium peroxide, is a grayish-white powder that is slightly soluble in water. Barium peroxide is a dangerous fire and explosion risk in contact with organic materials and decomposes around 1450°F (787°C). It is also toxic by ingestion, is a skin irritant, and should be kept cool and dry in storage. The four-digit UN identification number is 1449. The primary uses of barium peroxide are in bleaching, in thermal welding of aluminum, as an oxidizing agent, and in the dyeing of textiles.
Химические свойства
Barium peroxide is a grayish-white powder.
Физические свойства
BaO2 is an iron gray or white powder. It is slowly
decomposed in air, forming the hydroxide and oxygen.
It does not dissolve in water, but can slowly hydrolyze,
forming hydrogen peroxide in solution. Barium peroxide is a strong oxidizing agent and will explode if direct contact with organic matter occurs. Therefore, barium peroxide is always diluted to form a slurry before usage.
Barium peroxide is a strong oxidizing agent that is
used for bleaching. Barium peroxide contains O22-
subunits wherein the oxygen atoms bond to each other
as well as to the barium.
Использование
Bariumperoxide is used as a hydrogen peroxide source
and oxygen oxidant, as well as a bleaching agent. Its main
usage has been for making hydrogen peroxide and
oxygen, in organic syntheses, fabric printing and dyeing.
Barium peroxide is available commercially, primarily
as the oxctahydrate (which is the more stable form of
this peroxide).
Определение
barium peroxide: A dense offwhitesolid, BaO2, prepared by carefullyheating barium oxide inoxygen; r.d. 4.96; m.p. 450°C. It is used as a bleaching agent. Withacids, hydrogen peroxide is formedand the reaction is used in the laboratorypreparation of hydrogen peroxide.
Методы производства
Barium peroxide, BaO2, was the first-known peroxo compound. It was used until mid-1900 in the manufacture of oxygen by the Brin process and of hydrogen peroxide by the Thenard reaction.
Подготовка
Barium peroxide is best prepared by reacting barium
nitrate with sodium peroxide in a cold solution:
Ba(NO3)2＋Na2O2＋xH2O→BaO2·xH2O＋2NaNO3
The hydrated form is usually the octahydrate. If the
anhydrate is desired, the hydrated peroxide is dried
and then sintered at 350°C for 10 min or less:
4BaO2·xH2O＋ heat→2BaO＋2BaO2＋xH2O＋O2
About equal amounts of oxide and peroxide form.
The ratio is a function of the time and temperature of
heating. To separate the two forms, the heated mass is
plunged into a large volume of water where the
hydroxide is formed. The peroxide is insoluble whereas
the hydroxide is soluble, allowing the separation of the
two by filtration. The peroxide is then vacuum dried.
Общее описание
A grayish-white granular solid. Insoluble in water. Noncombustible, but accelerates the burning of combustible material. Mixture with finely divided combustible material may be explosive. Mixtures with combustible material may be ignited by friction or contact with moisture.
Реакции воздуха и воды
Decomposed by water. Insoluble in water.
Профиль реактивности
Barium peroxide is a strong oxidizing agent. Contact with water can produce a temperature and oxygen concentration high enough to ignite organic materials [Bretherick's, 5th ed., 1995, p. 94]. Reacts explosively with acetic anhydride due to the formation of acetyl peroxide [Rust, 1948, p. 337]. Ignites when mixed with powdered aluminum, powdered magnesium or calcium-silicon alloys. Wood may ignite with friction from the peroxide. Decomposes when heated to 700°C to produce barium oxide and pure oxygen [Sax, 9th ed., 1996, p. 317]. Forms highly reactive mixtures with fuel-type materials.
Опасность
Oxidizing material. Fire and explosion risk
in contact with organic materials. Keep cool and
dry. Toxic by ingestion, skin irritant.
Угроза здоровью
Inhalation causes irritation of mucous membranes, throat, and nose. Contact with eyes or skin causes severe burns. Ingestion causes excessive salivation, vomiting, colic, diarrhea, convulsive tremors, slow, hard pulse, and elevated blood pressure; hemorrhages may occur in the stomach, intestines, and kidneys; muscular paralysis may follow.
Пожароопасность
Behavior in Fire: Can increase intensity of fire.
Профиль безопасности
A poison via
subcutaneous route. A powerful oxidtzer.
Explodes on contact with acetic anhydride.
Ignites when mixed with calcium-silicon
alloys, powdered aluminum, powdered
magnesium, water + organic compounds.
Mixtures with propane react violently when
heated. The powder ignites when heated to
265℃ with selenium. Wood ignites with
friction from the peroxide. Incompatible
with H2S, water, peroxyformic acid,
hydroxylamine solution, mixture of (Mg +
Zn + Ba(NO3)2), and organic matter. See
also BARIUM COMPOUNDS (soluble)
and PEROXIDES, INORGANIC.
Возможный контакт
Is used as a bleaching agent; in making
hydrogen peroxide, oxygen; in aluminum welding; in
textile dyeing and for bleaching fibers; animal substances.
Перевозки
UN1449 Barium peroxide, Hazard Class: 5.1;
Labels: 5.1—Oxidizer, 6.1—Poisonous materials.
Несовместимости
A strong oxidizer. Keep away from
organic and combustible materials (such as wood, paper,
oil, fuels, and other easily oxidized materials) and peroxyformic
acid, hydrogen sulfide and hydroxylamine solutions,
since violent reactions occur.
Утилизация отходов
Dispose of contents and container
to an approved waste disposal plant. All federal,
state, and local environmental regulations must be
observed. Contact your local or federal environmental protection
agency for specific recommendations.
ПЕРОКСИД БАРИЯ препаратная продукция и сырье
сырьё
препарат