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POTASSIUM TRIETHYLBOROHYDRIDE

POTASSIUM TRIETHYLBOROHYDRIDE Structure
  • ₹9731.68
  • Product name: POTASSIUM TRIETHYLBOROHYDRIDE
  • CAS: 22560-21-0
  • MF: C6H16BK
  • MW: 138.1
  • EINECS:245-077-3
  • MDL Number:MFCD00011702
  • Synonyms:POTASSIUM TRIETHYLBOROHYDRIDE;potassiumtriethylborohydride,calselect?kt, ;Potassium triethylhydroborate(1-);PotassiuM triethylborohydride solution 1.0 M in THF;PotassiuM triethylborohydride, 1.0 M solution in THF, SpcSeal;Potassium triethylhydridoborate;potassiumtriethylborohydride,calselect?kt,intetrahydrofuran ;potassium triethylhydroborate
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 100ML
  • ManufacturerSigma-Aldrich(India)
  • Product number213438
  • Product descriptionPotassium triethylborohydride solution 1.0?M in THF
  • Packaging100ML
  • Price₹9731.68
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 213438 Potassium triethylborohydride solution 1.0?M in THF 100ML ₹9731.68 2022-06-14 Buy

Properties

Density :0.902 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables + water-Freezer (-20°C)e area
form :Solution
color :Clear
Sensitive :air sensitive, moisture sensitive

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

  • Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity
  • Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon

Reagent for:
  • Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine
  • Dehydrogenation reactions
  • Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates
  • Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons
  • Substitution reactions

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