1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
1,3-Bis(2,4,6-trimethylphenyl)imidazolium Chloride
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Properties
- Melting point:
- >300 °C (lit.)
- Boiling point:
- 499.2°C (rough estimate)
- Density
- 1.0279 (rough estimate)
- refractive index
- 1.5940 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- color
- Off-white to beige
- Water Solubility
- Slightly soluble in water.
- InChIKey
- OTOSIXGMLYKKOW-UHFFFAOYSA-M
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H315-H319-H335
- Precautionary statements
- P261-P264-P271-P280-P302+P352-P305+P351+P338
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 29332900
Use
1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides.
2 India supplier list of "1,3-Bis(2,4,6-trimethylphenyl)imidazolium Chloride"
- Product Name:1,3-Bis(2,4,6-trimethylphenyl)imidazoliumchloride
- Products Intro:Brand:sigma aldrich | Product Number:574066
- Company Type: Trader
- Country/Region: Bangalore,INDIA
- Product Name:1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE
- Company Type: Reagent
- Country/Region: Gujarat,INDIA
- Product Name:1,3-Dimesityl-1H-imidazol-3-iumchloride
- Products Intro:Brand:ajchemicals | Product Number:JDH-5780 | Purity:98%
- Company Type: Trader
- Country/Region: New Delhi,INDIA
- Product Name:1,3-DimesitylimidazoliumChloride
- Products Intro:Brand:tcichemicals | Product Number:D3446
- Company Type: Reagent
- Country/Region: New Delhi,INDIA
- Product Name:1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE
- Company Type: Reagent
- Country/Region: Hyderabad,INDIA
- Product Name:1,3-bis(2,4,6-trimethylphenyl)imidazol-1-ium;chloride
- Products Intro:Brand:thermofisher.in | Product Number:356190010 | Purity:95%
- Company Type: Trader
- Country/Region: Maharashtra,INDIA
- Product Name:1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
- Products Intro:Purity: 98 | Package: 25Kg
- Company Type: Trader
- Country/Region: CHINA
- Product Name:1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
- Products Intro:Purity: 98%(Min,HPLC) | Package: 100g;1kg;5kg,10kg,25kg,50kg
- Company Type: Trader
- Country/Region: CHINA
- Main Products: 1159983-30-8,89466-59-1,149739-51-5,104901-79-3,10541-83-0
- Product Name:TIANFU CHEM 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE
- Products Intro:Purity: 99% | Package: 25KG;5KG;1KG
- Company Type: Trader
- Country/Region: CHINA
- Product Name:1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride
- Products Intro:Purity: 98% | Package: 10MG;50MG;100MG,1G,5G,10G.100G
- Company Type: Reagent
- Country/Region: CHINA