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ChemicalBook > Product Catalogue >Organic Chemistry >Quinones >1,4-Benzoquinone

1,4-Benzoquinone

1,4-Benzoquinone Structure
  • ₹1280 - ₹496990
  • Product name: 1,4-Benzoquinone
  • CAS: 106-51-4
  • MF: C6H4O2
  • MW: 108.09
  • EINECS:203-405-2
  • MDL Number:MFCD00001591
  • Synonyms:1,4-Benzochinon ;1,4-Benzoquine;1,4-Cyclohexadiene dioxide;1,4-Cyclohexadienedione;p-Benzochinon ;pbq2 ;p-Chinon;quinone(p-benzoquinone)
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  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ALFA India
  • ottokemi

Package

  • 25G
  • 100gm
  • 8024105021
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  • 5G
  • 100G
  • 250g
  • 250gm
  • 500gm
  • 500G
  • 8024100521
  • 1000g
  • 1KG
  • 5000g
  • 25KG
  • 50KG
  • ManufacturerSigma-Aldrich(India)
  • Product numberB10358
  • Product descriptionp-Benzoquinone reagent grade, ≥98%
  • Packaging500G
  • Price₹5304.25
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product numberB10358
  • Product descriptionp-Benzoquinone reagent grade, ≥98%
  • Packaging1KG
  • Price₹6375.93
  • Updated2022-06-14
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  • ManufacturerTCI Chemicals (India)
  • Product numberB0089
  • Product description1,4-Benzoquinone
  • Packaging100G
  • Price₹6400
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.02410
  • Product descriptionp-Benzoquinone for synthesis
  • Packaging8024100521
  • Price₹6529.99
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.02410
  • Product descriptionp-Benzoquinone for synthesis
  • Packaging100G
  • Price₹6560
  • Updated2022-06-14
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  • ManufacturerALFA India
  • Product numberALF-A13162-30
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging250g
  • Price₹7552
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberB0887
  • Product description1,4-Benzoquinone
  • Packaging500G
  • Price₹8000
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product numberPHR1028
  • Product description1,4-Benzoquinone Pharmaceutical Secondary Standard; Certified Reference Material
  • Packaging1G
  • Price₹8530.1
  • Updated2022-06-14
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  • ManufacturerALFA India
  • Product numberALF-A13162-0B
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging1000g
  • Price₹10113
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.02410
  • Product descriptionp-Benzoquinone for synthesis
  • Packaging1KG
  • Price₹12600
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number12309
  • Product descriptionp-Benzoquinone for spectrophotometric det. of amines, ≥99.5% (HPLC)
  • Packaging25G
  • Price₹14992.63
  • Updated2022-06-14
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  • ManufacturerTCI Chemicals (India)
  • Product numberB0089
  • Product description1,4-Benzoquinone
  • Packaging500G
  • Price₹15100
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A13162-0I
  • Product descriptionp-Benzoquinone, 98+%
  • Packaging5000g
  • Price₹41181
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.02410
  • Product descriptionp-Benzoquinone for synthesis
  • Packaging8024105021
  • Price₹46630
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number12309
  • Product descriptionp-Benzoquinone for spectrophotometric det. of amines, ≥99.5% (HPLC)
  • Packaging100G
  • Price₹59299.35
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.02410
  • Product descriptionp-Benzoquinone for synthesis
  • Packaging25KG
  • Price₹255540.01
  • Updated2022-06-14
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Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) B10358 p-Benzoquinone reagent grade, ≥98% 500G ₹5304.25 2022-06-14 Buy
Sigma-Aldrich(India) B10358 p-Benzoquinone reagent grade, ≥98% 1KG ₹6375.93 2022-06-14 Buy
TCI Chemicals (India) B0089 1,4-Benzoquinone 100G ₹6400 2022-05-26 Buy
Sigma-Aldrich(India) 8.02410 p-Benzoquinone for synthesis 8024100521 ₹6529.99 2022-06-14 Buy
Sigma-Aldrich(India) 8.02410 p-Benzoquinone for synthesis 100G ₹6560 2022-06-14 Buy
ALFA India ALF-A13162-30 p-Benzoquinone, 98+% 250g ₹7552 2022-05-26 Buy
TCI Chemicals (India) B0887 1,4-Benzoquinone 500G ₹8000 2022-05-26 Buy
Sigma-Aldrich(India) PHR1028 1,4-Benzoquinone Pharmaceutical Secondary Standard; Certified Reference Material 1G ₹8530.1 2022-06-14 Buy
ALFA India ALF-A13162-0B p-Benzoquinone, 98+% 1000g ₹10113 2022-05-26 Buy
Sigma-Aldrich(India) 8.02410 p-Benzoquinone for synthesis 1KG ₹12600 2022-06-14 Buy
Sigma-Aldrich(India) 12309 p-Benzoquinone for spectrophotometric det. of amines, ≥99.5% (HPLC) 25G ₹14992.63 2022-06-14 Buy
TCI Chemicals (India) B0089 1,4-Benzoquinone 500G ₹15100 2022-05-26 Buy
ALFA India ALF-A13162-0I p-Benzoquinone, 98+% 5000g ₹41181 2022-05-26 Buy
Sigma-Aldrich(India) 8.02410 p-Benzoquinone for synthesis 8024105021 ₹46630 2022-06-14 Buy
Sigma-Aldrich(India) 12309 p-Benzoquinone for spectrophotometric det. of amines, ≥99.5% (HPLC) 100G ₹59299.35 2022-06-14 Buy
Sigma-Aldrich(India) 8.02410 p-Benzoquinone for synthesis 25KG ₹255540.01 2022-06-14 Buy

Properties

Melting point :113-115 °C(lit.)
Boiling point :293°C
Density :1.31
vapor density :3.73 (vs air)
vapor pressure :0.1 mm Hg ( 25 °C)
refractive index :n20/D 1.453
Flash point :38°C
storage temp. :room temp
solubility :10g/l
form :Powder
pka :7.7
color :Yellow to green
PH :4 (1g/l, H2O, 20℃)
Odor :irritant odor
Water Solubility :10 g/L (25 ºC)
Merck :14,8074
BRN :773967
Exposure limits :TLV-TWA 0.4 mg/m3 (0.1 ppm); STEL 1.2 mg/m3 (0.3 ppm) (ACGIH); IDLH 75 ppm (NIOSH).
Stability :Stable, but light sensitive. Incompatible with strong oxidizing agents. Flammable.
InChIKey :AZQWKYJCGOJGHM-UHFFFAOYSA-N
LogP :0.1-0.3 at 23℃ and pH4.8-5.3
CAS DataBase Reference :106-51-4(CAS DataBase Reference)
NIST Chemistry Reference :p-Benzoquinone(106-51-4)
IARC :3 (Vol. 15, Sup 7, 71) 1999
EPA Substance Registry System :Quinone (106-51-4)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,4-Benzoquinone is used as a dienophile in Diels-Alder cycloadditions to prepare naphthoquinones and 1,4-phenanthrenediones. It acts as a dehydrogenation reagent and an oxidizer in synthetic organic chemistry. In the Thiele-Winter reaction, it is involved in the preparation of triacetate of hydroxyquinol by reacting with acetic anhydride and sulfuric acid. It is also used in the synthesis of bromadol and to suppress double- bond migration during olefin metathesis reactions. It is used as a precursor to hydroquinone which finds application in photography and as a reducing agent and an antioxidant in rubber production.

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