DEUTERIUM HYDRIDE
DEUTERIUM HYDRIDE атрибут
| Температура плавления: |
−259.2 °C(lit.) |
| Температура кипения: |
−252.8 °C(lit.) |
| плотность пара: |
0.07 (21 °C, vs air) |
| форма: |
gas |
| цвет: |
colorless |
DEUTERIUM HYDRIDE химические свойства, назначение, производство
Химические свойства
col gas [CRC10]Density, g/L: 0.123 [CRC10]
Синтез
About 150 ml. of n-butyl ether, dried over Na, is distilled into
the reaction flask and 5.75 g. of LiAlH4 (40% excess) is then added
under a nitrogen blanket. The mixture is frozen with liquid N s.
The apparatus is then evacuated, and the flask contents are
brought to boiling by careful heating. After 1.5 hours, it is again cooled with liquid Ns
, the evacuation is repeated, and 5 ml. of
99.5% D2O is added to the solidified mixture, using
a hypodermic syringe to pierce the rubber cap. Because of the low reaction temperature, the flask
becomes coated with ice on the outside. By repeated immersion
in liquid N3, the temperature is controlled so that the ice on the
outer wall of the flask does not melt. As soon as the reaction
subsides somewhat, two additional portions of 6.5 ml. of DSO
each are added (for a total of 18 ml. or 150% excess). The yield
is 10 liters of HD. The purity is 97-99%.
LiAlH4 + 4D2O = LiOD + Al(OD)3 + 4HD
DEUTERIUM HYDRIDE препаратная продукция и сырье
сырьё
препарат
DEUTERIUM HYDRIDE поставщик
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