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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Silane >Trimethylsilyl trifluoromethanesulfonate

Trimethylsilyl trifluoromethanesulfonate

Trimethylsilyl trifluoromethanesulfonate Structure
  • ₹2400 - ₹50217.18
  • Product name: Trimethylsilyl trifluoromethanesulfonate
  • CAS: 27607-77-8
  • MF: C4H9F3O3SSi
  • MW: 222.26
  • EINECS:248-565-4
  • MDL Number:MFCD00000406
  • Synonyms:CT3795;Methanesulfonic acid, trifluoro-, trimethylsilyl ester;SILANE TMS-TRIFLATE;TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TRIMETHYLSILYL TRIFLUOROMETHYLSULPHONATE;TRIFLUOROMETHANSULFONIC ACID TRIMETHYLSILYL ESTER;TRIFLUOROMETHANESULFONIC ACID TRIMETHYLSILYL ESTER;Trimethylsilyl Trifluoromethanesulfonate [Trimethylsilylating Agent]
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Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ottokemi

Package

  • 5G
  • 10G
  • 10ML
  • 25gm
  • 25G
  • 50ML
  • 50G
  • 100gm
  • 250ML
  • 250G
  • 500gm
  • ManufacturerSigma-Aldrich(India)
  • Product number225649
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging10G
  • Price₹2511.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number91741
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T)
  • Packaging10ML
  • Price₹4373.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number225649
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging50G
  • Price₹8703.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number91741
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T)
  • Packaging50ML
  • Price₹15782.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number225649
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging250G
  • Price₹35224.55
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number91741
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T)
  • Packaging250ML
  • Price₹50217.18
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0871
  • Product descriptionTrimethylsilyl Trifluoromethanesulfonate
  • Packaging250G
  • Price₹19300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0871
  • Product descriptionTrimethylsilyl Trifluoromethanesulfonate
  • Packaging25G
  • Price₹5200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0871
  • Product descriptionTrimethylsilyl Trifluoromethanesulfonate
  • Packaging5G
  • Price₹2400
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 2239
  • Product descriptionTrimethyl silyl triflate 99%
  • Packaging500gm
  • Price₹24003
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 2239
  • Product descriptionTrimethyl silyl triflate 99%
  • Packaging100gm
  • Price₹8604
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 2239
  • Product descriptionTrimethyl silyl triflate 99%
  • Packaging25gm
  • Price₹2403
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 225649 Trimethylsilyl trifluoromethanesulfonate 99% 10G ₹2511.4 2022-06-14 Buy
Sigma-Aldrich(India) 91741 Trimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T) 10ML ₹4373.3 2022-06-14 Buy
Sigma-Aldrich(India) 225649 Trimethylsilyl trifluoromethanesulfonate 99% 50G ₹8703.3 2022-06-14 Buy
Sigma-Aldrich(India) 91741 Trimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T) 50ML ₹15782.85 2022-06-14 Buy
Sigma-Aldrich(India) 225649 Trimethylsilyl trifluoromethanesulfonate 99% 250G ₹35224.55 2022-06-14 Buy
Sigma-Aldrich(India) 91741 Trimethylsilyl trifluoromethanesulfonate purum, ≥98.0% (T) 250ML ₹50217.18 2022-06-14 Buy
TCI Chemicals (India) T0871 Trimethylsilyl Trifluoromethanesulfonate 250G ₹19300 2022-05-26 Buy
TCI Chemicals (India) T0871 Trimethylsilyl Trifluoromethanesulfonate 25G ₹5200 2022-05-26 Buy
TCI Chemicals (India) T0871 Trimethylsilyl Trifluoromethanesulfonate 5G ₹2400 2022-05-26 Buy
ottokemi T 2239 Trimethyl silyl triflate 99% 500gm ₹24003 2022-05-26 Buy
ottokemi T 2239 Trimethyl silyl triflate 99% 100gm ₹8604 2022-05-26 Buy
ottokemi T 2239 Trimethyl silyl triflate 99% 25gm ₹2403 2022-05-26 Buy

Properties

Melting point :25°C
Boiling point :77 °C/80 mmHg (lit.)
Density :1.228 g/mL at 25 °C (lit.)
vapor pressure :4.7 hPa (20 °C)
refractive index :n20/D 1.36(lit.)
Flash point :78 °F
storage temp. :Store below +30°C.
solubility :sol aliphatic and aromatic hydrocarbons, haloalkanes, ethers.
form :Fuming Liquid
color :Clear colorless to light brown
Specific Gravity :1.15
Water Solubility :REACTS
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,9719
BRN :1868911
InChIKey :FTVLMFQEYACZNP-UHFFFAOYSA-N
CAS DataBase Reference :27607-77-8(CAS DataBase Reference)
NIST Chemistry Reference :Trimethylsilyl trifluoromethanesulfonate(27607-77-8)
EPA Substance Registry System :Methanesulfonic acid, trifluoro-, trimethylsilyl ester (27607-77-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Trimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their enol ethers. It is also employed for chemical glycosylation reactions. Its reactivity is similar to trimethylsilyl chloride and is also involved in organic synthesis.

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