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Chloroacetaldehyde

Chloroacetaldehyde

CAS:
107-20-0
MF:
C2H3ClO
MW:
78.5

Properties

Melting point:
-28--23°C
Boiling point:
80-100 °C(lit.)
Density 
1.236 g/mL at 25 °C
vapor pressure 
100 at 20 °C (NIOSH, 1997)
refractive index 
n20/D 1.407
Flash point:
128 °F
solubility 
Soluble in ether (Weast, 1986), acetone, and methanol (Hawley, 1981)
form 
Colorless liquid
Water Solubility 
soluble in acetone, methanol. Fully miscible in water.
Sensitive 
Air Sensitive
Merck 
2109
BRN 
1071226
Exposure limits
Ceiling 3 mg/m3 (1 ppm) (ACGIH); IDLH.
LogP
0.62 at 25℃ and pH5.8

Safety Information

Symbol(GHS) 

GHS05,GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H301-H310+H330-H314-H335-H351-H400
Precautionary statements 
P202-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+,N
Risk Statements 
24/25-26-34-40-50-35
Safety Statements 
26-28-36/37/39-45-61
RIDADR 
UN 2232 6.1/PG 1
OEL
Ceiling: 1 ppm (3 mg/m3)
WGK Germany 
-
RTECS 
AB2450000
TSCA 
Yes
HazardClass 
6.1(a)
PackingGroup 
I
HS Code 
29130000
Toxicity
Acute oral LD50 for rats 75 mg/kg, mice 69 mg/kg (quoted, RTECS, 1985).
IDLA
45 ppm

Use

Chloroacetaldehyde polymerizes on standing. At greater than 50% concentration in water, Chloroacetaldehyde forms an insoluble hemihydrate. Sensitive to heat. Reacts with oxidizing agents. Incompatible with acids and water . Burns to give poisonous and irritating gases.

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