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Tolylene-2,4-diisocyanate

Tolylene-2,4-diisocyanate

CAS:
584-84-9
MF:
C9H6N2O2
MW:
174.16

Properties

Melting point:
20-22 °C(lit.)
Boiling point:
124-126 °C18 mm Hg(lit.)
Density 
1.225 g/mL at 25 °C
vapor density 
6 (vs air)
vapor pressure 
0.03 mm Hg ( 25 °C)
refractive index 
n20/D 1.568(lit.)
Flash point:
250 °F
storage temp. 
2-8°C
solubility 
Miscible with ether, acetone, benzene, carbontetrachloride and chlorobenzene.
form 
Liquid
Specific Gravity
1.225
color 
Colorless
Odor
Sharp, pungent odor detectable at 0.02 to 0.4 ppm
explosive limit
9.5%
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Merck 
14,9530
BRN 
744602
Exposure limits
TLV-TWA 0.0355 mg/m3 (0.005 ppm) (ACGIH and NIOSH); STEL or ceiling/10 min 0.142 mg/m3 (0.02 ppm) (ACGIH, NIOSH, and OSHA); IDLH 71 mg/m3 (10 ppm) (NIOSH).
Stability:
Stable, but decomposes in the presence of moisture. Also heat and light sensitive. Readily polymerizes in contact with base. Reacts with compounds containing active hydrogen. Incompatible with strong oxidizing agents. Corrodes some copper and aluminium alloys.
InChIKey
DVKJHBMWWAPEIU-UHFFFAOYSA-N
LogP
3.43 at 22℃

Safety Information

Symbol(GHS) 

GHS06,GHS08
Signal word 
Danger
Hazard statements 
H315-H317-H319-H330-H334-H335-H351-H412
Precautionary statements 
P202-P273-P280-P302+P352-P304+P340+P310-P305+P351+P338
Hazard Codes 
T+
Risk Statements 
26-36/37/38-40-42/43-52/53
Safety Statements 
23-36/37-45-61
RIDADR 
UN 2078 6.1/PG 2
WGK Germany 
2
RTECS 
CZ6300000
10-21
Autoignition Temperature
>619 °C
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29291010
Toxicity
Acute oral LD50 for rats 5,800 mg/kg, wild birds 100 mg/kg (quoted, RTECS, 1985).
IDLA
2.5 ppm

Use

Tolylene-2,4-diisocyanate is explosive in the form of vapor when exposed to heat, flame or sparks. Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides. Reacts with water to liberate carbon dioxide. Potential explosion if stored in polyethylene containers due to absorption of water through the plastic. Emits very toxic fumes of oxides of nitrogen when heated to decomposition [Lewis, 3rd ed., 1993, p. 1251].

13 India supplier list of "Tolylene-2,4-diisocyanate"

  • Product Name:2,4-Toluenediisocyanate
  • Products Intro:Purity: 98% | Package: 1 kg,5 kg, 10 kg,25kg and 1 MT
  • Company Type: Manufacturer
  • Country/Region: Gujarat,INDIA
  • Product Name:Tolylene-2,4-diisocyanate
  • Products Intro:Brand:sigma aldrich | Product Number:T39853 | Purity:95%
  • Company Type: Trader
  • Country/Region: Bangalore,INDIA
  • Product Name:"Tolylene2,4-Diisocyanate"
  • Products Intro:Brand:clearsynth | Product Number:CS-T-44615
  • Company Type: Trader
  • Country/Region: Hyderabad,INDIA
  • Product Name:TolueneDiisocyanate
  • Products Intro:Brand:pciplindia | Product Number:184527349
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:Tolylene-2,4-diisocyanate,95%
  • Products Intro:Brand:ottokemi | Product Number:T2378
  • Company Type: Trader
  • Country/Region: Mumbai,INDIA
  • Product Name:Toluene-2-4-Diisocyanate(Tolylene-2,4-Diisocyanate,2,4-Diisocyanatotoluene)
  • Products Intro:Brand:cdhfinechemical | Product Number:245435
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:Tolylene2,4-diisocyanate,75%,technical,
  • Products Intro:Brand:thermofisher.in | Product Number:202502500 | Purity:80%
  • Company Type: Trader
  • Country/Region: Maharashtra,INDIA
  • Product Name:Tolylene-2,4-diisocyanate
  • Products Intro:Brand:tcichemicals | Product Number:T0263 | Purity:min.98.0%
  • Company Type: Reagent
  • Country/Region: New Delhi,INDIA
  • Product Name:Tolylene-2,4-diisocyanate
  • Company Type: Trader
  • Country/Region: New Delhi,INDIA
  • Product Name:Tolylene-2,4-Diisocyanate
  • Company Type: Trader
  • Country/Region: Mumbai,INDIA

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