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Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure
  • ₹8237.83
  • Product name: Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • CAS: 100516-54-9
  • MF: C24H21NO4
  • MW: 387.43
  • EINECS:
  • MDL Number:MFCD00074958
  • Synonyms:CIVENTICHEM CV-2652;CIVENTICHEM CV-2655;BENZYL (2R,3S)-(-)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE;benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholin;Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholine-carboxylate 98%;(2R,3S)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5R,6S)-(-)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone,98%;(2R,3S)-()-N-Z-6-oxo-2,3-diphenylMorpholine
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number331872
  • Product description(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine 98%
  • Packaging1G
  • Price₹8237.83
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 331872 (2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine 98% 1G ₹8237.83 2022-06-14 Buy

Properties

Melting point :205-207 °C(lit.)
Boiling point :583.5±50.0 °C(Predicted)
alpha :-66 º (c=5.5 in methylene chloride)
Density :1.242±0.06 g/cm3(Predicted)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
pka :-3.33±0.60(Predicted)
form :Solid
color :White
optical activity :[α]25/D 66°, c = 5.5 in methylene chloride
InChIKey :HECRUWTZAMPQOS-XZOQPEGZSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(2R,3S)-(?)-N-Z-6-Oxo-2,3-diphenylmorpholine can be used in the optimized large scale synthesis of L-m-tyrosine. Also used in the asymmetric synthesis of Fmoc-L-cyclopentylglycine.

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