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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organozirconium >Bis(cyclopentadienyl)zirconium dichloride

Bis(cyclopentadienyl)zirconium dichloride

Bis(cyclopentadienyl)zirconium dichloride Structure
  • ₹2749.55 - ₹24410.38
  • Product name: Bis(cyclopentadienyl)zirconium dichloride
  • CAS: 1291-32-3
  • MF: C10H10Cl2Zr
  • MW: 292.32
  • EINECS:215-066-8
  • MDL Number:MFCD00003726
  • Synonyms:BIS(CYCLOPENTADIENYL)ZIRCONIUMICHLORIDE;BIS(CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE;DICHLORODICYCLOPENTADIENYLZIRCONIUM;DICYCLOPENTADIENYLZIRCONIUM DICHLORIDE;bis(3-cyclopentadienyl)dichlorozirconium;Bis(cyclopentadienyl)zirconium dichloride~Dichlorobis(cyclopentadienyl)zirconium;ZirconiuM, dichlorobis(h5-2,4-cyclopentadien-1-yl)-;Bis(cyclopentadienyl)zirconiuM(IV) dichloride >=98%
5 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • 100G
  • ManufacturerTCI Chemicals (India)
  • Product numberZ0007
  • Product descriptionZirconocene Dichloride
  • Packaging5G
  • Price₹3600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberZ0007
  • Product descriptionZirconocene Dichloride
  • Packaging25G
  • Price₹9000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number196215
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging100G
  • Price₹24410.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number196215
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging25G
  • Price₹6410
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number196215
  • Product descriptionBis(cyclopentadienyl)zirconium(IV) dichloride ≥98%
  • Packaging5G
  • Price₹2749.55
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) Z0007 Zirconocene Dichloride 5G ₹3600 2022-05-26 Buy
TCI Chemicals (India) Z0007 Zirconocene Dichloride 25G ₹9000 2022-05-26 Buy
Sigma-Aldrich(India) 196215 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 100G ₹24410.38 2022-06-14 Buy
Sigma-Aldrich(India) 196215 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 25G ₹6410 2022-06-14 Buy
Sigma-Aldrich(India) 196215 Bis(cyclopentadienyl)zirconium(IV) dichloride ≥98% 5G ₹2749.55 2022-06-14 Buy

Properties

Melting point :242-245 °C(lit.)
Boiling point :124-125°C/15mm
Flash point :124-125°C/15mm
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
form :Powder
color :white to off-white
Water Solubility :hydrolysis
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Sensitive :Air & Moisture Sensitive
Exposure limits :ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 CAS DataBase Reference :1291-32-3(CAS DataBase Reference)
NIST Chemistry Reference :Bis(cyclopentadienyl)zirconium dichloride(1291-32-3)
EPA Substance Registry System :Zirconocene dichloride (1291-32-3)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Bis(cyclopentadienyl)zirconium dichloride is used for for Stereoselective Glycosidation. It is also used in the catalyzed transamidation of primary amides with amines. Zirconocene dichloride can also be used to prepare the Negishi reagent,in oxidative cyclisation reactions. Other applications include it is used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

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