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(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE

(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE Structure
  • ₹5098.58 - ₹42400
  • Product name: (4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
  • CAS: 32233-43-5
  • MF: C7H14O3
  • MW: 146.18
  • EINECS:
  • MDL Number:MFCD02682967
  • Synonyms:(S)-1,2-ISOPROPYLIDENEBUTANE-1,2,4-TRIOL;(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;2(2,2-DIMETHYL-[1,3] DIOXOLAN-4-YL)-ETHANOL (S);(4S)-2,2-Dimethyl-1,3-Dioxolane-4-Ethanol;(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHY&;(s)-(+)-2,2-dimethyl-1,3-dioxolane-4-ethanol;1,3-dioxolane-4-ethanol,2,2-dimethyl-,(4s);(S)-2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)ethanol
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberH1189
  • Product description(S)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane min. 95.0 %
  • Packaging1G
  • Price₹42400
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number571326
  • Product description(4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 96%
  • Packaging5G
  • Price₹5098.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number571326
  • Product description(4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 96%
  • Packaging25G
  • Price₹16962.78
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) H1189 (S)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane min. 95.0 % 1G ₹42400 2022-05-26 Buy
Sigma-Aldrich(India) 571326 (4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 96% 5G ₹5098.58 2022-06-14 Buy
Sigma-Aldrich(India) 571326 (4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 96% 25G ₹16962.78 2022-06-14 Buy

Properties

Boiling point :98 °C15 mm Hg(lit.)
Density :1.027 g/mL at 25 °C(lit.)
refractive index :n20/D 1.4380(lit.)
Flash point :213 °F
storage temp. :2-8°C
pka :14.80±0.10(Predicted)
form :liquid
color :Colorless to Almost colorless
optical activity :[α]20/D +2°, c = 1% in chloroform
InChIKey :LMHCQSYOFZFRMI-AGZQWMCOSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane may be used in the preparation (prop-2-ynyloxy)ethyl-tethered dioxolanes viaO-propargylation.It may also be used as an intermediate in the total synthesis of rugulactone.

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