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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE

1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE

1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Structure
  • ₹4892.9
  • Product name: 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
  • CAS: 21969-32-4
  • MF: C4H7ClMg
  • MW: 114.86
  • EINECS:
  • MDL Number:MFCD00216570
  • Synonyms:1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE;1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF;1-Methyl-2-propenylmagnesium chloride solution;1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE, 0 .5M SOLUTION IN TETRAHYDROFURAN;1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF
Price1 Properties Safety Information Description
1 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 100ML
  • ManufacturerSigma-Aldrich(India)
  • Product number420042
  • Product description1-Methyl-2-propenylmagnesium chloride solution 0.5?M in THF
  • Packaging100ML
  • Price₹4892.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 420042 1-Methyl-2-propenylmagnesium chloride solution 0.5?M in THF 100ML ₹4892.9 2022-06-14 Buy

Properties

Boiling point :67 °C
Density :0.917 g/mL at 25 °C
Flash point :−4 °F

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3		 Danger
Warning		 GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.

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