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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon sulfonate >N-Fluorobenzenesulfonimide

N-Fluorobenzenesulfonimide

N-Fluorobenzenesulfonimide Structure
  • ₹905 - ₹27311.48
  • Product name: N-Fluorobenzenesulfonimide
  • CAS: 133745-75-2
  • MF: C12H10FNO4S2
  • MW: 315.34
  • EINECS:-0
  • MDL Number:MFCD00144885
  • Synonyms:N-FLUOROBENZENESULFONIMIDE;N-FLUOROBENZENESULPHONIMIDE;N-FLUORODIBENZENESULFONAMIDE;N-Fluorobenzenesulfonimide(NFSI);N-FluorobenzenesulfonMide (NFA);N-FluorobenzenesulfoniMide, 97% 5GR;N-Fluorobis(phenylsulfonyl)amine NFSI NFBS;N-fluoro-N-(phenylsulfonyl)benzenesulfonaMide, NFSI
7 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 5g
  • 25g
  • 500G
  • ManufacturerALFA India
  • Product numberALF-L13955-03
  • Product descriptionN-Fluorobenzenesulfonimide, 97%
  • Packaging1g
  • Price₹905
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L13955-06
  • Product descriptionN-Fluorobenzenesulfonimide, 97%
  • Packaging5g
  • Price₹7647
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L13955-14
  • Product descriptionN-Fluorobenzenesulfonimide, 97%
  • Packaging25g
  • Price₹15103
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberF0335
  • Product descriptionN-Fluorobenzenesulfonimide [Fluorinating Reagent]
  • Packaging5G
  • Price₹3700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberF0335
  • Product descriptionN-Fluorobenzenesulfonimide [Fluorinating Reagent]
  • Packaging25G
  • Price₹14500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number392715
  • Product descriptionN-Fluorobenzenesulfonimide 97%
  • Packaging5G
  • Price₹5964.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number392715
  • Product descriptionN-Fluorobenzenesulfonimide 97%
  • Packaging500G
  • Price₹27311.48
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L13955-03 N-Fluorobenzenesulfonimide, 97% 1g ₹905 2022-05-26 Buy
ALFA India ALF-L13955-06 N-Fluorobenzenesulfonimide, 97% 5g ₹7647 2022-05-26 Buy
ALFA India ALF-L13955-14 N-Fluorobenzenesulfonimide, 97% 25g ₹15103 2022-05-26 Buy
TCI Chemicals (India) F0335 N-Fluorobenzenesulfonimide [Fluorinating Reagent] 5G ₹3700 2022-05-26 Buy
TCI Chemicals (India) F0335 N-Fluorobenzenesulfonimide [Fluorinating Reagent] 25G ₹14500 2022-05-26 Buy
Sigma-Aldrich(India) 392715 N-Fluorobenzenesulfonimide 97% 5G ₹5964.58 2022-06-14 Buy
Sigma-Aldrich(India) 392715 N-Fluorobenzenesulfonimide 97% 500G ₹27311.48 2022-06-14 Buy

Properties

Melting point :114-116 °C
Boiling point :471.4±28.0 °C(Predicted)
Density :1.4466 (estimate)
Flash point :110℃
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
solubility :Very soluble in acetonitrile, dichloromethane or THF and less soluble in toluene.
form :solid
pka :-32.45±0.70(Predicted)
color :white
BRN :5348902
InChIKey :RLKHFSNWQCZBDC-UHFFFAOYSA-N
CAS DataBase Reference :133745-75-2(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

N-Fluorobenzenesulfonimide fluorinates aromatics, enolates, azaenolates and carbanions in high yield. It is used for diastereoselective fluorination of Li enolates of chiral carboximides, for directed fluorination of ortho-lithiated aromatics and for a review of electrophilic N-F fluorinating agents. Asymmteric fluorinations is effected in the presence of a Pd-BINAP catalyst system at room temperature in an ionic liquid. It is a reagent employed in a palladium-catalyzed enantioselective fluorination of t-butoxycarbonyl lactones and lactams. It is also used in the electrophilic difluorination of dihalopyridines with butyl lithium and in the direct conversion of alcohols to dibenzenesulfonamides with triphenylphosphine.

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