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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon halides >3,3-Dimethylallyl bromide

3,3-Dimethylallyl bromide

3,3-Dimethylallyl bromide Structure
  • ₹1061.94 - ₹6495
  • Product name: 3,3-Dimethylallyl bromide
  • CAS: 870-63-3
  • MF: C5H9Br
  • MW: 149.03
  • EINECS:212-799-5
  • MDL Number:MFCD00000242
  • Synonyms:1-Brom-3-methyl-2-buten(4-2,2) ;1-bromo-3-methyl-2-buten ;2-Butene,1-bromo-3-methyl- ;3-Methyl-1-bromo-2-butene ;3-Methyl-2-butyenyl bromide;3-Methyl-butenyl bromide;3-Methylcrotyl bromide;3-Methylcrotylbromide
6 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • 10G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberB0844
  • Product description1-Bromo-3-methyl-2-butene (stabilized with Silver chip) min. 90.0 %
  • Packaging5G
  • Price₹2000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB0844
  • Product description1-Bromo-3-methyl-2-butene (stabilized with Silver chip) min. 90.0 %
  • Packaging25G
  • Price₹5700
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274372
  • Product description3,3-Dimethylallyl bromide 95%, contains silver wool as stabilizer
  • Packaging1G
  • Price₹1061.94
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number249904
  • Product description3,3-Dimethylallyl bromide technical grade, ~90%
  • Packaging5G
  • Price₹1959.33
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number274372
  • Product description3,3-Dimethylallyl bromide 95%, contains silver wool as stabilizer
  • Packaging10G
  • Price₹3464
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number249904
  • Product description3,3-Dimethylallyl bromide technical grade, ~90%
  • Packaging25G
  • Price₹6495
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B0844 1-Bromo-3-methyl-2-butene (stabilized with Silver chip) min. 90.0 % 5G ₹2000 2022-05-26 Buy
TCI Chemicals (India) B0844 1-Bromo-3-methyl-2-butene (stabilized with Silver chip) min. 90.0 % 25G ₹5700 2022-05-26 Buy
Sigma-Aldrich(India) 274372 3,3-Dimethylallyl bromide 95%, contains silver wool as stabilizer 1G ₹1061.94 2022-06-14 Buy
Sigma-Aldrich(India) 249904 3,3-Dimethylallyl bromide technical grade, ~90% 5G ₹1959.33 2022-06-14 Buy
Sigma-Aldrich(India) 274372 3,3-Dimethylallyl bromide 95%, contains silver wool as stabilizer 10G ₹3464 2022-06-14 Buy
Sigma-Aldrich(India) 249904 3,3-Dimethylallyl bromide technical grade, ~90% 25G ₹6495 2022-06-14 Buy

Properties

Melting point :-106.7°C (estimate)
Boiling point :82-83 °C150 mm Hg(lit.)
Density :1.29 g/mL at 20 °C(lit.)
refractive index :n20/D 1.489(lit.)
Flash point :88 °F
storage temp. :2-8°C
form :Liquid
Specific Gravity :1.27
color :Clear colorless, yellow or brown
Water Solubility :Immiscible with water
Sensitive :Light Sensitive
BRN :1420778
InChIKey :LOYZVRIHVZEDMW-UHFFFAOYSA-N
CAS DataBase Reference :870-63-3(CAS DataBase Reference)
NIST Chemistry Reference :2-Butene, 1-bromo-3-methyl-(870-63-3)
EPA Substance Registry System :2-Butene, 1-bromo-3-methyl- (870-63-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1-Bromo-3-methyl-2-butene is considered as a source of 3,3-dimethylallyl group and used in the preparation of natural products. It is also employed in the synthesis of base-modified pyrimidine nucleosides. Further, it is used in the preparation of (±)-eldanolide, 1-(3,3-dimethylallyl)-L-tryptophan and (±)-fumagillin, an antibiotic isolated from Aspergillus fumigattus.

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