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Hexafluoroacetone

Hexafluoroacetone

CAS:
684-16-2
MF:
C3F6O
MW:
166.02

Properties

Melting point:
−129 °C(lit.)
Boiling point:
−26 °C(lit.)
Density 
1,32 g/cm3
vapor density 
1.65 (vs air)
vapor pressure 
4525 mm Hg ( 21.1 °C)
storage temp. 
Refrigerator
solubility 
Chloroform
form 
Colorless gas, which reacts vigorously with water to form hydrates

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS04,GHS06
Signal word 
Danger
Hazard statements 
H330-H314-H280
Precautionary statements 
P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P410+P403-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501
Hazard Codes 
T
Risk Statements 
60-14-23/24/25-34-63
Safety Statements 
53-26-28-36-45-7/9
RIDADR 
UN 2420 2.3
OEB
C
OEL
TWA: 0.1 ppm (0.7 mg/m3) [skin]
WGK Germany 
3
RTECS 
UC2450000
Hazard Note 
Highly Toxic
TSCA 
T
HazardClass 
2.3
Toxicity
LD50 (mg/kg) in rats: 190 orally (trihydrate), 670 dermally (sesquihydrate); in mice: 250 i.p., 180 i.v.; in rabbits: 113 dermally (trihydrate) (Kennedy)
IDLA
9 ppm (61 mg/m3)

Use

Hexafluoroacetone is a colorless, toxic, and highly reactive gas. At ambient temperatures, Hexafluoroacetone is likely to generate a considerable amount of vapor. Hexafluoroacetone is an irritant to skin, eyes and mucous membranes and is toxic by ingestion, skin absorption, and inhalation. When heated to high temperatures Hexafluoroacetone emits toxic fluoride fumes. Prolonged exposure of the container to fire or intense heat may cause Hexafluoroacetone to violently rupture and rocket. Hexafluoroacetone is used in the production of other chemicals.

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