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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Alkyne >1,9-DECADIYNE

1,9-DECADIYNE

1,9-DECADIYNE Structure
  • ₹5800
  • Product name: 1,9-DECADIYNE
  • CAS: 1720-38-3
  • MF: C10H14
  • MW: 134.22
  • EINECS:217-012-9
  • MDL Number:MFCD00014926
  • Synonyms:TIMTEC-BB SBB008879;1,9-DECADIYNE;Decadiyne;deca-1,9-diyne ;1,9-Decanediyne;1,9-Decadiyne,98%;1,9-Decadiyne, 97+%;1,9-Decadiyne (6CI, 7CI, 8CI, 9CI)
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Brand

  • TCI Chemicals (India)

Package

  • 5ML
  • ManufacturerTCI Chemicals (India)
  • Product numberD1326
  • Product description1,9-Decadiyne min. 98.0 %
  • Packaging5ML
  • Price₹5800
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D1326 1,9-Decadiyne min. 98.0 % 5ML ₹5800 2022-05-26 Buy

Properties

Melting point :-6.35°C (estimate)
Boiling point :80-81 °C (10 mmHg)
Density :0.822
refractive index :1.449-1.453
Flash point :60°C
storage temp. :Flammables area
form :Liquid
color :Clear yellow
Specific Gravity :0.816
Water Solubility :Insoluble in water.
BRN :1734594
CAS DataBase Reference :1720-38-3(CAS DataBase Reference)
EPA Substance Registry System :1,9-Decadiyne (1720-38-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

One-step synthesis of carbametacyclophane 3 from 1,9-decadiyne and diethyl acetylenedicarboxylate is described. The use of 1,9-decadiyne as a nucleophile led only to the monoalkynylation product, a selectivity that would be difficult to achieve with a catalytic in situ metalation process. 1,9-decadiyne reacts with iodobenzene (excess) to afford the bis-Sonogashira coupling product in excellent yield. 1,9-Decadiyne was dihydrated and gave 2,9-decanedione in 92% yield.

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