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3-ETHOXY-3-OXOPROPYLZINC BROMIDE

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Structure
  • ₹21845 - ₹23620.15
  • Product name: 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
  • CAS: 193065-68-8
  • MF: C5H9BrO2Zn
  • MW: 246.41
  • EINECS:
  • MDL Number:MFCD00671976
  • Synonyms:3-ETHOXY-3-OXOPROPYLZINC BROMIDE;3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN;3-ethoxy-3-oxopropylzinc bromide solution;2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF;2-(Ethoxycarbonyl)ethylzinc bromide;3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF;3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF;3-Ethoxy-3-oxopropyL
Price2 Properties Safety Information Description
2 prices
Selected condition：

Brand

  • ALFA India
  • Sigma-Aldrich(India)

Package

  • 50mL
  • ManufacturerALFA India
  • Product numberALF-H26739-AD
  • Product description2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF
  • Packaging50mL
  • Price₹21845
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number498521
  • Product description3-Ethoxy-3-oxopropylzinc bromide solution 0.5?M in THF
  • Packaging50ML
  • Price₹23620.15
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-H26739-AD 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF 50mL ₹21845 2022-05-26 Buy
Sigma-Aldrich(India) 498521 3-Ethoxy-3-oxopropylzinc bromide solution 0.5?M in THF 50ML ₹23620.15 2022-06-14 Buy

Properties

Density :0.972 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C
Water Solubility :Reacts with water.
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

Description

In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, beta-unsaturated carbonyl compounds, ring opening reactions of epoxides and oxo vanadium-induced ligand coupling of aryltrimethyl zincates.

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Suppliers and manufacturers

Alfa Aesar
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. Absin Bioscience Inc. Merck KGaA Infinity SCI Santa Cruz Biotechnology Inc Shaanxi DIDU pharmaceutical and Chemical Co., Ltd Guangdong Wengjiang Chemical Reagent Co., Ltd. Panjin Infinity Scientific CO. LTD Shanghai Yingxin laboratory equipment Co., Ltd